References of "Léonard, Grégoire"
     in
Bookmark and Share    
Full Text
Peer Reviewed
See detailIndustrial Integration of Biotechnological Processes from Raw Material to Energy Integration: Study by Modeling Approach
Léonard, Grégoire ULiege; Pfennig, Andreas ULiege; Celebi, Ayse Dilan et al

in Darvishi, Farshad; Hiligsmann, Serge (Eds.) Microbial Fuels: Technologies and Applications (in press)

Detailed reference viewed: 45 (5 ULiège)
Full Text
Peer Reviewed
See detailRecent Evolutions and Trends in the Use of Computer Aided Chemical Engineering for Educational Purposes at the University of Liège
Léonard, Grégoire ULiege; Belboom, Sandra ULiege; Toye, Dominique ULiege et al

in Computer Aided Chemical Engineering (2017)

The present paper addresses the evolution and perspectives in the teaching of CAPE methods in the Department of Chemical Engineering at the University of Liège. The transition that happened in the 90ies ... [more ▼]

The present paper addresses the evolution and perspectives in the teaching of CAPE methods in the Department of Chemical Engineering at the University of Liège. The transition that happened in the 90ies with the arrival of commercial software is highlighted, as the learning outcomes evolved from the ability of building programs to solve chemical engineering problems towards the ability to use complex commercial software and to understand their limitations. Moreover, CAPE methods were extended to non-dedicated CAPE courses, which is illustrated here by the goals and challenges of their use in courses like “Reactor Engineering” and “Life Cycle Analysis”. It was observed that students sometimes assume that CAPE softwares provide straightforward and trustworthy solutions without the need of understanding their mathematical bases and assumptions. Thus, solutions to make students aware of these limitations are proposed, including the creation of an integrated project focussing on complex multi-disciplinary issues, evidencing the need for critical input from the operator. [less ▲]

Detailed reference viewed: 30 (6 ULiège)
Full Text
See detailChallenges of CO2 capture as an application of fluid separation techniques
Léonard, Grégoire ULiege

Conference (2017, May)

The presentation offers a review of CO2 capture technologies presented as an application of fluid separation. CO2 capture processes (Post-combustion, pre-combustion, oxyfuel combustion and industrial ... [more ▼]

The presentation offers a review of CO2 capture technologies presented as an application of fluid separation. CO2 capture processes (Post-combustion, pre-combustion, oxyfuel combustion and industrial processes) and CO2 capture methods (absorption, adsorption, membranes...) are described, and illustrated by industrial examples of these technologies. Techno-economic challenges faced by these technologies are also mentionned, and perspectives for future developments are discussed. [less ▲]

Detailed reference viewed: 34 (1 ULiège)
Full Text
See detailEffect of agitation rate on oxydative degradation of monoethanolamine
Benkoussas, Hana ULiege; Léonard, Grégoire ULiege; Kerbachi, Rabah

Poster (2017)

Detailed reference viewed: 117 (75 ULiège)
Full Text
See detailCCUS ou le rôle clé du CO2 dans la transition énergétique
Léonard, Grégoire ULiege

Conference (2016, November 29)

Detailed reference viewed: 9 (0 ULiège)
Full Text
See detailStockage intersaisonnier d’énergie
Léonard, Grégoire ULiege

Conference given outside the academic context (2016)

Detailed reference viewed: 7 (1 ULiège)
Full Text
Peer Reviewed
See detailIntegrated Project with Focus on Energy Transition and Circular Economy for Developing Engineering Students' Soft Skills
Léonard, Grégoire ULiege; Pfennig, Andreas ULiege; Toye, Dominique ULiege et al

Poster (2016, September 05)

The present work reports the experience of an integrated project developed at the University of Liege for master students in chemical engineering. The goals are to promote the acquisition of soft skills ... [more ▼]

