References of "Jacquet, Nicolas"
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See detailComprehension of an organosolv process for lignin extraction on Festuca arundinacea and monitoring of the cellulose degradation
Schmetz, Quentin ULg; Maniet, Guillaume ULg; Jacquet, Nicolas ULg et al

in Industrial Crops and Products (2016), 94

It is commonly accepted that the current society needs to partially substitute fossil resources by renewable ones. Among many solutions, one approach consists in the development of biorefinery involving ... [more ▼]

It is commonly accepted that the current society needs to partially substitute fossil resources by renewable ones. Among many solutions, one approach consists in the development of biorefinery involving lignocellulosic biomass to produce bio-based materials and fuels. This study focuses on the comprehension of an organosolv treatment designed to break the complex lignocellulosic structure for high purity lignin extraction from tall fescue (Festuca arundinacea Schreb.). This grass benefits from an increasing interest in Western Europe and has been suggested as feedstock for biorefinery. However, its use as material for high purity lignin production has not been determined yet. Ethanol/water, 92/8% [v/v] with H2SO4 0.32 M was investigated at pilot scale under conventional heating (5 °C min−1 during 30 min and stabilized at 148 °C for 5 min). Precipitated lignin were analyzed as well as the composition of side-stream products (recovered cellulosic pulp and the aqueous hydrolysate). Lignin has been recovered at a purity level of 90% with a yield of 60%. The main contaminants were nitrogen containing compounds and degraded hemicelluloses. 2D-HSQC NMR (Two Dimension-Heteronuclear Single Quantum Correlation Nuclear Magnetic Resonance) revealed a co-extraction of ferulates and coumarates function as well as arabinoxylan. Cellulose was recovered at 53% purity with 60% yield. The conditions appear to be too harsh for tall fescue and led to significant amount of cellulose degradation. A process using a lower alcohol concentration will be developed to provide better yields of both cellulose and lignin. [less ▲]

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See detailHydrocracking and ionic liquids pretreatments effects on aldehydes extraction and lignin modification of Arabidopsis and Sorghum
Jacquet, Nicolas ULg; Richel, Aurore ULg

Scientific conference (2016, November 16)

Study shown the effect of hydrocracking and ionic liquids pretreatments on aldehydes extraction and physico-chemical properties modification of model ligninfrom Arabidopsis and Sorghum. Result of the ... [more ▼]

Study shown the effect of hydrocracking and ionic liquids pretreatments on aldehydes extraction and physico-chemical properties modification of model ligninfrom Arabidopsis and Sorghum. Result of the study show various effect of the pretreatment on the molecular weight of lignin and make links between pretratment applied and chemical links between lignin monomers. [less ▲]

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See detailThermochemical conversion of sugar industry by-products to biofuel
Nicodème, Thibault ULg; Jacquet, Nicolas ULg; Richel, Aurore ULg

Poster (2016, October 24)

Poster concernant la conversion des co-produits de l'industrie sucrière en biocarburants via la voie thermochimique. Description des procédés tels que la gazéification, Fischer-Trospch, la pyrolyse.

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See detailHoney polyphenols extraction: method development and evidence of cis isomerization
Istasse, Thibaut ULg; Jacquet, Nicolas ULg; Berchem, Thomas ULg et al

in Analytical Chemistry Insights (2016), 11

Honey polyphenols have been studied with the objective of relating honeys to their floral sources. Initially synthesized by plant, these polyphenols can be found in the plant’s nectar, where they are ... [more ▼]

