References of "Mahieu, Emmanuel"
     in
Bookmark and Share    
Full Text
Peer Reviewed
See detailA global inventory of stratospheric chlorine in 2004
Nassar, Ray; Bernath, Peter; Boone, Christopher D. et al

in Journal of Geophysical Research. Atmospheres (2006), 111(D22), 22312

[1] Total chlorine (Cl-TOT) in the stratosphere has been determined using the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) measurements of HCl, ClONO2, CH3Cl, CCl4, CCl3F (CFC ... [more ▼]

[1] Total chlorine (Cl-TOT) in the stratosphere has been determined using the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) measurements of HCl, ClONO2, CH3Cl, CCl4, CCl3F (CFC-11), CCl2F2 (CFC-12), CHClF2 (HCFC-22), CCl2FCClF2 (CFC-113), CH3CClF2 (HCFC-142b), COClF, and ClO supplemented by data from several other sources, including both measurements and models. Separate chlorine inventories were carried out in five latitude zones (60 degrees - 82 degrees N, 30 degrees - 60 degrees N, 30 degrees S - 30 degrees N, 30 degrees - 60 degrees S, and 60 degrees - 82 degrees S), averaging the period of February 2004 to January 2005 inclusive, when possible, to deal with seasonal variations. The effect of diurnal variation was avoided by only using measurements taken at local sunset. Mean stratospheric Cl-TOT values of 3.65 ppbv were determined for both the northern and southern midlatitudes (with an estimated 1 sigma accuracy of +/- 0.13 ppbv and a precision of +/- 0.09 ppbv), accompanied by a slightly lower value in the tropics and slightly higher values at high latitudes. Stratospheric Cl-TOT profiles in all five latitude zones are nearly linear with a slight positive slope in ppbv/km. Both the observed slopes and pattern of latitudinal variation can be interpreted as evidence of the beginning of a decline in global stratospheric chlorine, which is qualitatively consistent with the mean stratospheric circulation pattern and time lag necessary for transport. [less ▲]

Detailed reference viewed: 28 (14 ULg)
Full Text
Peer Reviewed
See detailComparisons between SCIAMACHY and ground-based FTIR data for total columns of CO, CH4, CO2 and N2O
Dils, Bart; De Mazière, Martine; Muller, Jean-François et al

in Atmospheric Chemistry and Physics (2006), 6

Total column amounts of CO, CH4, CO2 and N2O retrieved from SCIAMACHY nadir observations in its near-infrared channels have been compared to data from a ground-based quasi-global network of Fourier ... [more ▼]

Total column amounts of CO, CH4, CO2 and N2O retrieved from SCIAMACHY nadir observations in its near-infrared channels have been compared to data from a ground-based quasi-global network of Fourier-transform infrared ( FTIR) spectrometers. The SCIAMACHY data considered here have been produced by three different retrieval algorithms, WFM-DOAS (version 0.5 for CO and CH4 and version 0.4 for CO2 and N2O), IMAP- DOAS ( version 1.1 and 0.9 (for CO)) and IMLM (version 6.3) and cover the January to December 2003 time period. Comparisons have been made for individual data, as well as for monthly averages. To maximize the number of reliable coincidences that satisfy the temporal and spatial collocation criteria, the SCIAMACHY data have been compared with a temporal 3rd order polynomial interpolation of the ground-based data. Particular attention has been given to the question whether SCIAMACHY observes correctly the seasonal and latitudinal variability of the target species. The present results indicate that the individual SCIAMACHY data obtained with the actual versions of the algorithms have been significantly improved, but that the quality requirements, for estimating emissions on regional scales, are not yet met. Nevertheless, possible directions for further algorithm upgrades have been identified which should result in more reliable data products in a near future. [less ▲]

Detailed reference viewed: 59 (27 ULg)
Full Text
See detailPrecursor Gas Measurements (Chapter 2)
Notholt, J.; Bingemer, H.; Berresheim, H. et al

in Thomason, Larry W.; Peter, Thomas (Eds.) Assessment of Stratospheric Aerosol Properties (2006)

Assessments of stratospheric ozone have been conducted for nearly two decades and have evolved from describing ozone morphology to estimating ozone trends, and then to attribution of those trends ... [more ▼]

