Multivariate statistics to understand the geochemical processes induced by groundwater pollution Multi-scale applyingGesels, Julie ; ; et alConference (2013, June 07) Different hydrogeochemical approaches (classical diagrams, spatial distribution maps, geochemical equations and multivariate statistics) are combined to obtain a global understanding of the ... [more ▼] Different hydrogeochemical approaches (classical diagrams, spatial distribution maps, geochemical equations and multivariate statistics) are combined to obtain a global understanding of the hydrogeochemical processus at regional and at local scale. [less ▲] Detailed reference viewed: 12 (2 ULg) Time variyng groundwater flux measurement using a single well tracer techniqueJamin, Pierre ; Brouyère, Serge ; et alPoster (2013, April 24) Contaminant mass discharge measurements are often performed at given times or integrated over a certain period of time, using active or passive sampling techniques. One problem arising is that such ... [more ▼] Contaminant mass discharge measurements are often performed at given times or integrated over a certain period of time, using active or passive sampling techniques. One problem arising is that such measurements may not be representative of the temporal dynamics of the mass discharge variations. These variations can be caused by fluctuations in contaminant concentrations or, more frequently, by changes in the groundwater fluxes. Pollutant mass fluxes are typically estimated through a combination of solute concentrations and groundwater fluxes measured across a control plane made of several multi-level wells. Accurate measurements of local transient Darcy fluxes have been recognized as the weakest points in most of the developed techniques for groundwater contaminant mass flux measurements. The main objective here is to extend the FVPDM technique for temporal monitoring of groundwater fluxes and to demonstrate its ability to be used in combination with passive sampling devices for measurement of contaminant mass fluxes in groundwater. The Finite Volume Point Dilution Method (FVPDM) is a single well tracer technique for the measurement of local groundwater fluxes based on the continuous injection of tracer at very low injection rate (Brouyère et al. 2008). These developments are based on the application of the adapted technique on a case study in a fractured granitic aquifer in Ploemeur (France). This application investigates transient groundwater fluxes that are controlled by pumping in a well nearby the tested piezometers. Long monitoring time series have been recorded under these controlled conditions of transient groundwater flow. Results show the high sensivity of the FVPDM technique to small variations in groundwater flow velocities and its aptitude for long term monitoring of groundwater fluxes. The comparison between the results of FVPDM and classical point dilution tests performed in same conditions shows close correlation. Interpretation of FVPDM tests in transient conditions have been developed together with an evaluation of the uncertainties that can happen if the frequency of the groundwater flow variations is high. The tests carried on the Ploemeur site also illustrate the first ever application of the FVPDM technique between a double-packer system used for the investigation of a defined layer of an aquifer. This innovative application of the FVPDM using packers opens concrete perspectives for investigation of vertical heterogeneities of groundwater fluxes across a well. [less ▲] Detailed reference viewed: 23 (6 ULg) A combined hydrochemical, isotopic and multivariate statistics approach for pollutant source identification in a regional aquiferGesels, Julie ; ; et alConference (2013, April 23) In an urban and industrial context, a detailed hydrogeochemical characterization of groundwater has been performed in an alluvial aquifer, with the aim of determining the origin of the inorganic ... [more ▼] In an urban and industrial context, a detailed hydrogeochemical characterization of groundwater has been performed in an alluvial aquifer, with the aim of determining the origin of the inorganic contaminations and the main processes involved that contribute to a poor groundwater quality. [less ▲] Detailed reference viewed: 9 (3 ULg) Diffuse urban and industrial groundwater pollution with metallic trace elements A comparison between affected and unaffected areasGesels, Julie ; Dollé, Fabien ; et alPoster (2013, April 22) For metalic trace elements, spatially distributed background concentrations will be defined as a function of geological and hydrogeological context and considering the impact of diffuse pollution. Detailed reference viewed: 7 (1 ULg) Integrated field assessment of contaminant fate and transport in the unsaturated and saturated zoneFernandez de Vera, Natalia ; Peña Hernandez, Juan Angel ; Jamin, Pierre et alPoster (2013, April 22) In the poster, a multidisciplinary methodology is presented with the aim of characterizing fate and transport of pollutants in the vadose and the saturated zone of industrial sites. The methodology used ... [more ▼] In the poster, a multidisciplinary methodology is presented with the aim of characterizing fate and transport of pollutants in the vadose and the saturated zone of industrial sites. The methodology used for the vadose zone consist in the combination of the Vadose Monitoring System, cross-hole and surface geophysics at a local scale. For saturated zone studies, the approach consist in the chemical and isotopic analysis of the various contaminants present on site at regional scale. [less ▲] Detailed reference viewed: 22 (3 ULg) Coupling heat and salt tracer experiment for the estimation of heat transfer and solute