Honey polyphenols have been studied with the objective of relating honeys to their floral sources. Initially synthesized by plant, these polyphenols can be found in the plant’s nectar, where they are collected by bees which convert the nectar into honey. Consequently, polyphenols constitute minor honey components. The development of a solid phase extraction method for honey polyphenols is presented herein. The technique employs Amberlite XAD-2 adsorbent and was tested on monofloral honeys from six different plants: acacia, chestnut, eucalyptus, thyme, sunflower and wild carrot. Analyses were performed using high performance liquid chromatography coupled with UV detection and mass spectrometry. Several phenolic acids and flavonoids were identified: caffeic and p-coumaric acids, quercetin, kaempferol, naringenin, chrysin and pinocembrin. Generally, the quantity of a given polyphenol in the honey was around 0.2 mg/100g of honey, except for chestnut honey which contained around 3.0 mg of p-coumaric acid/100g of honey. Analyses highlighted significant formation of cis isomers for phenolic acids during the extraction despite protection from light. [less ▲]

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See detailNovel butanol pretreatment significantly improves delignification and saccharification of different lignocellulosic biomasses
Schmetz, Quentin ULg; Teramura, Hiroshi; Jacquet, Nicolas ULg et al

Poster (2016, July 07)

Organosolv pretreatment using diluted acid and butanol allows the separation of cellulose, hemicelluloses and lignin into three distinct phases. The butanol process has been investigated on six different ... [more ▼]

Organosolv pretreatment using diluted acid and butanol allows the separation of cellulose, hemicelluloses and lignin into three distinct phases. The butanol process has been investigated on six different biomasses: tall fescue, sugarbeet pulp, sugarcane bagasse, beech wood, eucalyptus and Japanese cedar. Dilute acid pretreatment has been performed under similar conditions for comparison. [less ▲]

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See detailEtude de la composition chimique de Pseudotsuga menziesii (Mirb.) Franco et évaluation de l’impact de divers prétraitements lignocellulosiques sur l’extraction de la lignine
Berchem, Thomas ULg; Schmetz, Quentin ULg; Jacquet, Nicolas ULg et al

Poster (2016, July 06)

La raréfaction des ressources fossiles est une certitude à l’heure actuelle. Il est donc primordial de trouver des voies de production plus durables pour des produits de consommation courante. Le ... [more ▼]

La raréfaction des ressources fossiles est une certitude à l’heure actuelle. Il est donc primordial de trouver des voies de production plus durables pour des produits de consommation courante. Le bioraffinage fait partie des solutions envisagées pour substituer les matériaux originaires de la filière pétrochimique. Dans cette optique, ce travail se focalise sur l’extraction et la caractérisation de la lignine à partir d’une biomasse présente en abondance en région Wallonne, Pseudotsuga menziesii (Mirb.) Franco (Douglas). Ce travail vise à montrer l’impact de divers prétraitements lignocellulosiques, tant en terme de rendements et de pureté d’extraction qu’au niveau de la modification de la structure et des propriétés des lignines. Ces différents paramètres sont évalués par des techniques gravimétriques (Klason), chromatographiques (chromatographie d’exclusion stérique) et spectroscopiques (RMN 2D HSQC). Pseudotsuga menziesii (Mirb.) Franco a été préalablement caractérisé par son taux de matière lignocellulosique (cellulose, hémicelluloses, lignine), ainsi que sa teneurs en cendres, en protéines et en extractibles (à l’eau et à l’éthanol). Les lignines natives ont été caractérisées par RMN 2D HSQC. [less ▲]

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See detailOptimisation de la production d’acide furan-2,5-dicarboxylique à partir de déchets verts pour la conception de plastiques bio-basés
Istasse, Thibaut ULg; Jacquet, Nicolas ULg; Richel, Aurore ULg

Poster (2016, July 06)

Afin de trouver des alternatives renouvelables aux produits issus de l’industrie pétrochimique, de nombreuses voies de recherches ont été explorées. Une voie prometteuse est la technologie des dérivés ... [more ▼]

