Amenability for processing of oolitic iron ore concentrate for phosphorus removalIonkov, Krassimir ; Gaydardzhiev, Stoyan ; Bastin, David et alin Minerals Engineering (2013), 46-47 Beneficiation routes aimed at dephosphorisation of oolitic gravity magnetic concentrate and involving a combination of roasting, re-grinding, magnetic separation and water and acid leaching are ... [more ▼] Beneficiation routes aimed at dephosphorisation of oolitic gravity magnetic concentrate and involving a combination of roasting, re-grinding, magnetic separation and water and acid leaching are investigated. Roasting was carried out at 900ºC for one hour without or with lime or sodium hydroxide as roasting additives. When additives were used, cement phases of Si-Al-Na-Ca-O type were detected as well as the mineral giuseppettite. During the thermal process sodium silicate is liquefied and the newly formed phases coat the oolites and penetrate inside the cracks. Energy Dispersive Spectroscopy analysis has indicated that the zone surrounding the oolites consists of Na, Al and Si phases with part of phosphorus being captured there. As a result of the alkaline roasting, goethite is partly transformed to magnetite and this reduction is reinforced with an increase in sodium hydroxide dosage. Investigation of redistribution of phosphorous shows that it could be only partly separated if leaching is not accompanied by re-grinding and physical separation. The recommended dosage of the reductive agent for the final flowsheet is 8 % mass ratio to concentrate. Grinding to a mean size of 0.040 mm, with water and acid leaching and double magnetic separation creates conditions to obtain a high-quality iron concentrate with 65.97 % Fe and recovery of 92.43 %, with simultaneous decrease in the phosphorus content from 0.71 % to 0.05 %. [less ▲] Detailed reference viewed: 13 (2 ULg) Online monitoring of the interaction of balls and slurry with the Sensomag ®; Leroy, Sophie ; Bastin, David et alPoster (2012, December 10) Presentation of Optimag Project results. Optimag aims to optimize the ball milling operations through the use of an embarked sensor, called the Sensomag, and developed by Magotteaux to monitor in real ... [more ▼] Presentation of Optimag Project results. Optimag aims to optimize the ball milling operations through the use of an embarked sensor, called the Sensomag, and developed by Magotteaux to monitor in real time the position of the slurry and the grinding balls. [less ▲] Detailed reference viewed: 15 (6 ULg) Potential for application of alkali roast acid leach technology for removal of phosphorus from iron oreIonkov, Krassimir ; Gaydardzhiev, Stoyan ; Bastin, David et alin Proceedings of 6-th International Congress on the Science and Technology of Ironmaking ICSTI (2012, October) The present study deals with the effect of sodium hydroxide and sodium carbonate used as additives during oxidizing roasting of oolitic limonite iron concentrate and more precisely upon the change in its ... [more ▼] The present study deals with the effect of sodium hydroxide and sodium carbonate used as additives during oxidizing roasting of oolitic limonite iron concentrate and more precisely upon the change in its magnetic susceptibility. Further, the efficiency of Alkali Roast Acid Leach (ARAL) technology for dephosphorisation of the concentrate is compared with the case when sodium hydroxide was added in alkali leach after roasting. The treatment without additives in roasting resulted in obtaining iron concentrate with 58 % iron and 0.21 % phosphorus, while the ARAL approach yielded concentrate with 63 % iron and 0.09 % phosphorus. The influence of combination of coke as reducing agent and sodium hydroxide in roasting at 900°C is also investigated and results displayed in 3D form. The combination of ARAL with reductive roasting, grinding of the clinker to 80 % - 0,075 mm, flotation of the non-reacted coke and magnetic separation before and after the acid leach resulted in iron concentrate with 66 % iron and 0.05 % phosphorus. The study has shown that the application of the ARAL approach with low addition of alkalis followed by 10 to 15 minute acid leaching at ambient temperature could substantially reduce phosphorus, thus offering the possibility for efficient treatment of high phosphorus iron ores. [less ▲] Detailed reference viewed: 47 (9 ULg) Removal of phosphorous through roasting of oolitic iorn ore with alkaline