References of "Dufour, Fabien"
     in
Bookmark and Share    
Peer Reviewed
See detailPhotocatalytic TiO2 Macroscopic Fibers Obtained Through Integrative Chemistry
Kinadjian, Natacha ULg; Le Bechec, Mickael; Pigot, Thierry et al

Poster (2013, March)

The photocatalytic properties of titanium dioxide depend not only on its electronic properties, but also on the material size and shape, which can increase interactions between the reactants and catalyst ... [more ▼]

The photocatalytic properties of titanium dioxide depend not only on its electronic properties, but also on the material size and shape, which can increase interactions between the reactants and catalyst. Most studies to date show that reducing the particle size down to the nanoscale increases photocatalytic efficiency, as a result of a higher surface to volume ratio and because a larger proportion of the material is actually irradiated by light. We demonstrate that a multiscale shape design, which integrates surface roughness, particle shape, and 1D material processing and orientation, can favor photocatalytic properties in the solidgas regime, especially mineralization (conversion into CO2), when the hierarchical 1D orientation of the material is combined with unidirectional gas flow. Several materials with hierarchical structure were prepared and characterized. They have been tested for the photocatalytic mineralization of gaseous acetone and compared with commercial catalysts. Our study reveals that a suitable combination of multiscale design and optimization of the material orientation and gas flow favors high mineralization. [less ▲]

Detailed reference viewed: 3 (2 ULg)
Peer Reviewed
See detailPhotocatalytic TiO2 Macroscopic Fibers Obtained Through Integrative Chemistry
Kinadjian, Natacha ULg; Le Bechec, Mickael; Pigot, Thierry et al

Poster (2012, November 25)

The photocatalytic properties of titanium dioxide depend not only on its electronic properties, but also on the material size and shape, which can increase interactions between the reactants and catalyst ... [more ▼]

The photocatalytic properties of titanium dioxide depend not only on its electronic properties, but also on the material size and shape, which can increase interactions between the reactants and catalyst. Most studies to date show that reducing the particle size down to the nanoscale increases photocatalytic efficiency, as a result of a higher surface to volume ratio and because a larger proportion of the material is actually irradiated by light. We demonstrate that a multiscale shape design, which integrates surface roughness, particle shape, and 1D material processing and orientation, can favor photocatalytic properties in the solidgas regime, especially mineralization (conversion into CO2), when the hierarchical 1D orientation of the material is combined with unidirectional gas flow. Several materials with hierarchical structure were prepared and characterized. They have been tested for the photocatalytic mineralization of gaseous acetone and compared with commercial catalysts. Our study reveals that a suitable combination of multiscale design and optimization of the material orientation and gas flow favors high mineralization. [less ▲]

Detailed reference viewed: 3 (3 ULg)
Full Text
Peer Reviewed
See detailPhotocatalytic TiO2 Macroscopic Fibers Obtained Through Integrative Chemistry
Kinadjian, Natacha ULg; Le Bechec, Mickael; Pigot, Thierry et al

in European Journal of Inorganic Chemistry [=EurJIC] (2012)

The photocatalytic properties of titanium dioxide depend not only on its electronic properties, but also on the material size and shape, which can increase interactions between the reactants and catalyst ... [more ▼]

The photocatalytic properties of titanium dioxide depend not only on its electronic properties, but also on the material size and shape, which can increase interactions between the reactants and catalyst. Most studies to date show that reducing the particle size down to the nanoscale increases photocatalytic efficiency, as a result of a higher surface to volume ratio and because a larger proportion of the material is actually irradiated by light. We demonstrate that a multiscale shape design, which integrates surface roughness, particle shape, and 1D material processing and orientation, can favor photocatalytic properties in the solidgas regime, especially mineralization (conversion into CO2), when the hierarchical 1D orientation of the material is combined with unidirectional gas flow. Several materials with hierarchical structure were prepared and characterized. They have been tested for the photocatalytic mineralization of gaseous acetone and compared with commercial catalysts. Our study reveals that a suitable combination of multiscale design and optimization of the material orientation and gas flow favors high mineralization. [less ▲]

Detailed reference viewed: 3 (2 ULg)
Peer Reviewed
See detail1D Organization of ZnO and TiO2 nanoparticles toward advanced photonic and photocatalytic materials
Kinadjian, Natacha ULg; Achard, Marie-France; Julian-Lopez, Beatriz et al

Poster (2012, October)

Nowadays Chemist are request to construct more and more complex architectures bearing multifunctionalities enable to respond to external stimuli. The construction of such complex architectures will be ... [more ▼]

Nowadays Chemist are request to construct more and more complex architectures bearing multifunctionalities enable to respond to external stimuli. The construction of such complex architectures will be addressed through strong interplay in chemical science, as proposed recently with the concept of integrative Chemistry.[1] We synthesized PVA/ZnO-nanorods composite fibers using co-axial flux extrusion.[2] These fibers exhibit higher anisotropic photonic properties, both in absorption and emission, as a result of the collective alignment of the ZnO nanorods along the main axis of the PVA fiber. This photonic anisotropy is triggered by a synergistic interaction between the PVA matrix, stretched above Tg, and cooled down under strain. Compared with non-elongated fibers that present an isotropic emission, composite fibers previously submitted to a tensile stress absorb selectively UV emission when the polarized laser beam is parallel to the main axis of the fiber. In addition, their photolumincescence is also anisotropic, with a waveguide behavior along the main axis of the fiber. Mechanical properties of these composite fibers are also drastically improved, compared with pure PVA fibers: the longitudinal Young modulus of these fibers is increased from 2 to 6 GPa upon ZnO addition, a value similar to those already observed for composite fibers, prepared either with carbon nanotubes, or Vanadium Oxide macroscopic fibers. [1] N. Brun, S. Ungureanu, H. Deleuze and R. Backov. Chem. Soc. Rev., 2011, 40, 771 [2] Kinadjian, N., Achard, M.-F., Julián-López, B., Maugey, M., Poulin, P., Prouzet, E. and Backov, R. (2012). Adv. Funct. Mater.. doi: 10.1002/adfm.201200360 [less ▲]

Detailed reference viewed: 13 (2 ULg)
Full Text
Peer Reviewed
See detailSynthesis and radioligand binding studies of bis-(8-isopropylisoquinolinium) derivatives as ligands for apamin-sensitive sites on cloned SK2 and SK3 channels
Badarau, Eduard; Dilly, Sébastien ULg; Dufour, Fabien et al

in Bioorganic & Medicinal Chemistry Letters (2011), 21(22), 6756-6759

A structure-activity relationship study of N-methyl-laudanosine, a SK channel blocker, has indicated that the 6,7-dimethoxy group could be successfully replaced by a hydrophobic moiety such as an ... [more ▼]

A structure-activity relationship study of N-methyl-laudanosine, a SK channel blocker, has indicated that the 6,7-dimethoxy group could be successfully replaced by a hydrophobic moiety such as an isopropyl substituent in position 8 of the isoquinoline ring. In the present study, bis-(8-isopropyl-isoquinolinium) derivatives (2a-e) were synthesized and tested for their affinity for cloned SK2 and SK3 channels in comparison with their 6,7-dimethoxy analogues (4a-f). Several ligands were investigated, both in flexible (propyl, butyl and pentyl) and rigid (m- or p-xylyl) series, the m-xylyl derivative (2d) having the best profile in terms of affinity and selectivity for SK3/SK2 channels. Molecular studies showed that the optimal conformation of compound 2d fits well with our SK pharmacophore model. [less ▲]

Detailed reference viewed: 49 (11 ULg)