Afin de trouver des alternatives renouvelables aux produits issus de l’industrie pétrochimique, de nombreuses voies de recherches ont été explorées. Une voie prometteuse est la technologie des dérivés furaniques. Parmi ces composés, le 5-hydroxyméthylfurfural (5-HMF) fait partie des molécules plateformes les plus importantes1. Il s’agit d’un produit de dégradation obtenu par déshydratation des hexoses2,3. Le 5-HMF peut servir de base à la conception de nombreuses molécules valorisables comme l’acide furan-2,5-dicarboxylique dont la structure proche de l’acide téréphtalique permet des applications dans la conception de polymères bio-basés3. L’acide furan-2,5-dicarboxylique respecte la législation REACH selon l’European Chemicals Agency4. Un rapport de l’EFSA de 2014 a démontré que cette substance ne posait pas de problème de toxicité lors de son utilisation comme monomère de base dans les plastiques d’emballage pour aliments5. Selon la société Avantium, le FDCA peut être utilisé pour produire un plastique entièrement bio-basé, le polyéthylène furanoate (PEF), qui affiche des performances supérieures à celle du poléthylène téréphtalate (PET) en termes de stabilité thermique, de propriétés mécaniques et de perméabilité aux gaz6. Si le FDCA peut être convertit en de nombreux produits à haute valeur ajoutée, il existe toutefois un frein majeur à son exploitation industrielle : son précurseur, le 5-HMF, n’est pas encore produit en grande quantité1. Ce problème est dû principalement à la déshydratation non sélective des sucres de la biomasse qui aboutit à de nombreux autres produits que le 5-HMF. La première difficulté à surmonter est donc la mise au point d’un procédé permettant de déshydrater de manière efficace et sélective les sucres de la biomasse. Le 5-HMF est également peu stable en milieu acide où il se décompose en acide formique et en acide lévulinique2. L'enjeu du projet de recherche présenté est donc l’optimisation de la production de 5-HMF à partir d’un ou plusieurs types de biomasses dans un premier temps, puis l’optimisation de la conversion du 5-HMF produit en FDCA. Les paramètres à prendre en compte sont notamment les sources de biomasse, l’efficacité des prétraitements concernant l’extraction des sucres, la sélectivité et l’efficacité de la conversion de ces sucres en 5-HMF (système mono- ou biphasique), l’étude de divers catalyseurs, le coût des traitements, etc… [less ▲]

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See detailIdentifying wheat varieties with low acrylamide potential
Lecart, Brieuc ULg; Jacquet, Nicolas ULg; Anseeuw, Laurent et al

Poster (2016, July 05)

Maillard reactions are responsible for the formation of many compounds in food that have been baked at temperatures above 120°C1. Some of these compounds are sought for their contribution to the ... [more ▼]

Maillard reactions are responsible for the formation of many compounds in food that have been baked at temperatures above 120°C1. Some of these compounds are sought for their contribution to the organoleptic qualities of food but others, such as acrylamide, have been identified since 1986 as reprotoxic, genotoxic and carcinogenic in animals2. Synthesized from a chain reaction between free sugars and free asparagine, acrylamide has been found in many food such as products prepared from wheat flour1,3,4. The correlation between the amount of free sugars and free asparagine in raw food with the acrylamide content in the baked food has been well documented5. For this reason we compared the levels of 15 wheat varieties and identified wheat varieties with significantly lower level (=0.05) in acrylamide precursors. Those varieties could therefore be used preferentially in products intended for food. [less ▲]

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See detailAssaying asparagine content in a complex matrix using a spectrophotometric method
Lecart, Brieuc ULg; Jacquet, Nicolas ULg; Anseeuw, Laurent et al

Poster (2016, June 23)

In this study we show, on 15 wheat varieties, the ability to assay the asparagine content in a complex matrix such as wheat flour by a simple spectrophotometric assay. This method is easier, faster and ... [more ▼]