Assessments of stratospheric ozone have been conducted for nearly two decades and have evolved from describing ozone morphology to estimating ozone trends, and then to attribution of those trends. Stratospheric aerosol has only been integrated in assessments in the context of their effects on ozone chemistry and has not been critically evaluated itself. As a result, the Assessment of Stratospheric Aerosol Properties (ASAP) has been carried out by the WCRP project on Stratospheric Process and their Role in Climate (SPARC). The objective of this report is to present a systematic analysis of the state of knowledge of stratospheric aerosols including their precursors. It includes an examination of precursor concentrations and trends, measurements of stratospheric aerosol properties, trends in those properties, and modeling of aerosol formation, transport, and distribution in both background and volcanic conditions. The scope of this report is extensive; however, some aspects of stratospheric aerosol science have been deliberately excluded. For instance, we have not attempted to include an examination of polar stratospheric clouds (PSCs) or other clouds (such as cirrus clouds) occurring at or above the tropopause except in as much as they influence aerosol observations. Polar stratospheric clouds are the subject of a separate SPARC activity. We have produced a gap-free aerosol data base for use beyond this report. This required some new analysis that has not previously appeared in the technical literature. Similarly, the trend analysis required the development of a new analysis technique that is the subject of an article published in the Journal of Geophysical Research. New work is clearly identified in the present report. [less ▲]

Detailed reference viewed: 26 (1 ULg)
Full Text
Peer Reviewed
See detailLong-term trend of CH4 at northern mid-latitudes: Comparison between ground-based infrared solar and surface sampling measurements
Rinsland, Curtis P.; Goldman, Aaron; Elkins, James W. et al

in Journal of Quantitative Spectroscopy & Radiative Transfer (2006), 97(3), 457-466

We report average tropospheric CH4 volume mixing ratios retrieved from a 27 year time series of high spectral resolution infrared solar absorption measurements recorded between May 1977 and July 2004 at ... [more ▼]

We report average tropospheric CH4 volume mixing ratios retrieved from a 27 year time series of high spectral resolution infrared solar absorption measurements recorded between May 1977 and July 2004 at the US National Solar Observatory station on Kitt Peak (31.9 degrees N, 111.6 degrees W, 2.09 km altitude) and their comparison with surface in situ sampling measurements recorded between 1983 and 2004 at the Climate Monitoring and Diagnostics Laboratory (CMDL) station at Niwot Ridge, Colorado (40.0 degrees N, 105.5 degrees W, 3013 m altitude). The two measurement sets therefore overlap for the 1983-2004 time period. An average tropospheric volume mixing ratios of 1814 +/- 48 ppbv (1 ppbv = 10(-9) per unit volume) has been derived from the solar absorption time series with a best-fit increase rate trend equal to 8.26 +/- 2.20 ppbv yr(-1) in 1983 decreasing to 1.94 +/- 3.69 ppbv yr(-1) in 2003. The CMDL measurements also show a continuous long-term CH4 volume mixing ratio rise, with subsequent slowing down. A mean ratio of the retrieved average tropospheric volume mixing ratio to the CMDL volume mixing ratio for the overlapping time period of 1.038 +/- 0.034 indicates agreement between both data sets within the quantified experimental errors. (C) 2005 Elsevier Ltd. All rights reserved. [less ▲]

Detailed reference viewed: 29 (3 ULg)
Full Text
Peer Reviewed
See detailLine-by-line calculations of thermal infrared radiation representative for global condition: CFC-12 as an example
Myhre, Gunnar; Stordal, Frode; Gausemel, Ingvil et al

in Journal of Quantitative Spectroscopy & Radiative Transfer (2006), 97(3), 317-331

We estimate a current direct radiative forcing due to CFC-12 of 0.18 Wm(-2), which is likely to be the peak radiative forcing for CFC-12. Global measurements of CFC-12 show at present an almost negligible ... [more ▼]

We estimate a current direct radiative forcing due to CFC-12 of 0.18 Wm(-2), which is likely to be the peak radiative forcing for CFC-12. Global measurements of CFC-12 show at present an almost negligible trend for CFC-12 and measurement in an industrialized region show evidence that the peak concentration is reached. It is expected that concentration of CFC-12 in industrialized regions begins to decline 1-3 years before the global concentration. Our radiative forcing calculations are based on a line-by-line model appropriate for simulation of global mean radiative forcing, including clouds and stratospheric temperature adjustment. The radiative forcing of 0.33 Wm(-2)/ppbv is close to earlier published results for this compound. New spectroscopic measurements for CFC-12 are performed and compared to previously published results. (C) 2005 Elsevier Ltd. All rights reserved. [less ▲]

