Etude de l'appareil producteur de sons d'Ophidion barbatum; Henrist, Catherine ; Cloots, Rudi et alPoster (2006) Detailed reference viewed: 6 (1 ULg) (Micro)-structural comparison between geopolymers, alkali-activated slag cement and Portland cement; Henrist, Catherine ; Duyckaerts, Monique et alin Journal of the European Ceramic Society (2006), 26(16), 3789-3797 Concurrently to research conducted on ordinary Portland cement (PC), new types of binders were developed during the last decades. These are formed by alkali-activation of metakaolin or ground-granulated ... [more ▼] Concurrently to research conducted on ordinary Portland cement (PC), new types of binders were developed during the last decades. These are formed by alkali-activation of metakaolin or ground-granulated blast furnace slag (GGBFS) and are named, respectively, geopolymers (GP) or alkali-activated slag (AAS). Four different cementitious materials were synthesised: PC, AAS, GP, and a mix GP-AAS and fully compared about their compositions and (micro)-structures. X-ray diffraction has revealed the presence of semi-crystalline C-S-H gel binding phase in PC while AAS, GP and GP-AAS are nearly amorphous. Progressive structural changes have been observed between the different samples by means of infrared spectroscopy, Si-29 and At-27 magic-angle-spinning nuclear magnetic resonance spectroscopy: there is a polymerisation extent of the (alumino)-silicate framework from PC [SiQ(1) and SiQ(2) units] to AAS [SiQ(2) and SiQ(2)(1Al) units] and finally to GP [SiQ(4)(2Al) and SiQ(4)(3Al) units]. Scanning electron microscopy has shown that GP is a homogeneous matrix while the other materials are composites containing GGBFS grains surrounded by a binding matrix. Energy dispersive X-ray EDX analyses (line scans) have shown the absence of formation of any specific phase at the matrix-grains interfaces. (c) 2006 Elsevier Ltd. All rights reserved. [less ▲] Detailed reference viewed: 94 (6 ULg) Characterisation of the magnetic shielding properties of YBaCuO thick films prepared by electrophoretic deposition on silver substrates; ; et al in Journal of Physics: Conference Series [=JPCS] (2006), 43 This communication reports experimental results on the superconducting properties of YBaCuO thick films prepared by electrophoretic deposition on silver substrates. The magnetic shielding properties of ... [more ▼] This communication reports experimental results on the superconducting properties of YBaCuO thick films prepared by electrophoretic deposition on silver substrates. The magnetic shielding properties of the coatings were characterised by various methods. First, the electrical resistance and the transport critical current density, Jc, were determined. Our coatings exhibit a superconducting transition at a temperature of 90 K. Next, shielding characterisations were carried out at 77 K for samples having either a slab or a cylindrical geometry. In both cases, the frequency of the applied magnetic field was 103 Hz; the field behind the shielding wall was measured by a pick-up coil connected to a lock-in amplifier. In the case of cylindrical samples and for an applied induction lower than 1 G, the field inside the shielding enclosure is reduced by a factor greater than 106 (i.e. 120 dB) with respect to the applied field. [less ▲] Detailed reference viewed: 81 (47 ULg) YBa2Cu3O(7-delta) thick films on Ag prepared by the electrophoretic deposition technique; ; Fagnard, Jean-François et alin Journal of Physics: Conference Series [=JPCS] (2006), 43 YBa2Cu3O7-δ thick films have been deposited onto Ag substrates by the Electrophoretic Deposition (EPD) technique. Different microstructures and electrical behaviours were observed depending on the ... [more ▼] YBa2Cu3O7-δ thick films have been deposited onto Ag substrates by the Electrophoretic Deposition (EPD) technique. Different microstructures and electrical behaviours were observed depending on the starting powder. Coatings prepared from commercial powder displayed significant porosity and the superconducting transition width was found to be magnetic-field dependent. Films produced from home-made coprecipitated powder are denser but contain some secondary phases. No dependence of the resistive transition as a function of magnetic field (H ≤ 20 Oe) was observed in that case. [less ▲] Detailed reference viewed: 41 (8 ULg) Use of a High-Temperature Superconducting Coil for Magnetic Energy StorageFagnard, Jean-François ; ; et alin Institute of Physics Conference Series (2006), 43 A high temperature superconducting magnetic energy storage device (SMES) has been realised using a 350 m-long BSCCO tape wound as a ''pancake'' coil. The coil is mounted on a cryocooler allowing ... [more ▼] A high temperature superconducting magnetic energy storage device (SMES) has been realised using a 350 m-long BSCCO tape wound as a ''pancake'' coil. The