Coupling X-ray microtomography and macroscopic soil measurements: a method to enhance near saturation functions?Beckers, Eléonore ; ; et alin Hydrology & Earth System Sciences Discussions (in press) Agricultural management practices influence soil structure, but the characterization of these modifications and consequences are still not completely understood. In this study, we aim at improving water ... [more ▼] Agricultural management practices influence soil structure, but the characterization of these modifications and consequences are still not completely understood. In this study, we aim at improving water retention and hydraulic conductivity curves using both classical soil techniques and X-ray microtomography in the context of tillage simplification. We show a good match for retention and conductivity functions between macroscopic measurements and microtomographic information. Microtomography highlights the presence of a secondary pore system. Analysis of structural parameters for these pores appears to be significant and offers additional clues for objects differentiation. We show that relatively fast scans supply not only good results, but also enhance near saturation characterization, making microtomography a highly competitive instrument for routine soil characterization. [less ▲] Detailed reference viewed: 9 (3 ULg) What is the right pathway to be sustainable? Case of biofuels and bioproducts in EuropeBelboom, Sandra ; Léonard, Angélique ![]() Conference (2013, May 15) Detailed reference viewed: 1 (1 ULg) Environmental footprint of HDPE: comparison between biobased and fossil productsBelboom, Sandra ; Léonard, Angélique ![]() Poster (2013, May) Detailed reference viewed: 25 (4 ULg) Convective drying of wastewater sludge: Introduction of shrinkage effect in mathematical modelingBennamoun, Lyes ; Crine, Michel ; Léonard, Angélique ![]() in Drying Technology (2013), 31(6), 643-654 Detailed reference viewed: 2 (0 ULg) Use of Life Cycle Assessment in view of Eco-Design for a glass wool processGerbinet, Saïcha ; Renzoni, Roberto ; et alConference (2013, April 25) Detailed reference viewed: 7 (1 ULg) Use of Life Cycle Assessment to determine the environmental impact of thermochemical conversion routes of lignocellulosic biomass: The gasification stepGerbinet, Saïcha ; ; Léonard, Angélique ![]() Poster (2013, April 22) Detailed reference viewed: 16 (3 ULg) Land use change: An essential aspect of Life Cycle Analysis of lignocellulosic biomass conversion processesGerbinet, Saïcha ; Léonard, Angélique ![]() Conference given outside the academic context (2013) Detailed reference viewed: 1 (0 ULg) L’Analyse du Cycle de vie : quoi, pourquoi, comment ?Léonard, Angélique ![]() Scientific conference (2013, March 22) Detailed reference viewed: 1 (0 ULg) ACV et Ecoconception: illustration de la démarche au sein de Knauf Insulation.Gerbinet, Saïcha ; ; Léonard, Angélique ![]() Conference (2013, March 22) Detailed reference viewed: 14 (0 ULg) Importance of LUC and ILUC on the carbon footprint of bioproduct:case of bio-HDPEBelboom, Sandra ; Léonard, Angélique ![]() Conference (2013) Due to the depletion of fossil fuels and the increase of greenhouse gas emissions, solutions are needed to replace petrol based products. As a consequence, the number of biobased products developed using ... [more ▼] Due to the depletion of fossil fuels and the increase of greenhouse gas emissions, solutions are needed to replace petrol based products. As a consequence, the number of biobased products developed using agricultural feedstock is continuously increasing. This study focuses on the carbon footprint of bio-HDPE produced either from Brazilian sugar cane or Belgian sugar beet. The goal of this study is to compare the carbon footprint of bio-HDPE with the fossil one, taking into account the effect of land use change. Common boundaries of the agricultural systems comprise the cultivation step for both crops, i.e. sugar cane and sugar beet, with all associated energy and fertilizer consumptions, the transportation step from field to the industrial plant, the sugar crops transformation into hydrate bioethanol, the by-products valorisation, the dehydration and polymerization steps and the HDPE incineration as end of life issue. Fossil scenario includes the production of ethylene, its polymerization and its incineration. When comparing the entire life cycle of bio and fossil HDPE, the GHG emissions are lower for the biobased product which is the willing effect. This result is only valid if no Land Use Change (LUC) or Indirect Land Use Change (ILUC) effect appears. To assess the environmental impact of the deforestation or of the transformation of a pasture into a field, the EC-Guidelines from the European Union were used in order to calculate the CO2 emissions depending on several parameters. For sugar cane, LUC consists in the