Detailed reference viewed: 55 (3 ULg)
Full Text
Peer Reviewed
See detailLong-term stratospheric carbon tetrafluoride (CF4) increase inferred from 1985-2004 infrared space-based solar occultation measurements
Rinsland, Curtis P.; Mahieu, Emmanuel ULg; Zander, Rodolphe ULg et al

in Geophysical Research Letters (2006), 33(2),

The long-term stratospheric carbon tetrafluoride (CF4) increase has been determined from infrared high spectral resolution solar occultation Fourier transform spectrometer measurements between 3 and 50 ... [more ▼]

The long-term stratospheric carbon tetrafluoride (CF4) increase has been determined from infrared high spectral resolution solar occultation Fourier transform spectrometer measurements between 3 and 50 hPa (similar to 20 to 40 km altitude) and latitudes from 50 degrees N to 50 degrees S during 1985, 1992, 1993, 1994, and 2004. The 1985 to 1994 measurements were recorded from the ATMOS ( Atmospheric Trace MOlecule Spectroscopy) instrument at 0.01 cm(-1) resolution and in 2004 by the Atmospheric Chemistry Experiment ( ACE) instrument at 0.02 cm(-1) resolution. Stratospheric volume mixing ratios, inferred from a polynomial fit to averages from the time periods considered here, increased from 49.37 +/- 2.60 pptv (10(-12) per unit volume) in 1985 to 58.38 +/- 4.14 pptv in 1992, 60.46 +/- 2.97 pptv in 1993, 60.11 +/- 3.60 pptv in 1994 and to 70.45 +/- 3.40 pptv in 2004. The stratospheric CF4 mixing ratio has continued to increase but at a slower rate than in previous years, for example, (1.14 +/- 0.68)% yr(-1) in 2004 as compared to (2.77 +/- 0.47)% yr(-1) in 1985, 1 sigma. Correlations of CF4 with N2O taking into account the increase of N2O with time also show the increase in the stratospheric CF4 burden over the two decade measurement time span. Our space-based measurements show that the slowdown in the rate of CF4 accumulation previously reported from surface measurements through 1997 has propagated to the stratosphere and is continuing. Citation: Rinsland, C. P., E. Mahieu, R. Zander, R. Nassar, P. Bernath, C. Boone, and L. S. Chiou (2006), Long-term stratospheric carbon tetrafluoride (CF4) increase inferred from 1985-2004 infrared space-based solar occultation measurements, Geophys. Res. Lett., 33, L02808, doi:10.1029/2005GL024709. [less ▲]

Detailed reference viewed: 25 (8 ULg)
See detailEvolution of a dozen non-CO2 greenhouse gases above Central Europe since the mid-1980s.
Zander, Rodolphe ULg; Mahieu, Emmanuel ULg; Demoulin, Philippe ULg et al

in Proceedings of the 4th International Symposium on Non-CO2 Greenhouse Gases (2006)

Detailed reference viewed: 9 (1 ULg)
Full Text
See detailAdvanced exploitation of ground-based Fourier transform infrared observations for tropospheric studies over Europe: achievements of the UFTIR project
De Mazière, Martine; Vigouroux, Corinne; Blumenstock, Thomas et al

in Geophysical Research Abstracts (2006), 8

Solar absorption measurements using Fourier transform infrared (FTIR) spectrometry carry information about the atmospheric abundances of many constituents, including information about their vertical ... [more ▼]

Solar absorption measurements using Fourier transform infrared (FTIR) spectrometry carry information about the atmospheric abundances of many constituents, including information about their vertical distributions in the troposphere and the stratosphere. Such observations have regularly been made since many years as a contribution to the NDSC (Network for the Detection of Stratospheric Change). They are the only ground-based remote sensing observations available nowadays that carry information about key atmospheric trace species in the free troposphere, among which the most important greenhouse gases. The European UFTIR project (Time series of Upper Free Troposphere observations from a European ground-based FTIR network, http://www.nilu.no/uftir) has focused on maximizing the information content of FTIR long-term monitoring data of some direct and indirect greenhouse gases (CH4, N2O, O3,HCFC-22, and CO and C2H6, respectively). The UFTIR network includes six NDSC stations in Western Europe, covering the polar to subtropical regions. At several stations of the network, the observations span more than a decade. Existing spectral time series have been reanalyzed according to a common optimized retrieval strategy, in order to derive distinct tropospheric and stratospheric abundances of the abovementioned target gases. A bootstrap resampling method has been implemented to evaluate trends of the tropospheric and total burdens of the target gases, including their uncertainties. In parallel, simulations of the target time series have been made with the Oslo CTM2 model: comparisons between the model results and the observations provide valuable information to improve the model, and in particular, to optimize emission estimates that are used as inputs to the model simulations, and to explain the observed trends. The final results of the project will be presented, and ways to proceed will be discussed. [less ▲]