The present work reports the experience of an integrated project developed at the University of Liege for master students in chemical engineering. The goals are to promote the acquisition of soft skills and to consolidate technical knowledge by integrating and linking chemical engineering disciplines usually taught separately. A case study was selected to address some of the challenges related to energy transition: students had to design the energy system of a remote island and make it as energy independent and CO2-neutral as possible by 2030. The course of action during the academic year, the assessment of soft skills, and the tools offered to ease the mentoring and encourage the acquisition of soft skills are described. Not all implemented techniques performed equally well, and this project finally appeared to be a challenge for the teaching team as well. 1 Introduction and background Over the last few years, University authorities, industrial partners as well as national and international experts that evaluated the education quality of our Department (AEQES, CTI) strongly suggested that opportunities should be offered to students to increase their soft skills as part of their curriculum. Moreover, many developments in chemical engineering are related to energy transition and circular economy, which are both transdisciplinary to conventional lectures. In this paper, we present methods and mentoring tools developed to teach students technical and soft skills for multi-disciplinary topics. 2 Description of the integrated project Objectives and constraints were defined at the onset of the project for both technical and soft skills. The technical objective was to propose an energy system that would make Reunion Island as energy independent and CO2-neutral as possible by 2030. This idea originated in the challenge set by the Eurecha 2015 student contest[1], for which students had to design facilities for a sheikhdom: electricity, water recycling, production of fertilizers… In our case, Reunion Island (~850 000 inhabitants) was considered as a case study as it is remote, has large biomass resources and high potential for renewable energies. Besides the objectives mentioned above and in order to force students to look at chemical engineering processes, the treatment of wastewater was imposed as well as the use of a synthetic liquid fuel as energy carrier. The targeted soft skills included working in large groups of minimum 4 students, efficient communication of results in English - both written and oral -, ability to integrate knowledge from various disciplines, development of critical mind and demonstration of independent and creative thinking. 3 Course of actions A team of 8 professors and senior scientists mentored the project and contributed to its assessment. The 10-ECTS project was divided in two parts. In the fall semester, students made global energy balances to design the energy system that would fulfill the objectives. As a result, a Sankey diagram of the energy flows on Reunion Island by 2030 was produced to allow for an overview of the available Island’s resources and needs, as well as of processes that can make the link between resources and needs. In the spring semester, two processes identified in the first part, namely the synthesis of bio-ethanol and bio-methanol, were modelled in more details using commercial software. Different tools were used to encourage student initiatives and work: • The use of a shared on-line portfolio for students to gather their documents improved their internal communication, but this remained a marginal channel for communication with teachers • In the fall semester, students orally presented progress reports every two weeks. After a feedback to students, the teaching team met to discuss the achievements and set the objectives for the next two weeks. This was very positive for the communication inside the teaching team. However, presentations every fortnight implied a work overload for students that had to constantly focus on preparing the presentations. • From the beginning, students were strongly encouraged to reach out to field experts whose contacts were provided. However, they preferred to rely mostly on Internet as their main source of information and reached out only rarely for help and usually very late. • In the fall semester, students had to designate new team leaders in turn every fortnight. This was abandoned as it prevented the establishment of clear structures in the group, reducing its efficiency. • In the spring semester, work tables allowed students to work directly with the teacher specialized in their task. This was appreciated by students and teachers, and it needs to be further encouraged. • Help in the group organization and interactions was provided by the PSGO (psychology of groups and organizations). This also included videoscopy, i.e. filming the students during their presentations and analyzing the records with them. This help was appreciated by students. The assessment was based on technical results for 60%, and soft skills for 40%. The evaluation of technical skills was done partly by all teachers equally and partly by teachers whose expertise was the closest to the technical sub-tasks. For soft skills, efficient communication, creativity in the work and results and links with conventional lectures were assessed. Critical thinking was evaluated through the relevance of qualitative and quantitative results and discussions. Group work was assessed by the teachers as well as by students through mutual evaluation. 4 Conclusions and perspectives The integrated project gave students a first opportunity to improve their soft skills along with their technical knowledge. It also improved their communication skills and their fluency in English. The teaching team proposed different mentoring techniques to encourage efficient work, with varying results. Finally, as the assessment ignored soft skills improvements, it may be modified by evaluating soft skills all year long so both the final result and the observed improvements contribute to the grade. Reference Eurecha, The European Committee for the Use of Computers in Chemical Engineering Education, 2015. Announcement for student contest problem competition 2015. http://bari.upc.es/eurecha/. [less ▲]

Detailed reference viewed: 75 (10 ULiège)
See detailUtilisation of CO2 from an Industrial source for Methanol production
Font-Palma, Carolina; Douven, Sigrid ULiege; Léonard, Grégoire ULiege

Conference (2016, September)

Detailed reference viewed: 44 (13 ULiège)
Full Text
Peer Reviewed
See detailDesign and Evaluation of a High-Density Energy Storage Route with CO2 Re-Use, Water Electrolysis and Methanol Synthesis
Léonard, Grégoire ULiege; Giulini, Davide; Villarreal-Singer, Diego

in Computer Aided Chemical Engineering (2016), 38

The energy transition corresponding to more electricity generation from variable and decentralized renewable energy sources requires the development of electricity storage technologies ranging from ... [more ▼]

The energy transition corresponding to more electricity generation from variable and decentralized renewable energy sources requires the development of electricity storage technologies ranging from seconds to seasons. The power-to-fuel process provides a way to store electricity as a liquid energy vector, leading to high energy density and cheap long-term storage at ambient conditions. In the present work, we study the powerto- methanol process combining CO2 capture, water/CO2 co-electrolysis and methanol synthesis. An Aspen Plus model focussing on the electrolysis and methanol synthesis sub-processes is presented. The energy conversion efficiency is improved from 40.1 to 53.0 % thanks to heat integration using the pinch method. Further works include the experimental demonstration of this technology as well as the development of control strategies for its regulation. [less ▲]

Detailed reference viewed: 90 (4 ULiège)
Full Text
See detailDesign and evaluation of a high-density energy storage route with CO2 re-use, water electrolysis and methanol synthesis
Léonard, Grégoire ULiege; Giulini, Davide; Villarreal-Singer, Diego

Poster (2016, June)

In the context of the Energy Transition, electricity storage ranging from seconds to seasons is needed to increase the integration of variable renewables sources. The power-tofuel process uses a liquid ... [more ▼]

In the context of the Energy Transition, electricity storage ranging from seconds to seasons is needed to increase the integration of variable renewables sources. The power-tofuel process uses a liquid energy vector with high energy density for long-term energy storage. In the present work, we simulate the power-to-methanol process in Aspen Plus. Then, we use heat integration to increase the conversion efficiency from 40.1 to 53.0 %, evidencing large improvement potential thanks to process integration. Further work includes experimental design and development of control strategies. [less ▲]

Detailed reference viewed: 21 (0 ULiège)
Full Text
Peer Reviewed
See detailInfluence of process operating conditions on solvent thermal and oxidative degradation in post-combustion CO2 capture
Léonard, Grégoire ULiege; Crosset, Cyril; Toye, Dominique ULiege et al

in Computers & Chemical Engineering (2015), 83

The CO2 post-combustion capture with amine solvents is modeled as a complex system interconnecting process energy consumption and solvent degradation and emission. Based on own experimental data ... [more ▼]

The CO2 post-combustion capture with amine solvents is modeled as a complex system interconnecting process energy consumption and solvent degradation and emission. Based on own experimental data, monoethanolamine degradation is included into a CO2 capture process model. The influence of operating conditions on solvent loss is validated with pilot plant data from literature. Predicted solvent consumption rates are in better agreement with plant data than any previous work, and pathways are discussed to further refine the model. Oxidative degradation in the absorber is the largest cause of solvent loss while thermal degradation does not appear as a major concern. Using a single model, the process exergy requirement decreases by 10.8% and the solvent loss by 11.1% compared to our base case. As a result, this model provides a practical tool to simultaneously minimize the process energy requirement and the solvent consumption in post-combustion CO2 capture plants with amine solvents. [less ▲]