In this study we show, on 15 wheat varieties, the ability to assay the asparagine content in a complex matrix such as wheat flour by a simple spectrophotometric assay. This method is easier, faster and cheaper than conventional chromatography analysis and allow to discriminate quickly which materials has high or low level of this amino acid. Asparagine is an amino acid present in free form in the food biomass and has the property of reacting with the free sugars during the Maillard reactions that occur during baking at temperatures above 120°C. The Acrylamide resulting from this reaction chain has been identified as reprotoxic, genotoxic and carcinogenic in animals since 1986. The present method allowed us to identify wheat varieties with significantly lower or higher asparagine contents (α=0.05). Therefore, this method can be used to identify wheat varieties or other plants with low asparagine content to use preferentially in products designed for food. [less ▲]

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See detailLignin as a bio-based flame retardant additive: Pretreatments overview
Istasse, Thibaut ULg; Jacquet, Nicolas ULg; Richel, Aurore ULg

Poster (2016, June 12)

Lignin is a cross-linked phenol polymers from plant cells wall and is the third most abundant organic material after cellulose and hemicelluloses. This substance was studied as a flame retardant for ... [more ▼]

Lignin is a cross-linked phenol polymers from plant cells wall and is the third most abundant organic material after cellulose and hemicelluloses. This substance was studied as a flame retardant for various polymers and represents an interesting opportunity to create more eco-friendly and safer plastics and resins. This poster explains one potential technology to extract lignin: the organosolv treatment. [less ▲]

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See detailLa légistation REACH: une opportunité d’innovation pour l’économie biobasée
Schmetz, Quentin ULg; Istasse, Thibaut ULg; Jacquet, Nicolas ULg et al

Scientific conference (2016, May 12)

Cet exposé fait le point sur les tendances en cours dans ce secteur au travers de divers cas concrets tels que la substitution de retardateur de flamme, plastifiant et surfactant par des alternatives ... [more ▼]

Cet exposé fait le point sur les tendances en cours dans ce secteur au travers de divers cas concrets tels que la substitution de retardateur de flamme, plastifiant et surfactant par des alternatives issues du végétale. Il aborde également les différents programmes de recherche réalisés au laboratoire de Chimie Biologique Industrielle de Gembloux Agro-Bio Tech qui ont permis le développement de nouvelles substances biobasées en accord avec une chimie plus durable et répondant aux exigences de REACH. [less ▲]

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See detailPRODUCTION OF BIOFUELS AND BIOBASED COMPOUNDS IN URBAN BIOREFINERIES: A STRATEGY TO MANAGE WASTE IN WALLONIA?
Richel, Aurore ULg; Haubruge, Eric ULg; Jacquet, Nicolas ULg

Conference (2016, May)

“Urban biorefining” is an original concept aiming at using urban wastes (household wastes, municipal wastes, industrial liquid and/or solid residues and side-products, etc.), mainly of vegetal origin, for ... [more ▼]

“Urban biorefining” is an original concept aiming at using urban wastes (household wastes, municipal wastes, industrial liquid and/or solid residues and side-products, etc.), mainly of vegetal origin, for the production of an array of biofuels and bioproducts. This “urban biorefining” concept fits particularly with the economic, geographic and politic contexts and constraints of the Walloon Region (south part of Belgium). Indeed, Walloon Region is a very small territory (area of about 6,504 sq mi) with a temperate climate. Supply feedstock, mainly arising form forestry and agriculture, are thus rather restricted, submitted to importation, and subjected to non-standardized quality. Several examples of our regional strategy, still available on an industrial scale, are herein proposed and detailed. [less ▲]

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See detailNovel butanol pretreatment significantly improves delignification and saccharification of different lignocellulosic biomasses
Schmetz, Quentin ULg; Teramura, Hiroshi; Jacquet, Nicolas ULg et al

Conference (2016, April 05)

Organosolv pretreatment using diluted acid and butanol allows the separation of cellulose, hemicelluloses and lignin into three distinct phases. The butanol process has been investigated on six different ... [more ▼]