coil is mounted on a cryocooler allowing temperatures down to 17.2 K to be achieved. The temperature dependence of coil electrical resistance R(T) shows a superconducting transition at T = 102.5 K. Measurements of the V(I) characteristics were performed at several temperatures between 17.2 K and 101.5 K to obtain the temperature dependence of the critical current (using a 1 uV/cm criterion). Critical currents were found to exceed 100 A for T < 30 K. An electronic DC-DC converter was built in order to control the energy flow in and out of the superconducting coil. The converter consists of a MOS transistor bridge switching at a 80 kHz frequency and controlled with standard Pulse Width Modulation (PWM) techniques. The system was tested using a 30 V squared wave power supply as bridge input voltage. The coil current, the bridge input and output voltages were recorded simultaneously. Using a 10 A setpoint current in the superconducting coil, the whole system (coil + DC-DC converter) can provide a stable output voltage showing uninterruptible power supply (UPS) capabilities over 1 s. [less ▲] Detailed reference viewed: 56 (11 ULg) Study of thermal effects in bulk RE-BCO superconductors submitted to a variable magnetic field; Fagnard, Jean-François ; et alin Journal of Physics: Conference Series [=JPCS] (2006), 43 When bulk RE-BCO superconductors are used as permanent magnets in engineering applications, they are likely to experience transient variations of the applied magnetic field. The resulting vortex motion ... [more ▼] When bulk RE-BCO superconductors are used as permanent magnets in engineering applications, they are likely to experience transient variations of the applied magnetic field. The resulting vortex motion may cause a significant temperature increase. As a consequence the initial trapped flux is reduced. In the present work, we first focus on the cause of a temperature increase. The temperature distribution within a superconducting finite cylinder subjected to an alternating magnetic field is theoretically predicted. Results are compared to experimental data obtained by two temperature sensors attached to a bulk YBCO pellet. Second, we consider curative methods for reducing the effect of heat flux on the temperature increase. Hall-probe mappings on YBCO samples maintained out of the thermal equilibrium are performed for two different morphologies : a plain single domain and a single domain with a regularly spaced hole array. The drilled single-domain displays a trapped induction which is weakly affected by the local heating while displaying a high trapped field. [less ▲] Detailed reference viewed: 29 (13 ULg) Texturation of YBa2Cu3O7-delta thick films by electrophoretic deposition under magnetic field; Denis, Samuel ; Nutal, Nicolas et alin Key Engineering Materials [=KEM] (2006), 314 YBa2Cu3O7-delta coatings were deposited by electrophoretic deposition (EPD) onto Ni substrates. Particles of different sizes and shapes were used in order to study the influence of the powder ... [more ▼] YBa2Cu3O7-delta coatings were deposited by electrophoretic deposition (EPD) onto Ni substrates. Particles of different sizes and shapes were used in order to study the influence of the powder microstructure on the film density. Texturation of the thick films was induced by application of a magnetic field during the electrophoretic deposition. X-ray diffraction analysis has clearly shown preferred c-axis alignment of the YBa2Cu3O7-delta films along the direction normal to the substrate surface. Scanning electron microscopy and optical polarised light microscopy were used to characterise the microstructure of the coatings, revealing a nonrandom platelets organisation. [less ▲] Detailed reference viewed: 39 (16 ULg) Preparation of YBa2Cu3O7-x superconducting thick films by the electrophoretic deposition method; Denis, Samuel ; Vanderbemden, Philippe et alin Journal of Materials Science (2006), 41(24), 8109-8114 YBa2Cu3O7-x thick films have been realised by the Electrophoretic Deposition method (EPD). The influence of several parameters (powder and iodine concentrations in the suspension, applied voltage and ... [more ▼] YBa2Cu3O7-x thick films have been realised by the Electrophoretic Deposition method (EPD). The influence of several parameters (powder and iodine concentrations in the suspension, applied voltage and deposition time) on the EPD process has been studied by measuring the conductivity of the suspension and the amount of YBa2Cu3O7-x particles deposited on the electrode. Superconducting coatings onto silver substrates have been produced by a multilayer process during different deposition times. The highest critical current density value of these coatings measured by the four-point probe method is about 10^3 A/cm^2 (77 K), in a suitable range for magnetic shielding applications. [less ▲] Detailed reference viewed: 35 (11 