References of "Job, Nathalie"
     in
Bookmark and Share    
Full Text
Peer Reviewed
See detailCarbon xerogels as model materials: toward a relationship between pore texture and electrochemical behavior as anodes for lithium-ion batteries
Piedboeuf, Marie-Laure ULg; Léonard, Alexandre ULg; Deschamps, Fabien ULg et al

in Journal of Materials Science (2016), 51(9), 4358-4370

The mechanisms of Li+ insertion in porous hard carbons used as anodes for Li-ion batteries are still a matter of debate, especially considering the divergence of electrochemical performances observed in ... [more ▼]

The mechanisms of Li+ insertion in porous hard carbons used as anodes for Li-ion batteries are still a matter of debate, especially considering the divergence of electrochemical performances observed in literature. Since these materials usually exhibit several levels of porosity, the pore texture vs. electrochemical behavior relationship is difficult to establish. In this paper, we propose to use carbon xerogels, prepared from aqueous resorcinol-formaldehyde mixtures, as model materials for Li-ion battery anodes to study the influence of the pore texture on the overall electrochemical behavior. Indeed, carbon xerogels are described as microporous nodules linked together to form meso- or macroporous voids inside a 3D gel structure; the size of these voids can be tuned by changing the synthesis conditions without affecting other parameters such as the micropore volume. The materials are chosen so as to obtain identical average particle sizes, homogeneous coatings with similar thicknesses and a comparable surface chemistry. The electrochemical behavior of carbon xerogels as Li-ion anodes are correlated with the surface accessible to the electrolyte and are not dependent on the total specific surface area calculated by the BET method from nitrogen adsorption isotherms. The key parameter proposed to understand their behavior is the external surface area of the nodules, which corresponds to the surface of the meso/macropores. [less ▲]

Detailed reference viewed: 81 (12 ULg)
Full Text
Peer Reviewed
See detailStructured carbons as supports for hydrogenation hybrid catalysts prepared by the immobilization of a Rh diamine complex
Gheorghiu, Cristina; Garcia-Bordeje, Enrique; Job, Nathalie ULg et al

in Chemical Engineering Journal (2016), 291

Detailed reference viewed: 49 (8 ULg)
Full Text
Peer Reviewed
See detailFuel cell electrodes from organometallic platinum precursors: an easy atmospheric plasma approach
Merche, Delphine; Dufour., Thierry; Baneton, Joffrey et al

in Plasma Processes and Polymers (2016), 13

Detailed reference viewed: 52 (8 ULg)
Full Text
See detailPt-Ni Hollow Nanoparticles for Oxygen Reduction Reaction : Controlling the Nanoparticle Morphology
Asset, Tristan ULg; Zubiaur, Anthony ULg; Chattot, Raphael et al

Poster (2015, September 13)

Detailed reference viewed: 35 (2 ULg)
Full Text
Peer Reviewed
See detailA new design of organic radical batteries (ORBs): carbon nanotube buckypaper electrode functionalized by electrografting
Aqil, Abdelhafid ULg; Vlad, Alexandru; Piedboeuf, Marie-Laure ULg et al

in Chemical Communications (2015), 51(45), 9301-9304

A novel hybridmaterial displaying a fast and reversible charge storage capability is prepared by electrografting of an alkoxyamine-bearing acrylate onto a carbon nanotube buckypaper, followed by the quan ... [more ▼]

A novel hybridmaterial displaying a fast and reversible charge storage capability is prepared by electrografting of an alkoxyamine-bearing acrylate onto a carbon nanotube buckypaper, followed by the quan- titative generation of an electroactive polynitroxide. [less ▲]

Detailed reference viewed: 68 (14 ULg)
Full Text
Peer Reviewed
See detailInfluence of the textural parameters of resorcinol–formaldehyde dry polymers and carbon xerogels on particle sizes upon mechanical milling
Piedboeuf, Marie-Laure ULg; Léonard, Alexandre ULg; Traina, Karl et al

in Colloids and Surfaces A : Physicochemical and Engineering Aspects (2015), 471

Porous carbons find various applications in catalysis, electrochemical storage or sorption. Prior to use, their particle sizes need however to be controlled according to the targeted application. In this ... [more ▼]

Porous carbons find various applications in catalysis, electrochemical storage or sorption. Prior to use, their particle sizes need however to be controlled according to the targeted application. In this study, the grinding behavior of materials prepared from aqueous resorcinol–formaldehyde mixtures and displaying different pore textures was studied in detail. Both dry polymer gels and pyrolyzed carbon xerogels were compared in terms of particle size distributions after planetary ball-milling. The results show that the pore texture and the qualitative hardness of the materials have a strong influence on the grinding behavior, especially if carbon xerogels pyrolyzed before grinding are considered. On the other hand, it appears that the milling of polymer gels, followed by a pyrolysis step, is the most efficient way to obtain homogeneous particle size distributions, for all of the investigated mesopore textures. In this case, carbon particles displaying a narrow grain size distribution centered on a mode value near 10 μm are successfully obtained after similar grinding durations, with retention of the mesopore texture of the starting materials. This work also demonstrates the possibility of using mercury intrusion porosimetry as an interesting tool to assess simultaneously the mesopore dimensions and the particle sizes of porous powders. [less ▲]