transformation of pastures into fields in the region of Sao Paulo in Brazil. Three scenarios can be developed based on different agricultural practices for pasture and field (tillage and fertilizers inputs): the best, the worst and the average. The best case leads to a supplementary environmental gain. The worst and average achieve additional emissions. A payback time, considering the time needed to find again an environmental gain compared to the fossil counterpart, was calculated for the average scenario which is equal to 12 years. The ILUC effect for sugar cane is assumed to be deforestation due to the transformation of forest into pasture induced by the previous LUC effect. The rate of deforestation can vary between 16% or 100% depending on used statistics and leads to a payback time of respectively 26 and 101 years. For sugar beet, no LUC is considered. Indeed, no land expansion is available in Belgium due to small available areas. In the case of an increase of bioplastics production, Belgium should import sugar beet from neighboring countries which can induce ILUC. In this study, sugar beet is assumed to be provided by the Netherlands on pastures previously transformed into fields. The average scenario implies a payback time of 8 years. This study permits to highlight the importance of LUC and ILUC especially for energetic crops dedicated to replace fossil products. This effect can reverse expected results and induce long payback times. [less ▲] Detailed reference viewed: 21 (0 ULg) Determination of Moisture Diffusivity During Drying of Mortar Cement: Experimental and Modeling StudyBennamoun, Lyes ; Kahlerras, Loubna ; Michel, Frédéric et alin International Journal of Energy Engineering (2013), 3(1), 1-6 The aim of this study is the experimental characterization of the behaviour of a mortar during convective drying. We focalise on mortar that has a rate water-cement of 0.5. The drying tests are developed ... [more ▼] The aim of this study is the experimental characterization of the behaviour of a mortar during convective drying. We focalise on mortar that has a rate water-cement of 0.5. The drying tests are developed in a micro-convective dryer that can use samples weighing from 0 to 8g. The advantage of these experiments is to reproduce the natural conditions that can be found during the treatment of the mortar-atmosphere problems. The response of the drying curve or the drying kinetic depends on the applied drying conditions. So, the temperature of the air varies from 60°C to 130°C, the velocity of the air is changed from 2 m.s-1 to 5 m. s-1and the relative humidity is kept less than 1.7%. The comparison between the experimental results and the proposed analytical solutions of the equation of diffusion represented by Fick’s law, applied for a finite shape, allows determination of the values of the diffusion coefficient. It has a value of 1.71×10-10 m2.s-1 at 60°C, 13.69×10-10 m2.s-1 at 90°C and 16.27×10-10 m2.s-1 at 130°C. Calculation of the activation energy and the D0 constant are also possible. [less ▲] Detailed reference viewed: 85 (27 ULg) A comparison of three calcium phosphate based space fillers in sinus elevation: a study in rabbitsLAMBERT, France ; Léonard, Angélique ; LECLOUX, Geoffrey et alin International Journal of Oral & Maxillofacial Implants (2013) Aim: Sub-sinusal bone regeneration procedures are reliable procedures that are known to be efficient with the use of biomaterials alone. Nevertheless, many types of biomaterials are available, and their ... [more ▼] Aim: Sub-sinusal bone regeneration procedures are reliable procedures that are known to be efficient with the use of biomaterials alone. Nevertheless, many types of biomaterials are available, and their efficacy in terms of bone formation and resorption rate have rarely been compared. This study aimed to compare the bone formation, resorption rate, osteoconductivity and 3D volume changes of three biomaterials often used for alveolar ridge augmentation. Materials and Methods: Rabbits underwent a double sinus lift procedure using three different types of space fillers: bovine hydroxyapatite (BHA), beta calcium phosphate (ß-TCP) and biphasic calcium phosphate (BCP). Animals were sacrificed at 1 week, 5 weeks and 6 months. Samples were subjected to X-ray microtomography and histology. Qualitative analysis was performed on non-decalcified sections, and quantitative histomorphometric analysis was conducted using SEM. Volume variations of bone augmentations were calculated at different time points. Results: All three particulated biomaterials proved to be effective in promoting osteogenesis. At 6 months, biomaterial resorption rates were significantly different across the 3 groups (p<0.0001). The highest resorption rate was found with β-TCP, in which only 6.7% of the baseline particle surface remained. At 6 months, bone was in close