earth additivesIonkov, Krassimir ; Gaydardzhiev, Stoyan ; Bastin, David et alin Proceedings of the XXVI International Mineral Processing Congress (2012, September) The present study is devoted to improvement of the leaching efficiency during phosphorous removal from high phosphorous gravity-magnetic concentrate. Before leaching the concentrate has been subjected to ... [more ▼] The present study is devoted to improvement of the leaching efficiency during phosphorous removal from high phosphorous gravity-magnetic concentrate. Before leaching the concentrate has been subjected to roasting with the addition of either Ca(OH)2 or CaO. The oolitic iron ore is roasted at 900°C for one hour. This reflects in reaction between alkaline earth additive and quartz, aluminosilicates, phosphorus, and some other minor components of the gangue minerals. The application of leaching, physical separation, and wash out of salts has resulted in the decrease of phosphorus from 0.7 to 0.15 % and it is established that the major influencing factor is the concentration of acid and to a less extent duration of the leaching process. About two third of the phosphorus can be removed by roasting with 3 % CaO to hematite, coarse grinding to d50 0.3 mm, dry high intensity magnetic separation and leaching of the magnetic fraction with hydro-chloric or nitric acid. [less ▲] Detailed reference viewed: 30 (2 ULg) Optical analysis of particle size and chromite liberation from pulp samples of a UG2 ore regrinding circuitLeroy, Sophie ; ; Bastin, David et alin Minerals Engineering (2011), 24 Since the early seventies high chromite and low base metal sulphide (BMS) contents of the UG2 reef imposes technological challenges to mineral processors and extractive metallurgists. Forty years later ... [more ▼] Since the early seventies high chromite and low base metal sulphide (BMS) contents of the UG2 reef imposes technological challenges to mineral processors and extractive metallurgists. Forty years later, particle size distribution and size by size mineralogy are considered as key factors to the continuous improvement of the UG-2 ore metallurgy. With the successful development of ultra fine grinding technologies, a compromise has to be found between fine grinding to achieve platinum group minerals liberation and to avoid the overgrinding of gangue minerals, especially chromite gangue which is detrimental in smelting process. Indeed, fine chromite grains, despite of being naturally hydrophobic mineral, can be recovered in flotation concentrate by entrainment. In addition, overgrinding also increase liberation of naturally floatable gangue (talc) which contaminate the concentrate and need to be controlled during flotation. In this paper, innovative techniques of single particle image analysis from both dry and wet samples have been tentatively used to assess the chromite particle size distribution and the chromite grade of samples taken from a secondary milling circuit. Preliminary results demonstrate excellent potential for online particle imaging making use of both the particle geometry (size, shape) and the optical properties (translucency). [less ▲] Detailed reference viewed: 112 (23 ULg) Bio hydrometallurgical recovery of metals from Fine Shredder ResiduesLewis, Grégory ; Gaydardzhiev, Stoyan ; Bastin, David et alin Minerals Engineering (2011), Vol 24, Issue 11 The leaching step of an integrated hydrometallurgical process for the selective recovery of metals from polymetallic concentrates has been investigated. The concentrate has been produced by physical ... [more ▼] The leaching step of an integrated hydrometallurgical process for the selective recovery of metals from polymetallic concentrates has been investigated. The concentrate has been produced by physical treatment of Fine Shredder Residues derived from a shredding plant processing a mixed feed. Bacterially assisted leaching experiments using a copper-adapted consortium of mesophilic bacterial strains have been carried out. Various technological parameters have been studied. Under optimal conditions about 95 % extraction levels for copper and zinc have been obtained. Bacterial presence has been found beneficial in view catalysing copper dissolution. [less ▲] Detailed reference viewed: 78 (25 ULg) DEPHOSPHORIZATION OF LIMONITIC CONCENTRATE BY ROASTING, ACID LEACHING AND MAGNETIC SEPARATIONIonkov, Krassimir ; Gaydardzhiev, Stoyan ; et alin Holmes, M. (Ed.) Proceedings of the Iron Ore 2011 International Conference (2011, July) The oolitic iron ore reserves in Lisakovsky, Northwest Kazakhstan represent a quite challenging deposit both from technological and from resource point of view. The difficulties in processing such type of ... [more ▼] The oolitic iron ore reserves in Lisakovsky, Northwest Kazakhstan represent a quite challenging deposit both from technological and from resource point of view. The difficulties in processing such type of ore are connected with the extremely fine dissemination of phosphorus and gangue minerals inside the oolitic formations. The goethite crystals are cemented in their structure by aluminosilicates with quartz and other gangue minerals and dissemination is so fine that they are not separable by physical methods. The laboratory tests performed in direction of dephosphorisation have shown that the combination of alkaline roasting followed by low intensity magnetic separation and acid leaching enables the obtaining of high grade iron concentrate. The magnetic separation performed ahead of leaching has been efficient by means of buffering the high pH via washing out the soluble salts and the excess of bases and applied after leaching has facilitated the removal of secondary liberated gangue minerals in the non-magnetic fraction. As a consequence, phosphorous content has been dropped to a more acceptable for the ferrous metallurgy levels while iron grade and recovery have reached respectively 61.6 and 80.8 percent. [less ▲] Detailed reference viewed: 76 (8 ULg) Impacts of grinding media alloys composition on the flotation of mixed oxides-sulphides copper ores.; Bastin, David ![]() Conference (2011) While the influence of the grinding media alloy composition on the flotation performances of sulphide ores has been widely studied, its role in the flotation of mixed (oxide and sulphide) ores is poorly ... [more ▼] While the influence of the grinding media alloy composition on the flotation performances of sulphide ores has been widely studied, its role in the flotation of mixed (oxide and sulphide) ores is poorly documented. For some deposits, the mixed ores zone is well developed and can be of great importance for the economics of a mining project. These ore types often present technical challenges for their beneficiation such as sulphides tarnishment, slimes generation, presence of hydrophobic gangue or presence of acid consuming gangue. This study highlights the importance of matching the right grinding media alloy to the mineralogy of the ore, particularly its degree of weathering and to the subsequent flotation scheme. Shifting the grinding media towards less electrochemically active alloys significantly enhanced the grade-recovery curves and the flotation kinetics of the sulphides fraction, particularly when high degrees of sulphides oxidation were induced within the orebody or during stockpiling. For ores with high acid consuming gangue and medium acid soluble copper content that require a preconcentration of the oxide fraction by flotation through activation by sulphidisation, the higher sulphides flotation rates achieved with the use of high chromium alloys limited the amount of sulphides entering the sulphidisation stages and led to a better selectivity between acid insoluble and acid soluble copper allowing better downstream extractive metallurgy performances. [less ▲] Detailed reference viewed: 28 (4 ULg) Copper extraction from scrap cables by biotechnological meansGaydardzhiev, Stoyan ; Bastin, David ; in Proceedings of the XXV International Mineral Processing Congress (2010, September) The papaer reports on laboratory results regarding bio leaching of metallic copper from cable-bearing scraps derived from recycling of end-of-life vehicles. The copper has been met in pure form as ... [more ▼] The papaer reports on laboratory results regarding bio leaching of metallic copper from cable-bearing scraps derived from recycling of end-of-life vehicles. The copper has been met in pure form as irregular shaped wires often coated with tin. The complex nature of the material renders both gravity and physicochemical separation unsuitable for efficient copper separation. Hence a bacterially assisted leaching with mixed consortium of mesophylic microorganisms has been tested for recevery of the remaining copper. Continuous adaptation of the cultures to the substrate has been envisaged in order to guarantee sufficient degree of ferric iron regeneration by bacteria during leaching. It has been established that under optimal leaching conditions such as acid consumption, pulp density, pH and temperature, it is possible to recover nearly 98 % of the copper in solution within acceptable leaching duration. [less ▲] Detailed reference viewed: 45 (6 ULg) Biosolubilization of copper from waste electric cablesGaydardzhiev, Stoyan ; Bastin, David ; Goffinet, Florence et alin Harre, Jens (Ed.) Proceedings of the Copper 2010 International Conference (2010, June) The paper reports on results from a laboratory tests for bacterial leaching of copper from scrap cables. The studied material is a reject fraction obtained after dismantling and separation of electric ... [more ▼] The paper reports on results from a laboratory tests for bacterial leaching of copper from scrap cables. The studied material is a reject fraction obtained after dismantling and separation of electric cables during recycling of end-of-life vehicles (ELV). The copper has been met predominately in pure metallic form as tiny irregular shaped wires often coated with tin and well liberated from the plastic isolations. For bringing copper in solution, a bacterially assisted agitative leaching with mixed consortium of mesophylic microorganisms has been chosen. Continuous bacterial adaptation of the cultures to the substrate has been envisaged in order to provide an efficient way for ferrous iron regeneration during the leaching. It has been established that under optimal conditions of pH, density and temperature it is possible to recover nearly the total copper within short leach duration. The obtained pregnant leach solution could be subjected to subsequent copper recovery via solvent extraction, while the solid leached residue could be considered as non-metallic material containing plastics suitable for recycling. [less ▲] Detailed reference viewed: 86 (11 ULg) Separation of Copper and Zinc by Solvent Extraction During Reprocessing of Flotation Tailings; Gaydardzhiev, Stoyan ; Frenay, Jean et alin Separation Science & Technology (2010), 45(4), 1-6 Results from solvent extraction of copper and zinc from pregnant solutions after bioleaching of re-floated tailings from the Kipushi concentrator in DR of Congo are presented. LIX984N has been used as ... [more ▼] Results from solvent extraction of copper and zinc from pregnant solutions after bioleaching of re-floated tailings from the Kipushi concentrator in DR of Congo are presented. LIX984N has been used as extractant for copper, while D2EHPA as such for zinc, following prior removal of the ferric iron via precipitation. The McCabe-Thiele diagrams constructed for Cu and Zn extraction have theoretically suggested the need for two stages for copper and one for zinc. Stripping these metals to aqueous phase by sulphuric acid has yielded rich electrolytes with 48.5 g/L copper and 85.5 g/L zinc. Thus, copper and zinc could be further recovered from the stripped solutions by electrolysis. [less ▲] Detailed reference viewed: 201 (33 ULg) Metallurgical performances of the sulphidisation route and the direct alkylhydroxamates flotation of mixed carbonated Cu-Au ores of the Kansanshi deposit; Bastin, David ; et alConference (2009) Detailed reference viewed: 20 (1 ULg)![]() Sampling of Fine Shredder Residues (FSR) and Characterization Oriented to Physical Separations; Bastin, David ; et alin Proceedings of the Sohn International Symposium on Advanced Processing of Metals and Materials: Principles, Technologies and Industrial Practice (2006) Detailed reference viewed: 17 (4 ULg) The roles of complexing agents in the sulfidisation and xanthate flotation of cobalt oxy hydroxides of copper-cobalt oxides ores from the Congolese CopperbeltBastin, David ; Frenay, Jean ; Conference (2006) Complex mineralogy combined with a variable chemistry lead to various flotation responses of cobalt oxy-hydroxides present in oxidised and mixed copper-cobalt stratiform deposits of the Central African ... [more ▼] Complex mineralogy combined with a variable chemistry lead to various flotation responses of cobalt oxy-hydroxides present in oxidised and mixed copper-cobalt stratiform deposits of the Central African Copperbelt. Optimum metallurgical results require very high dosages of reagents and the management of such high chemicals concentrations in the pulp at the plant scale is delicate. The transition period