Detailed reference viewed: 44 (2 ULg)
Full Text
Peer Reviewed
See detailCorrelation between morphology and electrical conductivity of dried and carbonized multi-walled carbon nanotube/resorcinol–formaldehyde xerogel composites
Haghgoo, M.; Yousefi, A. A.; Mehr, M. J. Z. et al

in Journal of Materials Science (2015), 20

Detailed reference viewed: 88 (17 ULg)
Full Text
Peer Reviewed
See detailDevelopment of novel SOlid Materials for high power Li polymer BATteries (SOMABAT). Recyclability of components.
Zubizarreta, Leire; Gil-Agusti, Mayte; Garcia. et al

in Briec, E.; Müller., B. (Eds.) Electric Vehicle Batteries: Moving from Research towards Innovation. Lecture notes on mobility (2015)

Detailed reference viewed: 61 (4 ULg)
Full Text
Peer Reviewed
See detailDesign of Pt/carbon xerogel catalysts for PEM fuel cells
Job, Nathalie ULg; Lambert, Stéphanie ULg; Zubiaur, Anthony ULg et al

in Catalysts (2015), 5

Detailed reference viewed: 27 (5 ULg)
Full Text
Peer Reviewed
See detailA facile and fast electrochemical route to produce functional few-layer graphene sheets for lithium battery anode application
Ouhib, Farid ULg; Aqil, Abdelhafid ULg; Thomassin, Jean-Michel ULg et al

in Journal of Materials Chemistry A (2014), 2(37), 15298-15302

A simple approach for the production of polymer functionalized graphene nanosheets is reported. The resulting polyacrylonitrile chemisorbed on graphene sheets is made of 1 to 2 layers, with a large ... [more ▼]

A simple approach for the production of polymer functionalized graphene nanosheets is reported. The resulting polyacrylonitrile chemisorbed on graphene sheets is made of 1 to 2 layers, with a large majority of graphene single-layers. This novel functionalized graphene exhibits good cycling stability as an anode in Li-ion batteries without a conductive additive or binder. [less ▲]

Detailed reference viewed: 56 (11 ULg)
Full Text
Peer Reviewed
See detailResorcinol-Formaldehyde Carbon Xerogels as Lithium-Ion Battery Anodes: Synthesis, Grinding, Coating on current collector and Electrochemical characterization
Piedboeuf, Marie-Laure ULg; Léonard, Alexandre ULg; Pirard, Jean-Paul ULg et al

Poster (2014, July 17)

Rechargeable lithium-ion batteries show great advantages over traditional batteries and are extensively used for consumer electronic devices due to their high energy density and long cycle life. However ... [more ▼]

Rechargeable lithium-ion batteries show great advantages over traditional batteries and are extensively used for consumer electronic devices due to their high energy density and long cycle life. However, the improvement of performance of current lithium-ion batteries requires the optimization of the materials used (electrolyte and electrodes). Therefore, tremendous efforts have been dedicated to exploring new materials with high capacity, excellent cycling performance, low cost and high safety features [1-4]. As an example, carbon xerogels are promising candidates in the development of new high performance C-based anode materials for Li-ion batteries, since such carbonaceous materials show very small changes of volume during the charge/discharge process, providing an improved cycle life. Nevertheless, hard carbons also exhibit quite high irreversible capacity losses due to their intrinsic high microporosity and, compared to graphite, a poor rate performance related to slow diffusion of Li in the internal structure [5-6]. To reduce these disadvantages, the structural and textural characteristics need to be carefully controlled. Also, due to the different morphology of these materials compared to graphite, the deposition of carbon xerogels on current collectors needs to be studied in detail. In this work, porous carbon xerogels were synthetized from Resorcinol-Formaldehyde mixtures by adjusting the pH of the solution in order to obtain different mesopore sizes. Monoliths of carbon xerogels were obtained after drying of the polymer gel and pyrolysis [7]. Mercury intrusion porosimetry and nitrogen adsorption techniques (BET) was used to characterize the pore texture of the carbon xerogels. These monoliths were ground to particles around 10 µm for all the samples. The resulting powders were then mixed with a binder and a solvent to form slurries and then cast on copper foil using a bar coater. After evaporation of the solvent, the resulting coatings were analyzed using scanning electron microscopy (SEM) for the morphology and their thickness was monitored by profilometry. The resulting electrodes were subjected to electrochemical characterization. Since the particle sizes and the method of coating was the same for all the samples, it was possible to evaluate selectively the influence of the textural and structural parameters of the different carbon materials on their performances. Electrochemical characterizations were performed using charge-discharge galvanostatic curves and cyclic voltammetry in Li/C half cells between 0.005 and 1.5 V vs. Li+/Li. References 1) Goodenough J.B., Kim Y. J. Power Sources 2011; 196(16): 6688-6694. 2) Bruce P.G. Solid State Ionics 2008; 179: 752-760. 3) Armand M., Tarascon J.-M., Nature 2008; 451: 652-657. 4) Scrosati B., Garche J., J. Power Sources 2010 ; 195 : 2419-2430. 5) Yuan X., Chao Y.-J., Ma Z.-F., Deng X., Electrochemistry Communications 2007 ; 9 : 2591-2595. 6) Zanto E.J., Ritter J.A., Popov B.N., Proceedings - Electrochemical Society 1999; 98-16: 71-8. 7) Job N., Théry A., Pirard R., Marien J., Kocon L., Rouzaud J., Béguin F., Pirard J. Carbon 2005; 43: 2481-2494. [less ▲]

Detailed reference viewed: 146 (9 ULg)
Full Text
See detailSynthesis of Pt/Carbon Xerogel Electrocatalysts for PEM Fuel Cells by the Multiple SEA Method
Zubiaur, Anthony ULg; Chatenet, Marian; Maillard, Frédéric et al

Poster (2014, July)

Detailed reference viewed: 41 (6 ULg)