References of "Pirard, Jean-Paul"
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See detailCondensation-Induced Decrease of Small-Angle X-ray Scattering Intensity in Gelling Silica Solutions
Gommes, Cédric ULg; Pirard, Jean-Paul ULg; Goderis, Bart

in Journal of Physical Chemistry C: Nanomaterials, Interfaces, and Hard Matter (2010), 114

We propose a mathematical modeling of the total SAXS intensity in silica sol-gel processes in terms of hydrolysis and condensation reactions, as well as of microsyneresis. The results are used to ... [more ▼]

We propose a mathematical modeling of the total SAXS intensity in silica sol-gel processes in terms of hydrolysis and condensation reactions, as well as of microsyneresis. The results are used to rationalize previously published SAXS data of TEOS solutions reacting with organically modified trialkoxysilanes. We notably show that the decrease in SAXS intensity reported for these samples at the end of gelation is a consequence of condensation reactions. The water released by the latter reactions contributes to reduce the electron density difference between the silica and the solvent phases of the gels [less ▲]

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See detailSynthesis and characterization of highly loaded Pt/carbon xerogel catalysts prepared by Strong Electrostatic Adsorption method
Job, Nathalie ULg; Maillard, Frédéric; Chatenet, Marian et al

in Studies in Surface Science and Catalysis (2010), 175

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See detailNi-doped carbon xerogels for H2 storage
Zubizarreta, Leire; Menendez, J. A.; Job, Nathalie ULg et al

in Carbon (2010), 48

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See detailFunctionalization of carbon xerogels for the preparation of Pd/C catalysts by grafting of Pd complex
Diverchy, Chantal; Hermans, Sophie; Job, Nathalie ULg et al

in Studies in Surface Science and Catalysis (2010), 175

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See detailMorphological models of complex ordered materials based on inhomogeneously clipped Gaussian fields
Gommes, Cédric ULg; Pirard, Jean-Paul ULg

in Physical Review. E : Statistical, Nonlinear, and Soft Matter Physics (2009), 80

Clipping a Gaussian random field at a level that is position-dependent yields statistically non-homogeneous morphologies, relevant to many ordered nanostructured materials. The 1-point and 2-point ... [more ▼]

Clipping a Gaussian random field at a level that is position-dependent yields statistically non-homogeneous morphologies, relevant to many ordered nanostructured materials. The 1-point and 2-point probability functions of the morphology are derived, as well as a general relation between the specific surface area and the gradient of the clipping function. The general results are particularized for the comprehensive analysis of small-angle x-ray scattering and nitrogen adsorption of SBA-15 ordered mesoporous silica. [less ▲]

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See detailPEM fuel cell cathodes based on Pt/carbon xerogel catalysts
Job, Nathalie ULg; Chatenet, M.; Brigaudet, M. et al

Poster (2009, October 25)

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See detailNi-doped carbon xerogels for H2 storage
Zubizarreta, Leire; Menénez, J. A.; Pis, J. J. et al

Poster (2009, October 25)

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See detailCarbon xerogels as supports for catalysts and electrocatalysts
Job, Nathalie ULg; Berthon-Fabry, S.; Lambert, Stéphanie ULg et al

Conference (2009, June 14)

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See detailEvolution of the surface chemistry of carbon xerogels with very different textural properties by chemical activation and oxidation
Zubizarreta, Leire; Arenillas, A.; Pirard, Jean-Paul ULg et al

Poster (2009, June 14)

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See detailEvaluation of the dynamic adsorption of gas on active carbon beds using in situ X-ray µ-tomography coupled with 3D image analysis
Almazan, Maria del Carmen; Léonard, Angélique ULg; Lodewyckx, Peter et al

Poster (2009, June)

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See detail15 Minutes about SAXS and gels
Gommes, Cédric ULg; Goderis, Bart; Pirard, Jean-Paul ULg

Scientific conference (2009, May)

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See detailSynthesis of very highly dispersed platinum catalysts supported on carbon xerogels by the strong electrostatic adsorption method
Lambert, Stéphanie ULg; Job, Nathalie ULg; D'Souza, Lawrence et al

in Journal of Catalysis (2009), 261

Highly dispersed Pt/carbon xerogel catalysts are obtained by applying the “Strong Electrostatic Adsorption” (SEA) of hexachloroplatinic acid to carbon xerogels (PZC = 9.4) and platinum tetraammine ... [more ▼]

Highly dispersed Pt/carbon xerogel catalysts are obtained by applying the “Strong Electrostatic Adsorption” (SEA) of hexachloroplatinic acid to carbon xerogels (PZC = 9.4) and platinum tetraammine chloride to oxidized carbon xerogels (PZC = 2.4). After the reduction step, all these Pt/carbon xerogel catalysts display a very high level of metal dispersion: very small platinum particles (1.1-1.3 nm) are observed by TEM. Pt particle sizes obtained by CO chemisorption are in good agreement with TEM micrographs, which shows that the metal is accessible to reactants. These Pt/carbon xerogel catalysts are very active for the hydrogenation of benzene into cyclohexane. [less ▲]

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See detailCarbon xerogels as supports for catalysts and electrocatalysts
Job, Nathalie ULg; Berthon-Fabry, S.; Lambert, Stéphanie ULg et al

in Proceedings of the International Carbon Conference 2009 (2009)

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See detailEvolution of the surface chemistry of carbon xerogels with very different textural properties by chemical activation and oxidation
Zubizaretta, Leire; Arenillas, A.; Pirard, Jean-Paul ULg et al

in Proceedings of the International Carbon Conference 2009 (2009)

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See detailStudying chemical activation in carbon xerogels
Zubizaretta, Leire; Arenillas, Ana; Pis, Jose Juan et al

in Journal of Materials Science (2009), 44

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See detailAg-and SiO2-doped porous TiO2 with enhanced thermal stability
Braconnier, Benoît ULg; Páez Martínez, Carlos ULg; Lambert, Stéphanie ULg et al

in Microporous & Mesoporous Materials (2009), 122

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