contact with the BHA particles, constituting a composite network; in contrast, BCP particles were often surrounded by soft tissues. In each group, no significant difference in volume variations were found at the different time point. Conclusions and clinical implications: Despite the limitations of the study, the three particulated space-filling biomaterials proved to be efficient to promote osteogenesis. High resorption rates and complete replacement of the biomaterials by bone seemed to withstand intrasinusal pressure. Further investigations in humans should consider longer follow-up periods. [less ▲] Detailed reference viewed: 8 (3 ULg) What is the best use of sugar crops? Environmental asssement of two applications : biofuels vs. bioproductsBelboom, Sandra ; Léonard, Angélique ![]() Poster (2012, November 08) Detailed reference viewed: 17 (6 ULg) Use of Life Cycle Assesment to determine the environmental impact of thermochemical conversion routes of lignocellulosic biomass: state of the art.Gerbinet, Saïcha ; Léonard, Angélique ![]() Poster (2012, November 07) Abstract: The biomass is a promising way to substitute fossil fuels. Lignocellulosic biomass valorisation is part of second generation technologies. They are interesting in that they imply less ... [more ▼] Abstract: The biomass is a promising way to substitute fossil fuels. Lignocellulosic biomass valorisation is part of second generation technologies. They are interesting in that they imply less competition with food crops for land and water, and they allow for the whole plant to be processed. Moreover, lignocellulose is abundant in cheap and non-food materials extracted from plants such as wood and energy crops. The thermo-chemical route is being considered more extensively, especially the gasification process. This process converts carbonaceous biomass into combustible gases (CO, H2, CO2, CH4, and impurities) called syngas in the presence of a suitable oxidant. The syngas can be converted into a large range of products, such as diesel, via a Fischer-Tropsch process, or methanol, used for producing DME (dimethyl ether), both of which can serve as fuels in traditional motors. Syngas can also be used to produce ethylene and propylene, two building blocks for the chemical industry. Production of these four compounds is specifically investigated. In order to insure that, under the principle of sustainability, the use of lignocellulosic biomass is a viable alternative, its environmental impact must be accurately quantified. The Life Cycle Assessment (LCA) methodology will be used in this regard for the gasification process. The gasification technology will be described, and a state of the art in LCA of the gasification process will be presented. Finally, the need for new research will be established. [less ▲] Detailed reference viewed: 16 (2 ULg) Use of Life Cycle Assessment to determine the environmental impact of thermochemical conversion routes of lignocellulosic biomass: state of the artGerbinet, Saïcha ; Léonard, Angélique ![]() in LCA conference 2012 - Proceeding of the 2nd international conference on life cycle approaches (2012, November 07) The biomass is a promising way to substitute fossil fuels. Lignocellulosic biomass valorisation is part of second generation technologies. They are interesting in that they imply less competition with ... [more ▼] The biomass is a promising way to substitute fossil fuels. Lignocellulosic biomass valorisation is part of second generation technologies. They are interesting in that they imply less competition with food crops for land and water, and they allow for the whole plant to be processed. Moreover, lignocellulose is abundant in cheap and non-food materials extracted from plants such as wood and energy crops. The thermo-chemical route is being considered more extensively, especially the gasification process. This process converts carbonaceous biomass into combustible gases (CO, H2, CO2, CH4, and impurities) called syngas in the presence of a suitable oxidant. The syngas can be converted into a large range of products, such as diesel, via a Fischer-Tropsch process, or methanol, used for producing DME (dimethyl ether), both of which can serve as fuels in traditional motors. Syngas can also be used to produce ethylene and propylene, two building blocks for the chemical industry. Production of these four compounds is specifically investigated. In order to insure that, under the principle of sustainability, the use of lignocellulosic biomass is a viable alternative, its environmental impact must be accurately quantified. The Life Cycle Assessment (LCA) methodology will be used in this regard for the gasification process. The gasification technology will be described, and a state of the art in LCA of the gasification process will be presented. Finally, the need for new research will be established. [less ▲] Detailed reference viewed: 10 (1 ULg) Life Cycle Assessment of an artisanal Belgian blond beerMelon, Raphaëlle ; ; Renzoni, Roberto et alin [avniR] editions (Ed.) Proceedings of the 2nd International Conference on life cycle approaches (2012, November 06) Detailed reference viewed: 19 (5 ULg) What is the best use of sugar crops? Environmental assessment of two applications : biofuels vs. bioproductsBelboom, Sandra ; Léonard, Angélique ![]() in [avniR] editions (Ed.) LCA Conference 2012 - Proceedings of the 2nd international conference on life cycle approaches (2012, November) Agricultural crops became through years a possibility to increase European energy independence. Brazil has taken this opportunity since the seventies by using sugar cane bioethanol as vehicle fuel. The ... [more ▼] Agricultural crops became through years a possibility to increase European energy independence. Brazil has taken this opportunity since the seventies by using sugar cane bioethanol as vehicle fuel. The development of biofuels production is more recent in Europe. Due to temperate climates, bioethanol production is mostly based on wheat and sugar beet, this latter being considered as the ‘equivalent’ sugar crop to sugar cane for Europe. Biofuel is the most common application of bioethanol but its transformation into bioethylene through a dehydration step can be an alternative as already found in Brazil. This paper will consider both potential uses and compare them using Life Cycle Assessment methodology. Common boundaries of the systems comprise the cultivation step for both crops, i.e. sugar cane and sugar beet, with all associated energetic and fertilizer consumptions, the transportation step from field to the industrial plant, the sugar crops transformation into hydrate bioethanol and the by-products valorisation. For the biofuel scenario, a dehydration step using molecular sieve is added to get anhydrous bioethanol. For the bioethylene scenario, an industrial dehydration step is added. Direct comparison between both scenarios is not possible due to different products uses. The comparison was then performed for both scenarios between the bio-based product and its fossil equivalent. ReCiPe 2008 method was used to get the environmental impacts. As expected, the impact of bio-based products in climate change and fossil fuel depletion categories decreases compared to the fossil counterparts. For other categories, difference is less significant and results are often better for fossil products. Land use change category was implemented to assess its importance. Depending on assumptions, the greenhouse gas emissions from crop implementation on a natural land can counteract the previous mentioned benefits. This study shows the importance of assumptions, especially in the agricultural field, on the obtained results. [less ▲] Detailed reference viewed: 34 (7 ULg) MODELING OF A GLASS WOOL PROCESS IN VIEW OF LIFE CYCLE ASSESSMENT (L.C.A.)Gerbinet, Saïcha ; Renzoni, Roberto ; et alPoster (2012, November) Taking into account the environmental aspects in the building sector has become unavoidable. In France, environmental and sanitary statements for building products (“Fiches de Déclarations ... [more ▼] Taking into account the environmental aspects in the building sector has become unavoidable. In France, environmental and sanitary statements for building products (“Fiches de Déclarations Environnementales et Sanitaires” (FDE&S)) have been developed. The environmental part of the statement is based on Life Cycle Assessment. So, KnaufInsulation, glass wool producer for the French market, has started to evaluated the environmental impacts of it process in view of FDE&S realization. The process has been modeling in GaBi with industrial data. Adjustable parameters have been introduced to allow to study the environmental impacts of almost all the KnaufInsulation products. So the FDE&S can be easily done for the different products. This model is also used for eco-conception. The LCA results allow to show the life cycle leaks. More, in modifying the model, the impact of a change in the process on its environmental performances will be highlighted. So relevant improvement will be brought out. The model and the mains results as the eco-conception strategy will be presented. The interest of making a modeling based on the step and process of the life cycle of a product or a product range will be clearly understood. [less ▲] Detailed reference viewed: 11 (0 ULg) What is the best use of sugar crops? Environmental assessment of two potential applications : biofuels vs. bioproductsBelboom, Sandra ; Léonard, Angélique ![]() Conference (2012, November) Agricultural crops became through years an attractive option to increase European energy independence. Brazil has taken this opportunity since the seventies by using sugar cane bioethanol as vehicle