Organosolv pretreatment using diluted acid and butanol allows the separation of cellulose, hemicelluloses and lignin into three distinct phases. The butanol process has been investigated on six different biomasses: tall fescue, sugarbeet pulp, sugarcane bagasse, beech wood, eucalyptus and Japanese cedar. Dilute acid pretreatment has been performed under similar conditions for comparison. [less ▲]

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See detailLa Chimie Biologique Industrielle à Gembloux Agro-Bio Tech
Berchem, Thomas ULg; Istasse, Thibaut ULg; Schmetz, Quentin ULg et al

Conference given outside the academic context (2016)

Présentation du laboratoire de Chimie Biologique Industrielle et illustration de nos principales activités; point sur les recherches de trois jeunes doctorants. Leur travail consiste en la valorisation de ... [more ▼]

Présentation du laboratoire de Chimie Biologique Industrielle et illustration de nos principales activités; point sur les recherches de trois jeunes doctorants. Leur travail consiste en la valorisation de matrices biologiques (déchets agricoles, industriels et forestiers,...) pour produire une gamme de nouveaux produits, biocarburants ou molécules chimiques. [less ▲]

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See detailLa législation REACH: une opportunité d’innovation pour l’économie biobasée
Schmetz, Quentin ULg; Richel, Aurore ULg; Jacquet, Nicolas ULg et al

Conference (2016, January 20)

REACH is the acronym given to the integrated legislative system for the recording, evaluation, authorization and restriction of chemicals introduced by the European Union. The aim of REACH is to improve ... [more ▼]

REACH is the acronym given to the integrated legislative system for the recording, evaluation, authorization and restriction of chemicals introduced by the European Union. The aim of REACH is to improve and ensure health and environmental protection while boosting competitiveness and innovation in the European chemicals industry. This system thus strongly encourages the transition to a biobased economy by encouraging the development and the operation of production patterns and new substitutes greener for the environment and health. Biotechnological production pathways, including the use of renewable raw materials have thus been developed over the past decade in the industry, and this trend is confirmed for the coming years. This presentation provides an update on current trends in this sector through various concrete cases such as flame retardant, plasticizer and surfactant substituted by alternatives from the vegetal. It also discusses the various research programs carried out in the Laboratory of Biological and Industrial Chemistry of Gembloux Agro-Bio Tech that allowed the development of new biobased substances consistent with a more sustainable chemistry and meeting REACH requirements. [less ▲]

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See detailProduction de nanocellulose à partir de pâte à papier: Hydrolyse enzymatique et valorisation des coproduits dans une stratégie de bioraffinage forestier intégré
Bombeck, Pierre-Louis ULg; Richel, Aurore ULg; Jacquet, Nicolas ULg et al

Conference (2016, January 19)

Présentation succincte de la thématique de recherche doctorale et de son contexte

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See detailEtude du potentiel des sous-produits vinicoles pour des applications à haute valeur ajoutée
Berchem, Thomas ULg; Jacquet, Nicolas ULg; Richel, Aurore ULg

Conference (2016, January 19)

Grape growing is one of the largest crops around world. Grape pomaces seem to be an interesting source of bio-based molecules but, despite this potential, these byproducts are untapped. Their uses are ... [more ▼]

Grape growing is one of the largest crops around world. Grape pomaces seem to be an interesting source of bio-based molecules but, despite this potential, these byproducts are untapped. Their uses are limited to poor value added applications like composting, agricultural spreading or bioethanol. This work focuses on high value added valorisation possibilities of grape pomace. It takes part in the current trend of using natural bioactive molecules in pharmaceutical, cosmetic or food industry, through the extraction of polyphenols. Firstly, chemical characterization is performed on grape pomace from two grape varieties (Cabernet sauvignon and Pinot noir) in order to determine variability. Secondly, the same approach is applied to grape seeds and skins. Finally, a method of extraction of polyphenols is developed. Results shown in this work tend to indicate a high valorisation potential of grape pomace thank to the identification of compounds like bioactive molecules and especially polyphenols (0.7% in seeds and 0.4% in skins) as well as high concentrations of other compounds in seeds (lignin (43-53%), grape oil (12%), proteins (12%)) and in skins (lignin (20%), tartaric acid (4%), proteins (10%)) of which the valorisation potential from wine-making byproducts needs to be explored. [less ▲]

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See detailProduction of biofuels from Brazil’s sugarcane bagasse via thermochemical pathway. A review
Nicodème, Thibault ULg; Jacquet, Nicolas ULg; Richel, Aurore ULg

Conference (2016)

Document décrivant la production de biocarburants à partir de la bagasse de canne à sucre par la voie thermochimique. Des techniques telles que la gazéification, le procédé Fischer-Tropsch ou la pyrolyse ... [more ▼]

Document décrivant la production de biocarburants à partir de la bagasse de canne à sucre par la voie thermochimique. Des techniques telles que la gazéification, le procédé Fischer-Tropsch ou la pyrolyse sont décrites. [less ▲]

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See detailMonitoring the laccase reaction of vanillin and poplar hydrolysate
Sòti, Valentin; Jacquet, Nicolas ULg; Apers, Sandra et al

in Journal of Chemical Technology & Biotechnology (2016), 91(6), 1914-1922

BACKGROUND: Laccase is an intensively researched enzyme for industrial use. Except for decolorisation measurements, HPLC analysis is the conventional method for monitoring the phenolic removal during ... [more ▼]

BACKGROUND: Laccase is an intensively researched enzyme for industrial use. Except for decolorisation measurements, HPLC analysis is the conventional method for monitoring the phenolic removal during laccase enzyme reaction. This paper reports an investigation of the continuous UV absorbance follow-up of the laccase reaction with steam pretreated poplar hydrolysate. RESULTS: Vanillin was used as a model substrate and lignocellulose xylose rich fraction (XRF) as a biologically complex substrate for laccase detoxification. The reaction was followed by HPLC-UV as well as by UV spectrometric measurements. Results suggest that the reaction can be successfully monitored by measuring the change of UV absorbance at 280 nm, without previous compound separation. In case of XRF experiments the spectrophotometric follow-up is especially useful, as HPLC analysis takes a long time and provides less information than in case of single substrates. The method seems to be suitable for optimization and process control. CONCLUSION: The obtained results can help to construct a fast, easy and straightforward monitoring system for laccase-phenolic substrate reactions. [less ▲]

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See detailCharacterization of saccharides released during an in vitro pepsin-pancreatin digestion of corn flour using HPAEC-PAD
Odjo, Djosse Psijus Sylvanus ULg; Bera, François ULg; Jacquet, Nicolas ULg et al

in Stärke = Starch (2016), 68

Saccharides released after an in vitro pepsin-pancreatin digestion of corn flour were quantified and characterized using high-performance anion-exchange chromatography coupled with a pulsed amperometric ... [more ▼]

Saccharides released after an in vitro pepsin-pancreatin digestion of corn flour were quantified and characterized using high-performance anion-exchange chromatography coupled with a pulsed amperometric detector (HPAEC-PAD) and two colorimetric approaches (glucose oxidase/ peroxidase assay and the 3,5-dinitrosalicylic acid assay). HPAEC-PAD revealed five major saccharides as the result of in vitro pepsin-pancreatin digestion of corn grain: glucose, isomaltose, maltose, maltotriose, and glucosyl-maltotriose. Concentrations of glucose released as measured by the three methods assessed are similar when the in vitro pepsin-pancreatin digestion is followed by post incubation with amyloglucosidase. This post incubation unfortunately leads to a loss of information about the degree of polymerization of oligosaccharides that can impact their absorption through intestinal tract. HPAEC-PAD gives both qualitative and quantitative information and then seems more suitable for a nutritional appreciation of the digestion of starchy feedstuffs. [less ▲]

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