Detailed reference viewed: 37 (2 ULg)
Full Text
Peer Reviewed
See detailLine narrowing effect on the retrieval of HF and HCl vertical profiles from ground-based FTIR measurements
Barret, Brice; Hurtmans, Daniel; Carleer, Michel R. et al

in Journal of Quantitative Spectroscopy & Radiative Transfer (2005), 95(4), 499-519

Collision-induced line narrowing, which has been discovered in the 1950s and investigated thoroughly in the laboratory since then, has yet never been taken into account in the spectroscopic remote sensing ... [more ▼]

Collision-induced line narrowing, which has been discovered in the 1950s and investigated thoroughly in the laboratory since then, has yet never been taken into account in the spectroscopic remote sensing of the atmosphere. This work investigates the effect of collision-induced line narrowing onto the retrieval of HCl and HF vertical profiles from ground-based solar absorption FTIR measurements made at the NDSC station of the Jungfraujoch (46.5 degrees N, 8 degrees E and 3580 m above see level). The retrievals are performed with the Atmosphit software, recently developed at the Universite Libre de Bruxelles. It is presented in this paper for the first time and is validated against the widely used SFIT2 software. The impact of the line narrowing onto the retrieval of HCl and HF vertical profiles is examined relying on careful information content and error budget analyses. We report that the effect is relatively weak for HCl but significant for HF. Confirmation of the need to take the line narrowing into account for the retrieval of vertical profiles from ground-based FTIR spectra is given by comparison with data from the HALOE space borne instrument, rather insensitive to this spectroscopic effect. (c) 2005 Elsevier Ltd. All rights reserved. [less ▲]

Detailed reference viewed: 38 (14 ULg)
Full Text
Peer Reviewed
See detailTrends of HF, HCl, CCl2F2, CCl3F, CHClF2 (HCFC-22), and SF6 in the lower stratosphere from Atmospheric Chemistry Experiment (ACE) and Atmospheric Trace Molecule Spectroscopy (ATMOS) measurements near 30 degrees N latitude
Rinsland, Curtis P.; Boone, Christopher D.; Nassar, Ray et al

in Geophysical Research Letters (2005), 32(16),

[ 1] Volume mixing ratios ( VMRs) of HF, HCl, CCl2F2, CHClF2 ( HCFC-22), and SF6 in the lower stratosphere have been derived from solar occultation measurements recorded with spaceborne high resolution ... [more ▼]

[ 1] Volume mixing ratios ( VMRs) of HF, HCl, CCl2F2, CHClF2 ( HCFC-22), and SF6 in the lower stratosphere have been derived from solar occultation measurements recorded with spaceborne high resolution Fourier transform spectrometers. Atmospheric Chemistry Experiment ( ACE) VMRs measured during 2004 have been compared with those obtained in 1985 and 1994 by the Atmospheric Trace MOlecule Spectroscopy ( ATMOS) instrument. Trends are estimated by referencing the measured VMRs to those of the long-lived constituent N2O to account for variations in the dynamic history of the sampled air masses. Pressure-gridded measurements covering 10-100 hPa ( similar to 16 to 30 km altitude) were used in the analysis that includes typically 25 degrees N-35 degrees N latitude. The VMR changes provide further evidence of the impact of the emission restrictions imposed by the Montreal Protocol and its strengthening amendments and adjustments and are consistent with model predictions and known sources and sinks of halocarbons. Decreases in the lower stratospheric mixing ratios of CCl3F and HCl are measured in 2004 with respect to 1994, providing important confirmation of recent ground-based solar absorption measurements of a decline in inorganic chlorine. Trends estimates are compared with other reported measurements and model predictions. [less ▲]

Detailed reference viewed: 65 (8 ULg)
Full Text
Peer Reviewed
See detailComparisons between ACE-FTS and ground-based measurements of stratospheric HCl and ClONO2 loadings at northern latitudes
Mahieu, Emmanuel ULg; Zander, Rodolphe ULg; Duchatelet, Pierre ULg et al

in Geophysical Research Letters (2005), 32(15),

We report first comparisons of stratospheric column abundances of hydrogen chloride (HCl) and chlorine nitrate (ClONO2) derived from infrared solar spectra recorded in 2004 at selected northern latitudes ... [more ▼]