transport parametersWildemeersch, Samuel ; Jamin, Pierre ; Orban, Philippe et alConference (2013, April 22) Geothermal energy is a promising source of energy in the context of sustainable development. Therefore, very low enthalpy geothermal systems (open or closed) are increasingly considered for heating or ... [more ▼] Geothermal energy is a promising source of energy in the context of sustainable development. Therefore, very low enthalpy geothermal systems (open or closed) are increasingly considered for heating or cooling houses and offices using groundwater energy. However, prior to the development of such systems, a feasibility study and an impact study of the system on groundwater ressources are required. Thereliability of such studies is highly dependent on the quality of the estimation of heat transfer parameters. This highlights the necessity of estimating properly such parameters. The objective of this study is to combine the use of heat and salt tracers to estimate simultaneously heat transfer and solute transport parameters in an alluvial aquifer. Additionally, coupling heat and salt tracing experiments is particularly useful for comparing heat transfer and solute transport processes occurring in the subsurface. An experimental field site, located near Liege (Belgium), is equipped with 21 piezometers drilled in the alluvial deposits of the Meuse River. These alluvial deposits are composed of a loess layer (3 m) overlying a sand and gravel layer which constitutes the alluvial aquifer (7 m). The coupled tracing experiment consists in injecting simultaneously heated water and salt in a piezometer and monitoring the evolution of groundwater temperature and salt concentration in a series of control panels set perpendicularly to groundwater flow. This coupled tracing experiment is then simulated using a numerical model. The estimation of heat transfer and solute transport parameters is obtained by calibrating this numerical model using inversion tools. The present study proposes a methodology coupling heat and salt tracing experiment for estimating heat transfer parameters at the field scale. Furthermore, this coupled tracing experiment shows that the comportment of heat and solute in the subsurface presents key differences. [less ▲] Detailed reference viewed: 25 (11 ULg) Downscaling transient climate change with a stochastic weather generator for the Geer catchment, Belgium; ; et al in Climate Research (2013) The coarse resolution of climate models creates the need for future scenarios which are downscaled to an appropriate spatial scale. Considerable effort has been devoted to the development of downscaling ... [more ▼] The coarse resolution of climate models creates the need for future scenarios which are downscaled to an appropriate spatial scale. Considerable effort has been devoted to the development of downscaling methods but a number of important issues remain in the development of robust, usable climate scenarios. These include the incorporation of various sources of uncertainty into future scenarios and the production of scenarios at timescales relevant to planners. This paper describes a new procedure which addresses these issues by producing a multi-model ensemble of transient climate change scenarios. This method couples an existing stochastic rainfall model to a new, transient implementation of a weather generator, using changes projected by an ensemble of regional climate model (RCM) experiments. The methodology is demonstrated by the generation of transient scenarios of daily rainfall, temperature and potential evapotranspiration (PET) for the Geer catchment in Belgium for the period 2010 to 2085. The utility of these scenarios is demonstrated by assessing the changes projected by the simulated time series of several temperature indices. The Geer is projected to experience a decrease in the occurrence of frost days with a corresponding shortening of the frost season and lengthening of the growing season. By examining a large ensemble of transient scenarios the range of uncertainty in these projections is assessed, but further, it is suggested that additional information on the projected timing of specified threshold events or system responses may be provided which could aid planners in assessing the likely timescales of required interventions and adaptation responses. [less ▲] Detailed reference viewed: 17 (1 ULg) Is it worth protecting groundwater from diffuse pollution with agri-environmental schemes? A hydro-economic modeling approach Journal of Environmental Management; Orban, Philippe ; Brouyère, Serge ![]() in Journal of Environmental Management (2013) In Europe, 30% of groundwater bodies are considered to be at risk of not achieving the Water Framework Directive (WFD) ‘good status’ objective by 2015, and 45% are in doubt of doing so. Diffuse ... [more ▼] In Europe, 30% of groundwater bodies are considered to be at risk of not achieving the Water Framework Directive (WFD) ‘good status’ objective by 2015, and 45% are in doubt of doing so. Diffuse agricultural pollution is one of the main pressures affecting groundwater bodies. To tackle this problem, the WFD requires Member States to design and implement cost-effective programs of measures to achieve the ‘good status’ objective by 2027 at the latest. Hitherto, action plans have mainly consisted of promoting the adoption of Agri- Environmental Schemes (AES). This raises a number of questions concerning the effectiveness of such schemes for improving groundwater status, and the economic implications of their implementation. We propose a hydro-economic model that combines a hydrogeological model to simulate groundwater quality evolution with agronomic and economic components to assess the