References of "Strivay, David"
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See detailFading of modern Prussian blue pigments in linseed oil medium
Samain, Louise ULg; Silversmit, Geert; Sanyova, Jana et al

in Journal of Analytical Atomic Spectrometry [=JAAS] (2011), 26(5), 930

The fading of modern laboratory-synthesized and commercial Prussian blue, iron(III) hexacyanoferrate(II), based pigments in a linseed oil medium during exposure to light has been investigated. The ... [more ▼]

The fading of modern laboratory-synthesized and commercial Prussian blue, iron(III) hexacyanoferrate(II), based pigments in a linseed oil medium during exposure to light has been investigated. The Prussian blue pigments were painted from linseed oil, as a pure pigment and mixed with white lead, (PbCO3)2Pb(OH)2, zinc white, ZnO, or titanium white, TiO2, pigment. The samples were subjected to accelerated ageing for 800 hours and the light fastness of the Prussian blue pigment was evaluated by reference to blue wool standards. Pure Prussian blue is extremely light fast whilst it strongly fades when mixed with a white pigment, especially with lead white or zinc oxide. The painted samples were studied by UV-visible, iron K-edge X-ray absorption, iron-57 transmission Mössbauer, and attenuated total reflectance infrared spectroscopy. X-ray absorption results reveal a decrease in the iron coordination number in aged samples in the presence of white pigment. The Mössbauer spectra of the pure Prussian blue and the unaged and aged mixtures of Prussian blue and lead white or zinc oxide at 1:100 and 1:10 dilution ratios, respectively, indicate the presence of iron(II) and iron(III) in a ratio close to one as expected for the bulk stoichiometric KFeIII[FeII(CN)6]; no change in the spectral parameters was observed upon ageing. Combined with the X-ray near edge absorption and infrared studies, these results suggest reduction of the surface iron ions in the Prussian blue with ageing upon exposure to light. [less ▲]

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See detailDirect analysis of the central panel of the so-called Wyts triptych after Jan van Eyck
Deneckere, A.; Hocquet, François-Philippe ULg; Born, A. et al

in Journal of Raman Spectroscopy (2010), 41(11), 1210-1219

The applicability of mobile, non-destructive techniques such as energy dispersive X-ray fluorescence spectroscopy, which reveals the elemental composition, and fibre-coupled Raman spectroscopy, offering ... [more ▼]

The applicability of mobile, non-destructive techniques such as energy dispersive X-ray fluorescence spectroscopy, which reveals the elemental composition, and fibre-coupled Raman spectroscopy, offering molecular information, is applied to the central panel of the Wyts triptych, after Jan van Eyck. Using a combination of these direct techniques, vermilion (HgS), lead white (2PbCO3·Pb(OH)2), anatase (TiO2), massicot (PbO), zinc white (ZnO) and lead-tin yellow type I (Pb2SnO4) could be identified. X-ray fluorescence spectroscopy (XRF) measurements also confirmed the presence of cobalt. Also, copper was detected in different blue and green areas. For the brown and red colour, iron oxides were used. Apart from identifying pigments, the combination of these analytical techniques also gave information about restored parts and the layered structure of the panel. XRF maps of three different areas of the panel painting were recorded to get an idea of the changes the painting underwent during its past history. This research confirms the results of the visual analysis that the painting is a heavily restored copy of a lost original by Jan van Eyck. [less ▲]

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See detailWear study on polymers and bio-materials by ultra thin layer activation
Delhalle, René ULg; Marchal, André ULg; Lucas, S. et al

Poster (2010, August)

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See detailGlass production in Merovingian time
Van Wersch, Line ULg; Mathis, François ULg; Othmane, G. et al

Poster (2010, May)

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See detailStudy of the degradation mechanisms of Prussian Blue in paint layers by X-ray absorption spectroscopy
Samain, Louise ULg; Silversmit, Geert; Vekemans, Bart et al

Conference (2010)

Detailed reference viewed: 67 (8 ULg)