We report first comparisons of stratospheric column abundances of hydrogen chloride (HCl) and chlorine nitrate (ClONO2) derived from infrared solar spectra recorded in 2004 at selected northern latitudes by the spaceborne Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (ACE-FTS) and by Fourier transform infrared (FTIR) instruments at the NDSC (Network for Detection of Stratospheric Change)-affiliated sites of Thule ( Greenland), Kiruna ( Sweden), Jungfraujoch ( Switzerland), and Egbert and Toronto ( Canada). Overall, and within the respective uncertainties of the independent measurement approaches, the comparisons show that the ACE-FTS measurements produce very good stratospheric volume mixing ratio profiles. Their internal precision allows to identify characteristic distribution features associated with latitudinal, dynamical, seasonal and chemical changes occurring in the atmosphere. [less ▲]

Detailed reference viewed: 24 (11 ULg)
Full Text
Peer Reviewed
See detailAtmospheric Chemistry Experiment (ACE): Mission overview
Bernath, Peter; McElroy, C. T.; Abrams, Mark et al

in Geophysical Research Letters (2005), 32(15),

SCISAT-1, also known as the Atmospheric Chemistry Experiment ( ACE), is a Canadian satellite mission for remote sensing of the Earth's atmosphere. It was launched into low Earth circular orbit ( altitude ... [more ▼]

SCISAT-1, also known as the Atmospheric Chemistry Experiment ( ACE), is a Canadian satellite mission for remote sensing of the Earth's atmosphere. It was launched into low Earth circular orbit ( altitude 650 km, inclination 74 degrees) on 12 Aug. 2003. The primary ACE instrument is a high spectral resolution (0.02 cm(-1)) Fourier Transform Spectrometer (FTS) operating from 2.2 to 13.3 mm ( 750 - 4400 cm(-1)). The satellite also features a dual spectrophotometer known as MAESTRO with wavelength coverage of 285 - 1030 nm and spectral resolution of 1 - 2 nm. A pair of filtered CMOS detector arrays records images of the Sun at 0.525 and 1.02 mu m. Working primarily in solar occultation, the satellite provides altitude profile information ( typically 10 - 100 km) for temperature, pressure, and the volume mixing ratios for several dozen molecules of atmospheric interest, as well as atmospheric extinction profiles over the latitudes 85 degrees N to 85 degrees S. This paper presents a mission overview and some of the first scientific results. [less ▲]

Detailed reference viewed: 58 (21 ULg)
Full Text
Peer Reviewed
See detailEvolution of a dozen non-CO2 greenhouse gases above central Europe since the mid-1980s
Zander, Rodolphe ULg; Mahieu, Emmanuel ULg; Demoulin, Philippe ULg et al

in Environmental Sciences (2005), 2(2-3), 295-303

High-resolution infrared solar observations have been conducted consistently since the mid-1980s at the International Scientific Station of the Jungfraujoch, Switzerland, by the GIRPAS-ULg team (Groupe ... [more ▼]

High-resolution infrared solar observations have been conducted consistently since the mid-1980s at the International Scientific Station of the Jungfraujoch, Switzerland, by the GIRPAS-ULg team (Groupe Infra-Rouge de Physique Atmosphrique et Solaire-University of Lige), and by colleagues from the Belgian Institute for Space Aeronomy and from the Royal Observatory of Belgium, Brussels. These observations were performed with state-of-the-art Fourier transform infrared (FTIR) spectrometers, revealing specific absorption features of over 20 atmospheric gases in the middle-infrared. Related spectrometric analyses have allowed the derivation of their burdens, seasonal and inter-annual variability, as well as their long-term evolution. In addition to updates of long-term changes for CCl2F2, CHClF2, CH4, N2O, SF6, CO, C2H6 and C2H2 already dealt with at previous Non-CO2 Greenhouse Gases (NCGG) symposia, this paper further reports temporal evolutions observed during the past two decades for a series of other source gases, namely OCS, HCN, CCl3F and CCl4, which also have direct or indirect effects on the radiation balance of the troposphere and on the stratospheric ozone layer. [less ▲]