Detailed reference viewed: 125 (23 ULiège)
Full Text
Peer Reviewed
See detailCOPPER LEACHING FROM WASTE ELECTRIC CABLES BY BIOHYDROMETALLURGY
Lambert, Fanny ULiege; Bastin, David ULiege; Gaydardzhiev, Stoyan ULiege et al

in Minerals Engineering (2015)

This study examines the leaching of copper from waste electric cables by chemical leaching and leaching catalysed by Acidithiobacillus ferrooxidans in terms of leaching kinetics and reagents consumption ... [more ▼]

This study examines the leaching of copper from waste electric cables by chemical leaching and leaching catalysed by Acidithiobacillus ferrooxidans in terms of leaching kinetics and reagents consumption. Operational parameters such as the nature of the oxidant (Fe3+, O2), the initial ferric iron concentration (0-10 g/L) and the temperature (21-50°C) were identified to have an important influence on the degree of copper solubilisation. At optimal process conditions, copper extraction above 90% was achieved in both leaching systems, with a leaching duration of 1 day. The bacterial leaching system slightly outperformed the chemical one but the positive effect of regeneration of Fe3+ was limited. It appears that the Fe2+ bio-oxidation is not sufficiently optimised. Best results in terms of copper solubilisation kinetics were obtained for the abiotic test at 50°C and for the biotic test at 35°C. Moreover, the study showed that in same operating conditions, a lower acid consumption was recorded for the biotic test than for the abiotic test. [less ▲]

Detailed reference viewed: 160 (46 ULiège)
Full Text
Peer Reviewed
See detailElectricity storage with liquid fuels in a zone powered by 100% variable renewables
Léonard, Grégoire ULiege; François-Lavet, Vincent ULiege; Ernst, Damien ULiege et al

in Proceedings of the 12th International Conference on the European Energy Market - EEM15 (2015)

In this work, an electricity zone with 100% renewables is simulated to determine the optimal sizing of generation and storage capacities in such a zone. Using actual wind output data, the model evaluates ... [more ▼]

In this work, an electricity zone with 100% renewables is simulated to determine the optimal sizing of generation and storage capacities in such a zone. Using actual wind output data, the model evaluates the economic viability of a power-to-fuel storage technology that combines water electrolysis, CO2 capture and methanol synthesis. The main advantage of using methanol as an energy carrier is that liquid fuels are suitable for (long-term) energy storage thanks to their high energy density. The levelized electricity cost projection by 2050 equals 83.4 €/MWh in the base case configuration. The effects of storage round-trip efficiency and the storage unit lifetime are quantified and their impacts on the electricity cost discussed. Additional benefits of using methanol as a fuel substitute may be taken into account in further work. [less ▲]

Detailed reference viewed: 876 (51 ULiège)
Full Text
See detailProcess Design and Heat Integration for the Power - to - Methanol Route
Léonard, Grégoire ULiege; Giulini, Davide ULiege; Villarreal-Singer, Diego et al

Conference (2015)

Detailed reference viewed: 43 (2 ULiège)
Full Text
See detailAir Capture and Power-to-Fuel to Close the Carbon Loop
Léonard, Grégoire ULiege; Giulini, Davide ULiege; Villarreal-Singer, D et al

Conference (2015)

Detailed reference viewed: 44 (2 ULiège)
Full Text
See detailAir Capture and Power-to-Fuel to Close the Carbon Loop
Léonard, Grégoire ULiege; Villarreal-Singer, D; Lackner, K S

Poster (2015)

Detailed reference viewed: 49 (7 ULiège)