ULg) Slip casting of barium zirconate aqueous concentrated suspensionsBoschini, Frédéric ; Guillaume, Bernard ; Rulmont, André et alin Journal of the European Ceramic Society (2006), 26(9), 1591-1598 The rheological behaviour of aqueous suspensions of barium zirconate was studied focusing on the effect of the Volume fraction of particles, leading to the determination of the maximum packing fraction ... [more ▼] The rheological behaviour of aqueous suspensions of barium zirconate was studied focusing on the effect of the Volume fraction of particles, leading to the determination of the maximum packing fraction. Optimised suspensions dispersed with both polymethacrylic acid and tetramethylammonium hydroxide were slip cast on plaster Moulds to produce discs and crucibles, leading to relative green densities greater than 62% of theoretical ones. Densification was studied at temperatures ranging from 1450 to 1700 degrees C by static and dynamic sintering experiments. Scanning electron microscopy studies demonstrate that slip cast parts are dense and very homogeneous, without any significant processing-related defects or abnormal grain growth. (c) 2005 Elsevier Ltd. All rights reserved. [less ▲] Detailed reference viewed: 20 (5 ULg) Influence of the shaping effect on hardness homogeneity by Vickers indentation analysisGuillaume, Bernard ; Boschini, Frédéric ; Rulmont, André et alin Journal of the European Ceramic Society (2006), 26(15), 3191-3196 In this study, indentation technique (Vickers indentation) has been unconventionally used to evaluate the homogeneity of barium zirconate ceramic samples which have been shaped through different routes ... [more ▼] In this study, indentation technique (Vickers indentation) has been unconventionally used to evaluate the homogeneity of barium zirconate ceramic samples which have been shaped through different routes. Statistical tools have been used to estimate the con-elation which can be established between heterogeneities within the samples and their shaping ways. (c) 2005 Elsevier Ltd. All rights reserved. [less ▲] Detailed reference viewed: 18 (1 ULg) Optimization of BaZrO3 sintering by control of the initial powder size distribution; a factorial design statistical analysisGuillaume, Bernard ; Boschini, Frédéric ; et alin Journal of the European Ceramic Society (2005), 25(16), 3593-3604 A factorial design statistical analysis has been conducted in order to obtain the optimum conditions in the solid state sintering process of barium zirconate bulk materials, optimum with respect to ... [more ▼] A factorial design statistical analysis has been conducted in order to obtain the optimum conditions in the solid state sintering process of barium zirconate bulk materials, optimum with respect to density, closed and open porosities. The optimized heat treatment permits to sinter a 99% dense barium zirconate sample at 1650 degrees C during only 2 h. When the temperature is higher than 1650 degrees C or when the heating time is longer than 2 h, a decrease in density is observed. (c) 2004 Elsevier Ltd. All rights reserved. [less ▲] Detailed reference viewed: 18 (1 ULg) Colloidal stability of aqueous suspensions of barium zirconateBoschini, Frédéric ; Rulmont, André ; Cloots, Rudi et alin Journal of the European Ceramic Society (2005), 25(13), 3195-3201 In this article, the colloidal behaviour of aqueous suspensions of barium zirconate is investigated. The variation of zeta-potential as a consequence of changing the pH and the concentration of an anionic ... [more ▼] In this article, the colloidal behaviour of aqueous suspensions of barium zirconate is investigated. The variation of zeta-potential as a consequence of changing the pH and the concentration of an anionic polyelectrolyte is studied, the isoelectric point occurring at pH 5.3. The IEP shifts down on calcining the powder and also when anionic polyelectrolytes are added. Rheological studies have been made on suspensions prepared to a solids loading of 27 vol.% (72 wt.%). Optimum dispersing conditions are reached for suspensions prepared at basic pH with 1.5 wt.% tetramethylammonium hydroxide (TMAH) and a concentration of ammonium polymethacrylate (PMAA) of 1.6 wt.