expected costs, effectiveness, and benefits of AES implementation. This hydro-economic model can be used to identify cost-effective AES combinations at groundwater-body scale and to show the benefits to be expected from the resulting improvement in groundwater quality. The model is applied here to a rural area encompassing the Hesbaye aquifer, a large chalk aquifer which supplies about 230,000 inhabitants in the city of Liege (Belgium) and is severely contaminated by agricultural nitrates. We show that the time frame within which improvements in the Hesbaye groundwater quality can be expected may be much longer than that required by the WFD. Current WFD programs based on AES may be inappropriate for achieving the ‘good status’ objective in the most productive agricultural areas, in particular because these schemes are insufficiently attractive. Achieving ‘good status’ by 2027 would demand a substantial change in the design of AES, involving costs that may not be offset by benefits in the case of chalk aquifers with long renewal times. [less ▲] Detailed reference viewed: 3 (0 ULg) Benzene dynamics and biodegradation in alluvial aquifers affected by river fluctuations; ; et al in Ground Water (2013) The spatial distribution and temporal dynamics of a benzene plume in an alluvial aquifer strongly affected by river fluctuations was studied. Benzene concentrations, aquifer geochemistry datasets, past ... [more ▼] The spatial distribution and temporal dynamics of a benzene plume in an alluvial aquifer strongly affected by river fluctuations was studied. Benzene concentrations, aquifer geochemistry datasets, past river morphology and benzene degradation rates estimated in situ using stable carbon isotope enrichment were analysed in concert with aquifer heterogeneity and river fluctuations. Geochemistry data demonstrated that benzene biodegradation was on-going under sulphate reducing conditions. Long-term monitoring of hydraulic heads and characterisation of the alluvial aquifer formed the basis of a detailed modelled image of aquifer heterogeneity. Hydraulic conductivity was found to strongly correlate with benzene degradation, indicating that low hydraulic conductivity areas are capable of sustaining benzene anaerobic biodegradation provided the electron acceptor (SO42-) does not become rate limiting. Modelling results demonstrated that the groundwater flux direction is reversed on annual basis when the river level rises up to two meters, thereby forcing the infiltration of oxygenated surface water into the aquifer. The mobilisation state of metal trace elements such as Zn, Cd and As present in the aquifer predominantly depended on the strong potential gradient within the plume. However, infiltration of oxygenated water was found to trigger a change from strongly reducing to oxic conditions near the river, causing mobilisation of previously immobile metal species and vice versa. Monitored natural attenuation appears to be an appropriate remediation strategy in this type of dynamic environment provided that aquifer characterisation and targeted monitoring of redox conditions is adequate and electron acceptors remain available until concentrations of toxic compounds reduce to acceptable levels. [less ▲] Detailed reference viewed: 8 (0 ULg) An object-oriented hydrogeological data model for groundwater projects; Brouyère, Serge ![]() in Environmental Modelling & Software (2013) Geological and hydrogeological data are expensive to obtain in the field but are crucial for specific hydrogeological studies, from hydrogeological water balances to groundwater flow modelling and ... [more ▼] Geological and hydrogeological data are expensive to obtain in the field but are crucial for specific hydrogeological studies, from hydrogeological water balances to groundwater flow modelling and contaminant transport, or for more integrated environmental investigations where groundwater plays a role. In this context, hydrogeological data are collected, transformed and exchanged at different scales, from local to international levels and between numerous institutions ranging from environmental consulting companies to the national and international environmental administrations. To guarantee that these exchanges are possible and meaningful, a clear structure and meta-information on applied hydrogeological data models is required. To make one step towards seamless management of groundwater projects, a new hydrogeological data model has been developed: Hg2O. It is described using object-oriented paradigms and it follows the recommendations of the International Organization for Standardization (ISO/TC211), the Open Geospatial Consortium (OGC), and the European Geospatial Information Working Group. Hydrogeological features are organized in packages of spatial feature datasets. The observations and measurements related to these features are organized in a seperate package. A particular focus is on specialized hydrogeological field experiments such as hydraulic and tracer tests. Two first implementations in the proprietary desktop ArcGIS environment and in the open-source web-based Web2GIS platform are presented, focusing on their respective standards support. [less ▲] Detailed reference viewed: 27 (1 ULg) Le projet Synclin’Eau : Support à la mise en oeuvre de la Directive Cadre sur l’eau pour les masses d’eau souterraine des Synclinoriums de Dinant et NamurOrban, Philippe ; Gesels, Julie ; et alPoster (2012, October 10) Detailed reference viewed: 29 (3 ULg) Modélisation régionale des eaux souterraines dans le cadre de la mise en œuvre de la Directive Cadre sur l’Eau : exemple du projet Synclin’EauOrban, Philippe ; Wildemeersch, Samuel ; Gesels, Julie et alConference (2012, October 10) Detailed