References of "Hermans, Sophie"
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See detailPhosphine- and ammonium-functionalized ordered mesoporous carbons as supports for cluster-derived metal nanoparticles
Vidick, Deborah; Léonard, Alexandre ULg; Poleunis, Claude et al

in Catalysis Today (2014), 235

An ordered mesoporous carbon (OMC) was functionalized with ammonium or chelating phosphine ligands. In both cases, the functionalization procedure started by oxidation by nitric acid treatment, followed ... [more ▼]

An ordered mesoporous carbon (OMC) was functionalized with ammonium or chelating phosphine ligands. In both cases, the functionalization procedure started by oxidation by nitric acid treatment, followed by activation of surface carboxylic acid groups with thionyl chloride, then formation of amide bonds with diamines. The pendant amine groups were then either quaternized or further reacted with phosphine. The introduced functions were used as anchors for molecular mixed-metal clusters. These organometallic grafted species could then be thermally transformed into hetero-metallic nanoparticles (NP) embedded within the mesoporous framework. The NP/OMC nanocomposites could find application in hydrogenation, heterogeneous catalysis or as electrodes in fuel cells. [less ▲]

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See detailFunctionalization of carbon xerogels for the preparation of palladium supported catalysts applied in sugar transformations
Mager, Nathalie; Meyer, Nathalie; Léonard, Alexandre ULg et al

in Applied Catalysis B : Environmental (2014), 148-149

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See detailComparison of functionalized carbon nanofibers and multi-walled carbon nanotubes as supports for Fe-Co nanoparticles
Vidick, Deborah; Herlitschke, Marcus; Poleunis, Claude et al

in Journal of Materials Chemistry A (2013), 1(6), 2050-2063

Multi-walled carbon nanotubes (MWCNT) and nanofibers (CNF) have been functionalized at their surfaces with chelating phosphine (PPh2) and ammonium (NMe3+) groups, as anchoring sites for metal complexes ... [more ▼]

Multi-walled carbon nanotubes (MWCNT) and nanofibers (CNF) have been functionalized at their surfaces with chelating phosphine (PPh2) and ammonium (NMe3+) groups, as anchoring sites for metal complexes. The surface functionalization has been monitored by XPS, elemental analyses, N-2 physisorption and/or SEM surface morphology analysis at each step. Bimetallic Fe-Co nanoparticles from two different starting cluster complexes, [HFeCo3(CO)(12)] (1) and (NEt4)[FeCo3(CO)(12)] (2), have been deposited onto the surfaces of the functionalized MWCNT and CNF as well as their pristine forms for comparison. The samples have been fully characterized before and after thermal treatment. The obtained nanoparticles were shown by TEM to be better dispersed and of smaller size on functionalized than on pristine supports. Magnetic characterization revealed blocked superparamagnetic Fe-Co nanoparticles together with paramagnetic ions on CNF as well as MWCNT. [less ▲]

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See detailEfficient Pt/carbon electrocatalysts for Proton Exchange Membrane fuel cells: avoid chloride-based Pt salts !
Job, Nathalie ULg; Chatenet, Marian; Berthon-Fabry, Sandrine et al

in Journal of Power Sources (2013), 240

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See detailKinetics and diffusional limitations in nanostructured heterogeneous catalyst with controlled pore texture
Pirard, Sophie ULg; Hermans, Sophie; Devillers, Michel et al

Poster (2011, September)

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See detailKinetics and diffusional limitations in nanostructured heterogeneous catalyst with controlled pore texture
Pirard, Sophie ULg; Diverchy, Chantal; Hermans, Sophie et al

in Catalysis Communications (2011), 12

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See detailSynthesis and characterization of highly loaded Pt/carbon xerogel catalysts prepared by Strong Electrostatic Adsorption method
Job, Nathalie ULg; Maillard, Frédéric; Chatenet, Marian et al

in Studies in Surface Science and Catalysis (2010), 175

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See detailFunctionalization of carbon xerogels for the preparation of Pd/C catalysts by grafting of Pd complex
Diverchy, Chantal; Hermans, Sophie; Job, Nathalie ULg et al

in Studies in Surface Science and Catalysis (2010), 175

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