References of "Eppe, Gauthier"
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See detailDioxin levels in European eels, a Belgian study
Focant, Jean-François ULg; Geeraerts, C.; Eppe, Gauthier ULg et al

in Organohalogen Compounds (2010, September)

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See detailPLE for extraction of dioxins in animal feed and ingredients
Focant, Jean-François ULg; Scholl, Georges ULg; De Pauw, Edwin ULg et al

in Organohalogen Compounds (2010, September), 72

Within the entire complex procedure required to measure dioxins and related compounds in biological matrices, the extraction step is often seen as a well controlled step. Although maybe true for many ... [more ▼]

Within the entire complex procedure required to measure dioxins and related compounds in biological matrices, the extraction step is often seen as a well controlled step. Although maybe true for many human and food-related matrices, the situation is very different for animal feed and feed ingredients. Specific European guidelines (e.g. Commission Directive 2006/13/EC, Commission Regulation (EC) No 152/2009) exist for animal feed but only list general requirements for the various stages of the procedure. The liberty is left to laboratories to select, for example, the tools used for the extraction steps. This has the advantage to allow ‘in-house’ methods to be used, as long as they satisfy with all the requirements of the EU Regulation. In that context, it is foreseen that the European Committee for Standardization (CEN) will soon propose a standard for the determination of PCDD/Fs and PCBs in animal feed that would be the reference method to be used to solve potential issues in case of dispute over results reported from different laboratories. A major point of concern is that it has been reported earlier1 that most commonly accepted extraction procedure can conduct to significantly different results for the extraction of dioxins and related compounds in feed and feed additives such as mineral clays and various oxides. Several non-instrumental and instrumental automated approaches are available for extraction. Soxhlet extractors have long been the most used tools for non-instrumental extraction of solids. They have proven to be very efficient but some limitations encouraged the development of other approaches based on instrumental techniques. For feed extraction, pressurized liquid extraction (PLE) (also branded as accelerated solvent extraction ASE®) is the technique of choice for high sample throughput. This study reports on the investigation of the use of various solvent mixtures, extraction temperatures, and instruments (parallel PLE, sequential ASE®) for the extraction of 17 PCDD/Fs and 12 dioxin-like PCBs in mineral clay, bovine feed, fish meal, and in-house quality control animal compound feed. [less ▲]

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See detailImpact of storage and handling on metabolites in a human plasma standard reference material
Eppe, Gauthier ULg; Dodder, Nathan; Lippa, Katrice et al

Conference (2010, June)

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See detailIDENTIFICATION OF METABOLITES IN A HUMAN PLASMA STANDARD REFERENCE MATERIAL BY MULTIPLE GC/MS APPROACHES
Eppe, Gauthier ULg; Benner, Bruce; White, Edward et al

Poster (2010, January)

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See detailREVISED EU-CRITERIA FOR APPLYING BIOANALYTICAL METHODS FOR SCREENING OF FEED AND FOOD FOR DIOXINS AND DIOXIN-LIKE PCBS.
Hoogenboom, LAP; Hadrich, Johan; Eppe, Gauthier ULg et al

in Organohalogen Compounds (2010), 72

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See detailFuran formation from vitamin C in a starch-based model system: Influence of the reaction conditions
Owczarek-Fendor, Agnieska; De Meulenaer, Bruno; Scholl, Georges ULg et al

in Food Chemistry (2010), 121(4), 1163-1170

The generation of furan from vitamin C during thermal treatment of a starch-based model system, which simulated baby food, was studied. Results indicated that the amount of sample heated in the vial ... [more ▼]

The generation of furan from vitamin C during thermal treatment of a starch-based model system, which simulated baby food, was studied. Results indicated that the amount of sample heated in the vial influenced the furan generation from ascorbic acid. Increasing the amount of heated sample from 5% to approximately 98% of the total vial volume, drastically reduced furan formation from 70 ppb to 16 ppb. Changes in ascorbic acid concentrations from 0.1 to 4.5 mg/g did not influence furan concentration nor did different ascorbic/dehydroascorbic acid molar ratios. Interestingly, waxy corn starch itself considerably enhanced furan generation from ascorbic acid. Under the same conditions, 13.2 ppb of furan was generated in starch-based samples, while in ascorbic acid buffered solutions only 0.4 ppb of furan was formed. Application of other matrices, in particular agar and hydrolysed starch, resulted in similar furan concentrations as for native starch, while in polyol solutions furan concentrations were comparable to those obtained for the buffered ascorbic acid solutions. [less ▲]

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See detailAPPLICATION OF THE XDS-CALUX BIOASSAY IN ROUTINE: SEMI-QUANTITATIVE SCREENING USING AL-BEQ CUT-OFF VALUES
Vanderperren, H.; Haedrich, J.; Eppe, Gauthier ULg et al

in Organohalogen Compounds (2010)