between high reducing conditions during the sulfidisation step and a more oxidising environment prevailing during collector adsorption is particularly critical. This paper demonstrates how the use of copper and cobalt complexing agents can significantly improve the process control and metallurgical performance. The different modes of action of these reagents are presented and mechanisms for the various reactions proposed. Plant results following the introduction of ammonium sulfate at the New Concentrator of Kipushi are discussed. [less ▲] Detailed reference viewed: 32 (0 ULg)![]() Potential valorization of the fine light fraction of automotive shredder residues (ASR); Bastin, David ; Frenay, Jean ![]() in Proceedings of the International Symposium of Metals and Energy Recovery (2003) Detailed reference viewed: 16 (2 ULg)![]() Ammonium sulphate as promoting agent of the sulphidization process of oxidized Cu-Co ores from the Luiswishi deposit (RDC)Bastin, David ; Frenay, Jean ; Poster (2003) The Luiswishi deposit belongs to the Cu-Co deposits of the Southern Group of the Katangian Copper Belt and is operated by a joint venture between EGMF (Entreprises Générales Malta Forrest) and Gecamines ... [more ▼] The Luiswishi deposit belongs to the Cu-Co deposits of the Southern Group of the Katangian Copper Belt and is operated by a joint venture between EGMF (Entreprises Générales Malta Forrest) and Gecamines (Générale des Carrières et des Mines). The Cu-Co ore is beneficiated by the sulphidization process at the NCK (New Concentrator of Kipushi) at Kipushi. Sulphidization followed by flotation with sulphydryl collectors is a common practice for the treatment of oxidized base metals ores. This process is complex and its application at the industrial scale is quite sensitive. In Central Africa it is also a cost intensive treatment as the sulphidizing agent has to be imported. In order to improve the metallurgical performances and to optimise the economics of the process, a laboratory research program was carried out by the Laboratory of Metallurgy and Mineral Processing (MTM) of the University of Liège in close collaboration with EGMF and Gecamines. This program included the study of various flotation reagents as dispersing, depressing and activating agents. This paper presents the results obtained with the use of ammonium sulphate as activator of the sulphidized xanthate flotation. Although ammonium sulphate has been mentioned in the literature as a promoting agent of the sulphidized xanthate flotation of malachite, its effects on the flotation of cobalt oxides was not known. The testworks were carried out on various oxidized siliceous ore types from the Luiswishi deposit. A 1.7 l Agitair laboratory flotation cell was used. NaHS and potassium amylxanthate were respectively choosen as sulphidizer and collector. A mixture of gasoil and tall oil (90/10) was used as secondary collector. A multistage sulphidization was realised. Values of pH were followed during the different tests and an ion selective electrode Ag/Ag2S was used to control the Es potentiel evolution during the stepwise addition of the sulphidizer. The addition of ammonium suphate [(NH4)2SO4] simultaneously with NaHS led to the following results: -A marked improvement of the sulfidization kinetics leading to shorter conditioning times and limiting the number of sulphidizing stages required to reach maximum recoveries. -The inhibition of the depressive effect on Cu and Co flotation of an excess of hydrosulphide ions in the pulp. -An improvement of the selectivity of the flotation combined with higher cobalt recoveries. The promoting effect is indeed more effective for cobalt than for copper and cobalt recoveries were improved by 4 to 8 %. -A significant decrease of the sulfidizer consumption. These laboratory results were implemented at an industrial scale at the NCK at Kipushi. In close accordance with the laboratory results the sulphidization kinetics were improved and the cobalt recoveries rose by 7 % while maintaining the previous Cu and Co grades of the concentrate. Ammonium sulphate being a low cost and common reagent (it is easily found in the fertiliser industry or as a byproduct of the coke industry), its use significantly improved the economics of the flotation of Cu-Co oxides ores from the Luiswishi deposit. [less ▲] Detailed reference viewed: 71 (1 ULg) |
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