reference viewed: 43 (8 ULg) Diffuse urban and industrial groundwater pollution with metallic trace elements: a comparison between affected and unaffected areasGesels, Julie ; Dollé, Fabien ; et alPoster (2012, September 20) For metalic trace elements, spatially distributed background concentrations will be defined as a function of geological and hydrogeological context and considering the impact of diffuse pollution. Detailed reference viewed: 35 (11 ULg) Interactions between the Meuse River and its heterogeneous alluvial deposits at a contaminated brownfieldBrouyère, Serge ; ; Dassargues, Alain ![]() Conference (2012, June 08) Detailed reference viewed: 15 (4 ULg) A regional flux-based risk assessment approach for multiple contaminated sites on groundwater bodiesJamin, Pierre ; Dollé, Fabien ; et alin Journal of Contaminant Hydrology (2012), 127(1-4), 65-75 In the context of the Water Framework Directive (EP and CEU, 2000), management plans have to be set up to monitor and to maintain water quality in groundwater bodies in the EU. In heavily industrialized ... [more ▼] In the context of the Water Framework Directive (EP and CEU, 2000), management plans have to be set up to monitor and to maintain water quality in groundwater bodies in the EU. In heavily industrialized and urbanized areas, the cumulative effect of multiple contaminant sources is likely and has to be evaluated. In order to propose adequate measures, the calculated risk should be based on criteria reflecting the risk of groundwater quality deterioration, in a cumulative manner and at the scale of the entire groundwater body. An integrated GIS- and flux-based risk assessment approach for groundwater bodies is described, with a regional scale indicator for evaluating the quality status of the groundwater body. It is based on the SEQ-ESO currently used in the Walloon Region of Belgium which defines, for different water uses and for a detailed list of groundwater contaminants, a set of threshold values reflecting the levels of water quality and degradation with respect to each contaminant. The methodology is illustrated with first results at a regional scale on a groundwater body-scale application to a contaminated alluvial aquifer which has been classified to be at risk of not reaching a good quality status by 2015. These first results show that contaminants resulting from old industrial activities in that area are likely to contribute significantly to the degradation of groundwater quality. However, further investigations are required on the evaluation of the actual polluting pressures before any definitive conclusion be established. [less ▲] Detailed reference viewed: 60 (22 ULg) Flux-based Risk Assessement of the impact of Contaminants on Water resources and ECOsystemsJamin, Pierre ; ; et alReport (2012) Detailed reference viewed: 22 (3 ULg) Flux-based risk assessment of the impact of contamnants on water ressources and ecosystems - FRAC-WECO.Jamin, Pierre ; ; et alReport (2012) Detailed reference viewed: 30 (3 ULg) Modeling climate change impacts on groundwater resources using transient stochastic climatic scenariosGoderniaux, Pascal ; Brouyère, Serge ; et alin Water Resources Research (2011), 47 Several studies have highlighted the potential negative impact of climate change on groundwater reserves but additional work is required to help water managers to plan for future changes. In particular ... [more ▼] Several studies have highlighted the potential negative impact of climate change on groundwater reserves but additional work is required to help water managers to plan for future changes. In particular, existing studies provide projections for a stationary climate representative of the end of the century, although information is demanded for the near-future. Such time-slice experiments fail to account for the transient nature of climatic changes over the century. Moreover, uncertainty linked to natural climate variability is not explicitly considered in previous studies. In this study, we substantially improve upon the state-of-the-art by using a sophisticated transient weather generator (WG) in combination with an integrated surface-subsurface hydrological model (Geer basin, Belgium) developed with the finite element modelling software 'HydroGeoSphere'. This version of the WG enables the stochastic generation of large numbers of equiprobable climatic time series, representing transient climate change, and used to assess impacts in a probabilistic way. For the Geer basin, 30 equiprobable climate change scenarios from 2010 to 2085 have been generated for each of 6 different RCMs. Results show that although the 95% confidence intervals calculated around projected groundwater levels remain large, the climate change signal becomes stronger than that of natural climate variability by 2085. Additionally, the WG ability to simulate transient climate change enabled the assessment of the likely timescale and associated uncertainty of a specific impact, providing managers with additional information when planning further investment. This methodology constitutes a real improvement in the field of groundwater projections under climate change conditions. [less ▲] Detailed reference viewed: 45 (14 ULg) The Hybrid Finite-Element Mixing-Cell method: a candidate for modelling groundwater flow and transport in karst systemsBrouyère, Serge ; Wildemeersch, Samuel ; Orban, Philippe et alin Bertrand, C.; Carry, N.; Mudry, J. (Eds.) et al Proc. H2Karst, 9th Conference on Limestone Hydrogeology (2011, September) Groundwater flow and contaminant transport modelling in karst systems remains a challenge because of the complexity of the geology made of caves, voids, conduits of various sizes and forms and interacting ... [more ