References of "Eshraghi, Nicolas"
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See detailUp-scalable spray-drying synthesis of Na2Ti3O7
Piffet, Caroline ULiege; Vertruyen, Bénédicte ULiege; Mahmoud, Abdelfattah ULiege et al

Poster (2017, September 07)

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See detailPreparation and characterization of Silicon-carbon composite powders using recycled Silicon from solar cells as anode material in Li-ion batteries
Eshraghi, Nicolas ULiege

Poster (2017, September)

Currently, silicon (Si) coming from the recycling of solar cells is a non-valued fraction. The principal aim of this work is the development of silicon recovered during the dismantling of solar panels as ... [more ▼]

Currently, silicon (Si) coming from the recycling of solar cells is a non-valued fraction. The principal aim of this work is the development of silicon recovered during the dismantling of solar panels as electrode material for Li-ion batteries. The main technological challenge associated with the use of silicon in this type of application is to control the volume expansion during charge/discharge cycles. This drawback could be avoided through the formation of Silicon/carbon composites in which the size of the silicon particles and their dispersion must be controlled. In this research, we develop a carbon matrix consisting of graphene or carbon nanotubes (CNT) that allow the incorporation of silicon particles coated with a carbon layer (Si@C/C). The process is divided in two main steps : I) the grinding of leached Si wafer pieces in order to extract pure Si powder and then a mixed aqueous suspension of this recycled Si and an organic carbon source (Acetic acid, Ascorbic acid or Lactose) is spray-dried followed by heat treatment to generate the coating of silicon particles with carbon (Si@C). Then, II) aqueous suspension of Si@C and graphene/CNT is spray dried and calcined to obtain the final composite structure (Si@C/C). The morphology of composite materials is analyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Electrochemical performance of Si@C/C composites are characterized by galvanostatic charge-discharge cycling and electrochemical impedance spectroscopy (EIS). [less ▲]

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See detailSodium vanadium (III) fluorophosphate/carbon nanotubes composite (NVPF/CNT) prepared by spray-drying: good electrochemical performance thanks to well-dispersed CNT network within NVPF particles
Eshraghi, Nicolas ULiege; Caes, Sebastien; Mahmoud, Abdelfattah ULiege et al

in Electrochimica Acta (2017), 228

We successfully prepared NASICON-type Na3V2(PO4)2F3 (NVPF) and a Na3V2(PO4)2F3/carbon nanotubes (CNT) composite by spray-drying followed by heat treatment in argon for 2 hours at 600 °C. The addition of ... [more ▼]

We successfully prepared NASICON-type Na3V2(PO4)2F3 (NVPF) and a Na3V2(PO4)2F3/carbon nanotubes (CNT) composite by spray-drying followed by heat treatment in argon for 2 hours at 600 °C. The addition of CNT in the spray-drying solution creates a CNT network within the NVPF particles. After grinding, the smaller NVPF particles remain linked by CNT. Thanks to this conducting network, the composite powder displays competitive electrochemical performance when cycled against lithium in hybrid-ion batteries (2–4.6 V vs. Li+/Li) with specific capacities of 125 mAh.g−1 at C/10, 103 mAh.g−1 at 1C and 91 mAh.g−1 at 4C, together with 97.5% capacity retention at 1C over 100 cycles with coulombic efficiency of 99.4%. These results demonstrate that sodium vanadium (III) fluorophosphate electrode material can be obtained in a time-efficient way using the easily up-scalable spray-drying method. [less ▲]

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See detailRECYCLING OF SILICON USED IN SOLAR CELLS TO PREPARE SILICON-CARBON COMPOSITE POWDERS AS ANODE MATERIAL IN LI-ION BATTERIES
Eshraghi, Nicolas ULiege

Poster (2017)

Currently, silicon (Si) coming from the recycling of solar cells is a non-valued fraction. The principal aim of this work is the development of silicon recovered during the dismantling of solar panels as ... [more ▼]