%. Comparison with similar suspensions prepared with NaOH instead PMAA demonstrated that TMAH gives an extra contribution to stability, probably related to the adsorption of N+(Me)(4) groups. The suspensions were slip cast, and green densities higher than 60% of theoretical were obtained. (c) 2004 Elsevier Ltd. All rights reserved. [less ▲] Detailed reference viewed: 20 (3 ULg) Vivianite formation and distribution in Lake Baikal sedimentsFagel, Nathalie ; ; et alin Global and Planetary Change (2005), 46(1-4), 315-336 In an effort to better understand vivianite formation processes, four Lake Baikal sediment cores spanning two to four interglacial stages in the northern, central and southern basins and under various ... [more ▼] In an effort to better understand vivianite formation processes, four Lake Baikal sediment cores spanning two to four interglacial stages in the northern, central and southern basins and under various biogeochemical environments are scrutinized. The vivianite-rich layers were detected by anomalous P-enrichments in bulk geochemistry and visually by observations on X-radiographs. The millimetric concretions of vivianite were isolated by sieving and analysed by X-ray diffraction, scanning electron microscope (SEM), microprobe, infrared spectroscopy, inductively coupled plasma atomic emission spectrometry and mass spectrometry (ICP-AES, ICP-MS). All the vivianites display similar morphological, mineralogical and geochemical signature, suggesting a common diagenetic origin. Their geochemical signature is sensitive to secondary alteration where vivianite concretions are gradually transformed from the rim to the center into an amorphous santabarbaraite phase with a decreasing Mn content. We analysed the spatial and temporal distribution of the concretions in order to determine the primary parameters controlling the vivianite formation, e.g., lithology, sedimentation rates, and porewater chemistry. We conclude that vivianite formation in Lake Baikal is mainly controlled by porewater chemistry and sedimentation rates, and it is not a proxy for lacustrine paleoproductivity. Vivianite accumulation is not restricted to areas of slow sedimentation rates (e.g., Academician and Continent ridges). At the site of relatively fast sedimentation rate, i.e., the Posolsky Bank near the Selenga Delta, vivianite production may be more or less related to the Selenga River inputs. It could be also indirectly related to the past intensive methane escapes from the sediments. While reflecting an early diagenetic signal, the source of P and Fe porewater for vivianites genesis is still unclear. (C) 2004 Elsevier B.V. All rights reserved. [less ▲] Detailed reference viewed: 60 (6 ULg) Low-field magnetoresistance in La0.7Ca0.3MnO3 manganite compounds prepared by the spray drying techniqueVertruyen, Bénédicte ; Rulmont, André ; Cloots, Rudi et alin Journal of Materials Science (2005), 40(1), 117-122 Calcium-substituted lanthanum manganite compounds were synthesized by the spray drying technique. This method - whose main advantages are versatility, high reproducibility and scalability - yields small ... [more ▼] Calcium-substituted lanthanum manganite compounds were synthesized by the spray drying technique. This method - whose main advantages are versatility, high reproducibility and scalability - yields small grain materials of high homogeneity and displaying low-field magnetoresistance effects. We report about the physical and chemical characterizations of these samples in order to investigate the potential interest of spray drying for the production of materials for low-field magnetoresistance applications. We have studied the dependence of the low-field magnetoresistance on the temperature and duration of the thermal treatment applied to the pelletized powders. The issue of the shape anisotropy (demagnetisation effects) influence on the magnetoresistance properties has also been dealt with. (C) 2005 Springer Science + Business Media, Inc. [less ▲] Detailed reference viewed: 39 (5 ULg) From RE-211 to RE-123. How to control the final microstructure of superconducting single-domainsCloots, Rudi ; ; et alin Superconductor Science and Technology (2005), 18(3), 9-23 This paper reviews the usual techniques for producing YBCO-type single-domains and the microstructure of the as-obtained samples. The problems of seed dissolution and parasite nucleations are discussed in ... [more ▼] This paper reviews the usual techniques for producing YBCO-type single-domains and the microstructure of the as-obtained samples. The problems of seed dissolution and parasite nucleations are discussed in detail. The formation of microstructural defects, such as pores and cracks, is examined. An important part of this review is devoted to the study of the influence of RE-211 particles (RE2BaCuO5 where RE denotes Y, Yb, Nd, Sm, Dy, Gd, Eu or a mixture of them. Generally Nd4Ba2Cu 2O10 is preferred to Nd2BaCuO5) for the microstructure and properties of RE-Ba-Cu-O single-domains. Pushing/trapping theory is described in order to explain the spatial distribution of RE-211 particles in the RE-123 ((RE)Ba2Cu3O7-δ) monoliths. The formation of RE-211-free regions is discussed. Different ways to limit the RE-211 coarsening are reviewed. Microstructural defects in the RE-123 matrix caused by the RE-211 particles are presented. It is also shown that RE-211 particles play a significant role in the mechanical properties of single-domain samples. We finish this review by discussing the infiltration and growth process as a good technique to control