Detailed reference viewed: 42 (7 ULg)
Full Text
Peer Reviewed
See detailSulphur hexafluoride (SF6): comparison of FTIR-measurements at three sites and determination of its trend in the northern hemisphere
Krieg, Juergen; Notholt, Justus; Mahieu, Emmanuel ULg et al

in Journal of Quantitative Spectroscopy & Radiative Transfer (2005), 92(3), 383-392

Fourier transform infrared spectrometry has been used to retrieve the total column abundances of SF6 at three locations in the northern hemisphere, i.e., the Ny- Angstromlesund site in Spitsbergen/Norway ... [more ▼]

Fourier transform infrared spectrometry has been used to retrieve the total column abundances of SF6 at three locations in the northern hemisphere, i.e., the Ny- Angstromlesund site in Spitsbergen/Norway at 79degreesN, the Jungfraujoch observatory in Switzerland at 47degreesN and the Kitt Peak observatory in Arizona, USA, at 32degreesN. The total column results have been converted to average tropospheric mixing ratios. The mean increases in these mixing ratios have been found to be, equal to 0.31 +/- 0.08 pptv yr(-1) at Ny Angstromlesund, 0.24 +/- 0.01 pptv yr(-1) at the Jungfraujoch and 0.28 +/- 0.09 pptv yr(-1) at Kitt Peak for the common period March 1993 to March 2002, in agreement with corresponding CMDL data (0.21 +/- 0.0002 pptv yr(-1)) at the surface. The limited accuracy of the Ny Angstromlesund and Kitt Peak data results from strong tropospheric water vapour interferences at these lower altitude sites. Observations at all three locations show that SF6 is Still accumulating in the atmosphere. Extrapolations of linear and second-order fits to the Jungfraujoch data predict tropospheric mixing ratios of SF6, respectively equal to 16.4 +/- 0.5 and. 14.7 +/- 0.6 in 2050, and 28.2 +/- 0.9 and 22.2 +/- 10.8 pptv in 2100, significantly, lower than those reported in the literature so far. (C) 2004 Elsevier Ltd. All, rights reserved. [less ▲]

Detailed reference viewed: 62 (5 ULg)
Full Text
Peer Reviewed
See detailLong-term evolution in the tropospheric concentration of chlorofluorocarbon 12 (CCl2F2) derived from high-spectral resolution infrared solar absorption spectra: retrieval and comparison with in situ surface measurements
Rinsland, Curtis P.; Goldman, Aaron; Mahieu, Emmanuel ULg et al

in Journal of Quantitative Spectroscopy & Radiative Transfer (2005), 92(2), 201-209

The average tropospheric volume mixing ratios of chlorofluorocarbon 12 (CCl2F2) have been retrieved from high-spectral resolution ground-based infrared solar-absorption spectra recorded from March 1982 to ... [more ▼]

The average tropospheric volume mixing ratios of chlorofluorocarbon 12 (CCl2F2) have been retrieved from high-spectral resolution ground-based infrared solar-absorption spectra recorded from March 1982 to October 2003 with the McMath Fourier transform spectrometer at the US National Solar Observatory facility on Kitt Peak in southern Arizona (31.9degreesN, 111.6degreesW, 2.09 km altitude). The retrievals are based on fits to the unresolved v(8) band Q-branches near 922 cm(-1) using the SFIT2 retrieval algorithm. The annual increase rate was equal to (16.88 +/- 1.37) parts per trillion (10(-12)) by volume at the beginning of the time series, March 1982, or (4.77 +/- 0.04)%, 1 sigma, declining progressively to (2.49 +/- 1.24) parts per trillion, by volume at the end, October 2003, or (0.46 +/- 0.24)%, 1 sigma. Average tropospheric mixing ratios from the solar spectra have been compared with average surface flask and in situ sampling measurements from the Climate Monitoring and Diagnostics Laboratory (CMDL) station at Niwot Ridge, CO, (USA) (40.0degreesN, 105.5degreesW, 3013 m altitude). The average ratio and standard deviation of the monthly means of the retrieved tropospheric mixing ratios relative to the CMDL surface mixing ratios is (1.01 +/- 0.03) for the overlapping time period. Both datasets demonstrate the progressive impact of the Montreal protocol and its strengthening amendments on the trend of CCl2F2, though a tropospheric decrease has yet to be observed. (C) 2004 Elsevier Ltd. All rights reserved. [less ▲]

Detailed reference viewed: 23 (4 ULg)
Full Text
Peer Reviewed
See detailIncreased Northern Hemispheric carbon monoxide burden in the troposphere in 2002 and 2003 detected from the ground and from space
Yurganov, Leonid N.; Duchatelet, Pierre ULg; Dzhola, A. V. et al

in Atmospheric Chemistry and Physics (2005), 5

Carbon monoxide total column amounts in the atmosphere have been measured in the High Northern Hemisphere (30degrees - 90degrees N, HNH) between January 2002 and December 2003 using infrared spectrometers ... [more ▼]

Carbon monoxide total column amounts in the atmosphere have been measured in the High Northern Hemisphere (30degrees - 90degrees N, HNH) between January 2002 and December 2003 using infrared spectrometers of high and moderate resolution and the Sun as a light source. They were compared to ground-level CO mixing ratios and to total column amounts measured from space by the Terra/MOPITT instrument. All these data reveal increased CO abundances in 2002 - 2003 in comparison to the unperturbed 2000 - 2001 period. Maximum anomalies were observed in September 2002 and August 2003. Using a simple two-box model, the corresponding annual CO emission anomalies (referenced to 2000 - 2001 period) have been found equal to 95 Tg in 2002 and 130 Tg in 2003, thus close to those for 1996 and 1998. A good correlation with hot spots detected by a satellite radiometer allows one to assume strong boreal forest fires, occurred mainly in Russia, as a source of the increased CO burdens. [less ▲]

Detailed reference viewed: 26 (10 ULg)
Full Text
See detailRecent Evolution of atmospheric OCS above the Jungfraujoch station : implications for the stratospheric aerosol layer.
Mahieu, Emmanuel ULg; Zander, Rodolphe ULg; Demoulin, Philippe ULg et al

in Proceedings of the Atmospheric Spectroscopy Applications. (2005)

Detailed reference viewed: 5 (0 ULg)
Full Text
See detailInterannual variations of the carbon monoxide tropospheric burden between 30ºN and 90ºN in 1996-2003: ground-based and satellite measurements, estimate of biomass burning emissions
Yurganov, L. N.; Edwards, D. P.; Grechko, E. I. et al

in Geophysical Research Abstracts (2005), 7(EGU05-A-03850),

Carbon monoxide total column amounts in the atmosphere were measured in the High Northern Hemisphere (30º-90º N, HNH) between January 1996 and December 2003 using Fourier Transform Infrared high ... [more ▼]

Carbon monoxide total column amounts in the atmosphere were measured in the High Northern Hemisphere (30º-90º N, HNH) between January 1996 and December 2003 using Fourier Transform Infrared high resolution spectrometers installed at the NDSC (Network for Detection of Stratospheric Change) sites. A grating spectrometer of moderate resolution was employed for the same purpose at the Zvenigorod Research Station of the Institute of Atmospheric Physics near Moscow. CO mixing ratios were measured in the air samples obtained at the ground-level stations of the CMDL (Climate Modeling and Diagnostic Laboratory, NOAA) network. Total column CO amounts were measured from space by the Terra/MOPITT instrument between March, 2000, and December, 2003 (Edwards et al., 2004). Anomalies of monthly mean CO densities (related to a quiet period of 2000 - 2001) for different sites in the HNH were in agreement. This fact confirmed a good mixing of CO in the Northern Hemisphere on the montly basis that may be expected from a 1.5-2-month-long CO life-time. The data were integrated over the HNH reservoir (0-10 km in altitude and 30º-90º N in latitude) and the CO burden anomalies (in Tg) were analysed using a box model. Two CO sinks were taken into account: i) internal chemical removal in the reaction between CO and OH, and ii) transport of CO into the southertn part of the Northern hemisphere, where CO concentrations are usually lower. OH concentarations were taken from Spivakovsky et al. (2000). The air exchange through the 30º N boundary of the reservoir was estimated using the GEOS-CHEM model with a real meteorology of 1998 (Yurganov et al., 2004). The interannual variations of the sinks were neglected; a corresponding uncertainty in the retrieved source anomaly was estimated to be 20-30%. Since 1996 four years have been found to experience high CO emission of similar magnitude (1996, 1998, 2002, and 2003). During four years (1997, 1999, 2000, and 2001) the emissions were relatively low. Seasonal patterns of the emissions in active years were similar, maxima occured in July-August. However, in 2003 emissions in June-July were higher than in August. These semi-hemisphere averaged emission rates correlate with Siberian forest fire counts detected at night time by the ATSR radiometer of the ERS-2 satellite (R2 =0.51). The early peak of 2003 may be attributed to forest fires in Baikal region, Siberia. An inclusion of fire counts for other areas (Europe, North America) only worsen the correlation; this implies a decisive role of the Siberian fires for polluting the Northern Hemisphere troposphere (cf., Kasischke et al., 2005). It was estimated that the boreal forest fires during active years emit 30-60 Tg CO per month in July-August and 150-200 Tg annually. These emissions may be compared to industrial and transport pollution in the Northern Hemisphere estimated by Kasischke et al. (2005) as 290 Tg CO annually (i.e., 25 Tg monthly). [less ▲]