Currently, silicon (Si) coming from the recycling of solar cells is a non-valued fraction. The principal aim of this work is the development of silicon recovered during the dismantling of solar panels as an electrode material for lithium or sodium batteries. The main technological challenge associated with the use of silicon in this type of application is to control the volume expansion during charge/discharge cycles. This problem could be solved through the synthesis of Silicon/carbon composites in which the size of the silicon particles and their dispersion must be controlled [1–4]. We develop a carbon matrix consisting of graphene or carbon nanotubes (CNT) that allow the incorporation of silicon particles coated with a carbon layer (Si@C/C). The process is divided in two main steps. In the first step, Si wafer pieces are ground to prepare Si powder and then a mixed suspension of Si and an organic carbon source (Acetic acid, Ascorbic acid or Lactose) is spray-dried followed by heat treatment to generate the coverage of silicon particles with carbon (Si@C). In the second step, aqueous suspension of Si@C and graphene/CNT is spray dried and heat treated to obtain the final composite structure. The morphology of composite materials is analyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Electrochemical performance of Si@C/C composites are characterized by galvanostatic charge-discharge cycling and electrochemical impedance spectroscopy (EIS). [less ▲]

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See detailPhosphate-based composite electrodes for Li/Na-ion batteries: upscalable solution syntheses with in-situ solid carbon addition
Vertruyen, Bénédicte ULiege; Brisbois, Magali; Eshraghi, Nicolas ULiege et al

Conference (2016, September 22)

Since the success story of lithium iron phosphate, other phosphate-based compounds have attracted a lot of interest as promising candidates for positive electrodes in lithium-ion or sodium-ion batteries ... [more ▼]

Since the success story of lithium iron phosphate, other phosphate-based compounds have attracted a lot of interest as promising candidates for positive electrodes in lithium-ion or sodium-ion batteries. Their electronic conductivity usually has to be improved through the preparation of composite powders ensuring intimate contact between the active material and conductive carbon. We report on the one-step synthesis of composite precursors using spray-drying or hydrothermal synthesis routes, two techniques which offer easy scaling-up of production. We show that addition of a solid carbon source (carbon black or carbon nanotubes) into the solution has a strong influence on the powder microstructure and is very effective in improving the battery cycling performance, taking our recent results on phosphates [Fex(PO4)(OH)y.zH2O)] and fluorophosphates [Na2FePO4F, Na3V2(PO4)2F3] as examples. We also compare this approach with the addition of the carbon source as a soluble precursor (such as ascorbic acid or citric acid) where the in situ formation of carbon is achieved by a heat treatment in inert atmosphere (typically argon). [less ▲]

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See detailA NASICON-type material as positive electrode in Li-ion and Na-ion batteries
Eshraghi, Nicolas ULiege

Conference (2016, July 07)

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See detailA NASICON-type material as positive electrode in Li-ion and Na-ion batteries
Eshraghi, Nicolas ULiege

Poster (2016, July 07)

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See detailNa2FePO4F/multi-walled carbon nanotubes for lithium-ion batteries: Operando Mössbauer study of spray-dried composites
Brisbois, Magali; Caes, Sébastien ULiege; Sougrati, M.T. et al

in Solar Energy Materials & Solar Cells (2016), 148

In order to favor electronic conductivity in sodium iron fluorophosphate electrodes for lithium- or sodium-ion batteries, composites of Na2FePO4F with multi-walled carbon nanotubes (CNTs) were prepared by ... [more ▼]

In order to favor electronic conductivity in sodium iron fluorophosphate electrodes for lithium- or sodium-ion batteries, composites of Na2FePO4F with multi-walled carbon nanotubes (CNTs) were prepared by pilot-scale spray drying. Addition of multi-walled CNTs in the solution results in an excellent dispersion of the CNTs within the volume of Na2FePO4F and not only at the surface of the particles. Following a heat treatment at 600°C in argon in order to reach crystallization, X-ray diffraction and ex situ Mössbauer spectroscopy revealed the presence of significant amounts of Fe(III) and maghemite (γ-Fe2O3) in the powder. However, Na2FePO4F/CNTs composites exhibit good electrochemical performance when cycling against lithium, with a discharge capacity of 104mAhg-1 at C/10 rate and 90mAhg-1 at 1C rate. Therefore, operando 57Fe transmission Mössbauer spectroscopy analyses were carried out in order to investigate the evolution of the iron oxidation state during cycling. During the first discharge, all the Fe(III) is reduced to Fe(II), explaining the good electrochemical performance. [less ▲]

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See detailSpray-drying synthesis of Na3V2(PO4)2F3 as cathode material for Li/Na ion batteries
Eshraghi, Nicolas ULiege; Caes, Sébastien ULiege; Cloots, Rudi ULiege et al

Poster (2015, May 08)

In this communication, Na3V2(PO4)2F3 (NVPF) powder with a NASICON-type structure is synthesized for the first time by spray-drying method. The effects of molar ratio of precursors, inlet temperature and ... [more ▼]

In this communication, Na3V2(PO4)2F3 (NVPF) powder with a NASICON-type structure is synthesized for the first time by spray-drying method. The effects of molar ratio of precursors, inlet temperature and heat treatment temperature on the powder purity and particle morphology were investigated. Structural and microstructural characterizations were carried out by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Best electrochemical properties, from specific capacities of 94 mAh .g-1 at C/15 to 80 mAh.g-1 at 1C in li-ion batteries, were obtained for powders dried at 180°C and fired at 600°C. These preliminary results show that spray-drying technique is suitable for obtaining complex powders with a very good homogeneity leading to very good electrochemical properties. [less ▲]

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See detailSintering of grey cast iron powder recycled via jet milling
Emadi Shaibani, M.; Eshraghi, Nicolas ULiege; Ghambari, M.

in Materials and Design (2013), 47

Porous grey cast iron powder metallurgy parts were made from grey cast iron powder manufactured via target jet milling of machining scraps. The powders were used in the as-milled state without any further ... [more ▼]

Porous grey cast iron powder metallurgy parts were made from grey cast iron powder manufactured via target jet milling of machining scraps. The powders were used in the as-milled state without any further physical or heat treatment. Sintering was conducted at 1025, 1100 and 1175°C in an argon atmosphere and the effect of sintering temperature on microstructure, sintered density and apparent hardness of the grey cast iron specimens pressed to 5.8g/cm3 was investigated. Although diffusion processes were partially activated at 1025°C, it was determined that a temperature of 1175°C proved to be the ideal temperature for solid state sintering of grey cast iron parts. The hardness value and sintered density for the specimens sintered at 1175°C were found to be 96 BHN and 6.1g/cm3 (around 15% porosity) respectively, all of which lends itself to promising properties for making self-lubricating bearings and parts with sliding properties. © 2012 Elsevier Ltd. [less ▲]

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See detailProduction of grey cast iron powder via target jet milling
Ghambari, M.; Emadi Shaibani, M.; Eshraghi, Nicolas ULiege

in Powder Technology (2012), 221

Target jet milling was used for the first time to convert cast iron scraps to powder. An experimental apparatus was designed which comprised a compressor, a mixing section, a nozzle, an impact chamber and ... [more ▼]

Target jet milling was used for the first time to convert cast iron scraps to powder. An experimental apparatus was designed which comprised a compressor, a mixing section, a nozzle, an impact chamber and two suction machines. Milling parameters i.e. the target to nozzle distance, the feed rate and the impact angle were optimized through appropriate tests. The travel distance of 8. cm and the impact angle of 90° were found to be ideal parameters of milling. The effect of feed rate on production of powders greater than 45. μm was found to be opposite to the production of the fines (<. 45. μm). Investigation of the fragmentation procedure of particles revealed that, the existence of graphite flakes in cast iron matrix plays the most important role in particle breakage. © 2012 Elsevier B.V. [less ▲]

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