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See detailDISCREPANCIES BETWEEN BIO-ANALYTICAL AND CHEMO-ANALYTICAL RESULTS HAVE A NON-NEGLIGIBLE MESSAGE
Goeyens, L.; Hoogenboom, R.; Eppe, Gauthier ULg et al

in Organohalogen Compounds (2010)

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See detailFuran formation in baby food model systems from vitamin C and unsaturated fatty acids
Owczarek-Fendor, Agnieszka; De Meulenaer, Bruno; Scholl, Georges ULg et al

Conference (2010)

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See detailDietary intake of PCDD/Fs and dioxin-like PCBs of the Belgian Population
Windal, Isabelle; Vandevijvere, S.; Maleki, M. et al

in Chemosphere (2010), 79

The World Health Organization recommends assessing human exposure to contaminants on a regular basis. In order to assess the current dietary exposure of the Belgian adult population to PCDD/Fs and dioxin ... [more ▼]

The World Health Organization recommends assessing human exposure to contaminants on a regular basis. In order to assess the current dietary exposure of the Belgian adult population to PCDD/Fs and dioxin-like PCBs and to update exposure estimates of 2000–2001, a total diet study was designed. The mean dietary intake of PCDD/Fs and dioxin-like PCBs in the Belgian adult population in 2008 was estimated to be 0.72 pg TEQ kgbw-1 d-1 (middle bound concentrations, TEF of 1998) based on occurrence data of 2008 and national food consumption data of 2004. This value is clearly below the Tolerable Weekly Intake (TWI) of 14 pg TEQ kgbw-1 week-1 set by the Scientific Committee on Food of the European Commission and below the provisional tolerable monthly intake of 70 pg TEQ kgbw-1 month-1 set by the Joint FAO/WHO Expert Committee on Food Additives. Considering the cumulative distribution, the intake was less than 1 pg TEQ kgbw-1 d-1 for more than 80% of the population, and less than 2 pg TEQ kgbw-1 d-1 for the entire population. When using the 2005 TEF instead of the 1998 TEF, the mean dietary intake in the Belgian adult population was estimated to be 0.61 pg TEQ kgbw-1 d-1. [less ▲]

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See detailImportance of fat oxidation in starch-based emulsions in the generation of the process contaminant furan.
Owczarek-Fendor, Agnieszka; De Meulenaer, Bruno; Scholl, Georges ULg et al

in Journal of Agricultural and Food Chemistry (2010), 58(17), 9579-86

The formation of the possibly carcinogenic process contaminant furan was studied in starch-based emulsions during heat treatments as applied for sterilization. Fresh and oxidized soybean, sunflower, high ... [more ▼]

The formation of the possibly carcinogenic process contaminant furan was studied in starch-based emulsions during heat treatments as applied for sterilization. Fresh and oxidized soybean, sunflower, high-oleic sunflower, olive, linseed, and rapeseed oils were compared. Results indicated that both the oil type, in particular, the fatty acid composition, and the oxidation degree of the oil determined the susceptibility of the oils to generate furan upon heating. Thus, oils containing the nutritionally relevant omega-3 unsaturated alpha-linolenic acid proved to be able to generate significant amounts of furan if the oils were oxidized. No clear relationship between p-anisidine values of various oils and the amount of generated furan could be observed. However, in the case of soybean oil, significantly more furan was produced upon an increase in oxidation degree. Surprisingly, furan formation in food-relevant systems containing fresh lipids proved to be a minor route (up to 1.5 ppb furan) compared to a previously studied vitamin C containing model system (up to 13 ppb furan). [less ▲]

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See detailHuman Serum biomonitoring: Methodology and Intercalibration
Focant, Jean-François ULg; Eppe, Gauthier ULg

Scientific conference (2009, March)

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See detailIdentification and quantification of selected Metabolites in a Human Plasma by Two Dimensional Gas Chromatography Time of Flight Mass Spectrometry’
Eppe, Gauthier ULg; Mc Gaw, Elizabeth; Dodder, Nathan et al

in 5th International Conference of the Metabolimic Society (2009)

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See detailIdentification and Quantification of Metabolites in a Human Plasma Standard Reference Material by Multiple Mass Spectrometry Methods
Dodder, Nathan; Barak, Ruth; Eppe, Gauthier ULg et al

in 57th ASMS Conference on Mass Spectrometry and Allied topics (2009)

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See detailDerivatization of Amino Acids in Human Plasma for Quantitation by Comprehensive Two Dimensional Gas Chromatography Time of Flight Mass Spectrometry
Mc Gaw, Elizabeth; Eppe, Gauthier ULg; Lowenthal, Mark et al

in 57th ASMS Conference on Mass Spectrometry and Allied Topics (2009)

Detailed reference viewed: 16 (2 ULg)