the microstructure. © 2005 IOP Publishing Ltd. [less ▲] Detailed reference viewed: 7 (2 ULg) Sound-producing apparatus of the snake-blenny Ophidion barbatum; Henrist, Catherine ; Cloots, Rudi et alPoster (2005) Surface modification of as-synthesized lamellar mesostructured silica obtained by liquid crystal templatingHenrist, Catherine ; ; Rulmont, André et alin New Journal of Chemistry (2005), 29(8), 1017-1021 We report a study of lamellar silica phase silylation, starting from as-synthesized silica, without the usual heat treatment step. Characterizations of the modified silica include X-ray diffraction ... [more ▼] We report a study of lamellar silica phase silylation, starting from as-synthesized silica, without the usual heat treatment step. Characterizations of the modified silica include X-ray diffraction, thermal analysis, electron microscopy and solid state NMR. Special attention is given to the possibility of keeping the lamellar organisation along with the elimination of the organic template. [less ▲] Detailed reference viewed: 26 (1 ULg) Silver paint as a soldering agent for DyBaCuO single-domain welding; Fagnard, Jean-François ; Laurent, Philippe et alin Superconductor Science and Technology (2005), 18(4), 508-512 Silver paint has been tested as a soldering agent for DyBaCuO 4 single-domain welding. Junctions have been manufactured on Dy-Ba-Cu-O single domains cut either along planes parallel to the c-axis IT or ... [more ▼] Silver paint has been tested as a soldering agent for DyBaCuO 4 single-domain welding. Junctions have been manufactured on Dy-Ba-Cu-O single domains cut either along planes parallel to the c-axis IT or along the ab-planes. Microstructural and superconducting characterizations of the samples have been performed. For both types of junctions, the microstructure in the joined area is very clean: no secondary phase or Ag particle segregation has been observed. Electrical and magnetic measurements for all configurations of interest are reported (rho(T) curves, and Hall probe mapping). The narrow resistive superconducting transition reported for all configurations shows that the artificial junction does not affect significantly the measured superconducting properties of the material. [less ▲] Detailed reference viewed: 38 (2 ULg) Magneto-transport characterization of Dy123 monodomain superconductors; Mucha, Jan ; Vanderbemden, Philippe et alin Applied Physics A : Materials Science & Processing (2005), 81(5), 1001-1007 We consider textured materials of the DyBa2Cu3O7 type seeded with a Nd123 seed as initiator. They are grown with an excess 20% Dy211 phase on a Dy2O3 substrate. We report chemical characterization ... [more ▼] We consider textured materials of the DyBa2Cu3O7 type seeded with a Nd123 seed as initiator. They are grown with an excess 20% Dy211 phase on a Dy2O3 substrate. We report chemical characterization, electrical resistivity, thermoelectric power and thermal conductivity over a broad temperature range as a function of an applied magnetic field up to 6 T. We show that specific features appear in the magneto-thermal transport properties, different in these materials from those found in single crystals and polycrystalline samples. We propose that two vortex regimes can be distinguished in the mixed phase, due to the intrinsic microstructure. We calculate the viscosity, entropy and figure of merit of the samples. [less ▲] Detailed reference viewed: 26 (11 ULg) Investigation of DyBa2CU3O7-d superconducting domains grown by the infiltration technique starting with small size Dy-211 particles; ; Rulmont, André et alin Superconductor Science and Technology (2005), 18(2 Sp. Iss. SI), 136-141 An infiltration and growth process is here used as an alternative to the classical top-seeded melt-textured growth process for the production of Dy-123 single-domains with finely dispersed small size Dy ... [more ▼] An infiltration and growth process is here used as an alternative to the classical top-seeded melt-textured growth process for the production of Dy-123 single-domains with finely dispersed small size Dy-211 particles. The starting materials are the 211-particles and a barium and copper rich liquid phase precursor. The infiltration and growth process allows for controlling both the spatial and size distribution of the 211-particles in the final superconducting 123-single-domain. The main parameters (set-ups, maximum processing temperature with respect to the peritectic temperature, nature of reactant, porosity of the 211-preform) of the infiltration and growth process are discussed. Moreover, different processes of chimie douce are shown in order to produce Dy-211 particles with controlled shape and size, particles that can be used as precursors for the infiltration and growth process. [less ▲] Detailed reference viewed: 25 (5 ULg) |
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