Unpredictable photocatalytic ability of H-2-reduced rutile-TiO2 xerogel in the degradation of dye-pollutants under UV and visible light irradiationPáez, Carlos ; ; Pirard, Jean-Paul et alin Applied Catalysis B : Environmental (2010), 94 Detailed reference viewed: 52 (28 ULg) Condensation-Induced Decrease of Small-Angle X-ray Scattering Intensity in Gelling Silica SolutionsGommes, Cédric ; Pirard, Jean-Paul ; in Journal of Physical Chemistry C: Nanomaterials, Interfaces, and Hard Matter (2010), 114 We propose a mathematical modeling of the total SAXS intensity in silica sol-gel processes in terms of hydrolysis and condensation reactions, as well as of microsyneresis. The results are used to ... [more ▼] We propose a mathematical modeling of the total SAXS intensity in silica sol-gel processes in terms of hydrolysis and condensation reactions, as well as of microsyneresis. The results are used to rationalize previously published SAXS data of TEOS solutions reacting with organically modified trialkoxysilanes. We notably show that the decrease in SAXS intensity reported for these samples at the end of gelation is a consequence of condensation reactions. The water released by the latter reactions contributes to reduce the electron density difference between the silica and the solvent phases of the gels [less ▲] Detailed reference viewed: 9 (2 ULg) Synthesis and characterization of highly loaded Pt/carbon xerogel catalysts prepared by Strong Electrostatic Adsorption methodJob, Nathalie ; ; et alin Studies in Surface Science and Catalysis (2010), 175 Detailed reference viewed: 7 (2 ULg) Ni-doped carbon xerogels for H2 storage; ; Job, Nathalie et alin Carbon (2010), 48 Detailed reference viewed: 11 (0 ULg) Functionalization of carbon xerogels for the preparation of Pd/C catalysts by grafting of Pd complex; ; Job, Nathalie et alin Studies in Surface Science and Catalysis (2010), 175 Detailed reference viewed: 15 (0 ULg) Synthesis of highly loaded Pt/carbon xerogel catalysts for PEM fuel cells by the Strong Electrostatic Adsorption methodJob, Nathalie ; Lambert, Stéphanie ; et alin Catalysis Today (2010), 150 Detailed reference viewed: 18 (3 ULg) Morphological models of complex ordered materials based on inhomogeneously clipped Gaussian fieldsGommes, Cédric ; Pirard, Jean-Paul ![]() in Physical Review. E : Statistical, Nonlinear, and Soft Matter Physics (2009), 80 Clipping a Gaussian random field at a level that is position-dependent yields statistically non-homogeneous morphologies, relevant to many ordered nanostructured materials. The 1-point and 2-point ... [more ▼] Clipping a Gaussian random field at a level that is position-dependent yields statistically non-homogeneous morphologies, relevant to many ordered nanostructured materials. The 1-point and 2-point probability functions of the morphology are derived, as well as a general relation between the specific surface area and the gradient of the clipping function. The general results are particularized for the comprehensive analysis of small-angle x-ray scattering and nitrogen adsorption of SBA-15 ordered mesoporous silica. [less ▲] Detailed reference viewed: 17 (2 ULg) PEM fuel cell cathodes based on Pt/carbon xerogel catalystsJob, Nathalie ; ; et alPoster (2009, October 25) Detailed reference viewed: 5 (0 ULg) Ni-doped carbon xerogels for H2 storage; ; et al Poster (2009, October 25) Detailed reference viewed: 6 (0 ULg) Ethylene partial pressure, carbon nanotube production and catalytic deactivation profiles through a continuous rotary reactor for carbon nanotube synthesis by the CCVD methodPirard, Sophie ; ; Pirard, Jean-Paul ![]() Conference (2009, August) Detailed reference viewed: 5 (0 ULg) Carbon xerogels as supports for catalysts and electrocatalystsJob, Nathalie ; ; Lambert, Stéphanie et alConference (2009, June 14) Detailed reference viewed: 8 (2 ULg) Evolution of the surface chemistry of carbon xerogels with very different textural properties by chemical activation and oxidation; ; Pirard, Jean-Paul et alPoster (2009, June 14) Detailed reference viewed: 2 (1 ULg) Evaluation of the dynamic adsorption of gas on active carbon beds using in situ X-ray µ-tomography coupled with 3D image analysis; Léonard, Angélique ; et alPoster (2009, June) Detailed reference viewed: 40 (9 ULg) 15 Minutes about SAXS and gelsGommes, Cédric ; ; Pirard, Jean-Paul ![]() Scientific conference (2009, May) Synthesis of very highly dispersed platinum catalysts supported on carbon xerogels by the strong electrostatic adsorption methodLambert, Stéphanie ; Job, Nathalie ; et alin Journal of Catalysis (2009), 261 Highly dispersed Pt/carbon xerogel catalysts are obtained by applying the “Strong Electrostatic Adsorption” (SEA) of hexachloroplatinic acid to carbon xerogels (PZC = 9.4) and platinum tetraammine ... [more ▼] Highly dispersed Pt/carbon xerogel catalysts are obtained by applying the “Strong Electrostatic Adsorption” (SEA) of hexachloroplatinic acid to carbon xerogels (PZC = 9.4) and platinum tetraammine chloride to oxidized carbon xerogels (PZC = 2.4). After the reduction step, all these Pt/carbon xerogel catalysts display a very high level of metal dispersion: very small platinum particles (1.1-1.3 nm) are observed by TEM. Pt particle sizes obtained by CO chemisorption are in good agreement with TEM micrographs, which shows that the metal is accessible to reactants. These Pt/carbon xerogel catalysts are very active for the hydrogenation of benzene into cyclohexane. [less ▲] Detailed reference viewed: 75 (12 ULg) Carbon xerogels as supports for catalysts and electrocatalystsJob, Nathalie ; ; Lambert, Stéphanie et alin Proceedings of the International Carbon Conference 2009 (2009) Detailed reference viewed: 25 (4 ULg) Evolution of the surface chemistry of carbon xerogels with very different textural properties by chemical activation and oxidation; ; Pirard, Jean-Paul et alin Proceedings of the International Carbon Conference 2009 (2009) Detailed reference viewed: 10 (1 ULg) Studying chemical activation in carbon xerogels; ; et al in Journal of Materials Science (2009), 44 Detailed reference viewed: 5 (0 ULg) Electrochemical characterization of Pt/carbon xerogel and Pt/carbon aerogel catalysts - first insights into the influence of the carbon texture on the Pt nanoparticles morphology and catalytic activityJob, Nathalie ; ; et alin Journal of Materials Science (2009), 44 Detailed reference viewed: 12 (4 ULg) Ag-and SiO2-doped porous TiO2 with enhanced thermal stabilityBraconnier, Benoît ; Páez Martínez, Carlos ; Lambert, Stéphanie et alin Microporous & Mesoporous Materials (2009), 122 Detailed reference viewed: 87 (36 ULg) |
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