Detailed reference viewed: 13 (1 ULg)
Full Text
Peer Reviewed
See detailThe exploitation of ground-based Fourier transform infrared observations for the evaluation of tropospheric trends of greenhouse gases over Europe
De Mazière, Martine; Vigouroux, Corinne; Gardiner, Tom et al

in Environmental Sciences (2005), 2(2-3), 283-293

Solar absorption measurements using Fourier transform infrared (FTIR) spectrometry carry information about the atmospheric abundances of many constituents, including non-CO2 greenhouse gases. Such ... [more ▼]

Solar absorption measurements using Fourier transform infrared (FTIR) spectrometry carry information about the atmospheric abundances of many constituents, including non-CO2 greenhouse gases. Such observations have regularly been made for many years as a contribution to the Network for the Detection of Stratospheric Change (NDSC). They are the only ground-based remote sensing observations available nowadays that carry information about a number of greenhouse gases in the free troposphere. This work focuses on the discussion of the information content of FTIR long-term monitoring data of some direct and indirect greenhouse gases (CH4, N2O, O3 and CO and C2H6, respectively), at six NDSC stations in Western Europe. This European FTIR network covers the polar to subtropical regions. At several stations of the network, the observations span more than a decade. Existing spectral time series have been reanalyzed according to a common optimized retrieval strategy, in order to derive distinct tropospheric and stratospheric abundances for the above-mentioned target gases. A bootstrap resampling method has been implemented to evaluate trends of the tropospheric burdens of the target gases, including their uncertainties. In parallel, simulations of the target time series are being made with the Oslo CTM2 model: comparisons between the model results and the observations provide valuable information to improve the model and, in particular, to optimize emission estimates that are used as inputs to the model simulations. The work is being performed within the EC project UFTIR. The paper focuses on N2O for which the first trend results have been obtained. [less ▲]

Detailed reference viewed: 52 (11 ULg)
Full Text
Peer Reviewed
See detailFree tropospheric measurements of formic acid (HCOOH) from infrared ground-based solar absorption spectra: Retrieval approach, evidence for a seasonal cycle, and comparison with model calculations
Rinsland, Curtis P.; Mahieu, Emmanuel ULg; Zander, Rodolphe ULg et al

in Journal of Geophysical Research. Atmospheres (2004), 109(D18),

The seasonal variation of the free tropospheric volume mixing ratio of formic acid (HCOOH) has been derived from high-spectral-resolution solar absorption spectra recorded with the Fourier transform ... [more ▼]

The seasonal variation of the free tropospheric volume mixing ratio of formic acid (HCOOH) has been derived from high-spectral-resolution solar absorption spectra recorded with the Fourier transform spectrometer in the U. S. National Solar Observatory facility on Kitt Peak (31.9degreesN, 111.6degreesE, 2.09 km altitude) at a typical spectral resolution of 0.005 cm(-1). The spectra have been analyzed with the SFIT2 algorithm, which is based on a semiempirical application of the optimal estimation method. Absorption by HCOOH is weak in these solar spectra, but successful retrievals have been obtained with a new procedure that fits the HCOOH nu(6) band Q branch at 1105 cm(-1) simultaneously with a window to account for a temperature-sensitive HDO line, which overlaps the HCOOH Q branch. After retaining only the best measurements from a database extending from June 1980 to October 2002 the retrievals show a seasonal variation, with a summer maximum and a winter minimum. Average 2.09-10 km volume mixing ratios binned in 3 month intervals range from a maximum of 792+/-323 parts per trillion by volume (pptv), or 10(-12), in July-September to a minimum of 313+/-175 pptv in October-December, with the uncertainties corresponding to statistical means from daily averages. The results are compared with previously reported measurements and model calculations. [less ▲]

Detailed reference viewed: 30 (5 ULg)