fuel ... [more ▼] Agricultural crops became through years an attractive option to increase European energy independence. Brazil has taken this opportunity since the seventies by using sugar cane bioethanol as vehicle fuel. The development of biofuels production is more recent in Europe. Due to temperate climates, bioethanol production is mostly based on wheat and sugar beet, this latter being considered as the ‘equivalent’ sugar crop to sugar cane for Europe. Biofuel is the most common application of bioethanol but its transformation into bioethylene through a dehydration step and then its polymerization into bioplastic can be an alternative as already found in Brazil. This paper will consider both potential uses and compare them using Life Cycle Assessment methodology. Common boundaries of the systems comprise the cultivation step for both crops, i.e. sugar cane and sugar beet, with all associated energetic and fertilizer consumptions, the transportation step from field to the industrial plant, the sugar crops transformation into hydrate bioethanol, the by-products valorisation and the specific end-of-life. For the biofuel scenario, a dehydration step using molecular sieve is added to get anhydrous bioethanol. For the bioethylene scenario, industrial dehydration and polymerization steps are added. Direct comparison between both scenarios is not possible due to different products uses. The comparison was then performed for both scenarios between the bio-based product and its fossil equivalent. ReCiPe 2008 method was used at midpoint level to get the environmental impacts. As expected, the impact of bio-based products in climate change and fossil fuel depletion categories decreases compared to the fossil counterparts. For other categories, difference is less significant and results are often better for fossil products. Land use change impact was implemented to assess its importance. Depending on assumptions, the greenhouse gas emissions from crop implementation on a natural land can counteract the previous mentioned benefits. To get an idea of the performance of each considered bioethanol use, a single score relative to the amount of sugar cane and sugar beet cultivated on one hectare was calculated using the endpoint level of ReCiPe 2008 methodology. The environmental gain was then evaluated comparing the bio-based product use with the classical one. The highest performance was obtained for the bioplastic scenario based on sugar cane followed by the sugar beet bioplastic. The E5 biofuel based on sugar beet reaches a slightly lower gain. The E85 fuel obtains less gain due to the higher amount of biofuel needed to drive the same distance as using fossil fuel. When taking the land use change into account, the best gain is given by the sugar beet bioplastic. On the one hand, this study shows the importance of assumptions, especially in the agricultural field, on the obtained results. On the other hand, it points out that considering bioethanol as a chemical intermediate and not a fuel can be better from an environmental point of view. [less ▲] Detailed reference viewed: 52 (7 ULg) MODELING OF A GLASS WOOL PROCESS IN VIEW OF LIFE CYCLE ASSESSMENT (L.C.A.)Gerbinet, Saïcha ; Renzoni, Roberto ; et alin LCA conference 2012 - Proceeding of the 2nd international conference on life cycle approaches (2012, November) Taking into account the environmental aspects in the building sector has become unavoidable. In France, environmental and sanitary statements for building products (“Fiches de Déclarations ... [more ▼] Taking into account the environmental aspects in the building sector has become unavoidable. In France, environmental and sanitary statements for building products (“Fiches de Déclarations Environnementales et Sanitaires” (FDE&S)) have been developed. The environmental part of the statement is based on Life Cycle Assessment. So, KnaufInsulation, glass wool producer for the French market, has started to evaluated the environmental impacts of it process in view of FDE&S realization. The process has been modeling in GaBi with industrial data. Adjustable parameters have been introduced to allow to study the environmental impacts of almost all the KnaufInsulation products. So the FDE&S can be easily done for the different products. This model is also used for eco-conception. The LCA results allow to show the life cycle leaks. More, in modifying the model, the impact of a change in the process on its environmental performances will be highlighted. So relevant improvement will be brought out. The model and the mains results as the eco-conception strategy will be presented. The interest of making a modeling based on the step and process of the life cycle of a product or a product range will be clearly understood. [less ▲] Detailed reference viewed: 18 (0 ULg) |
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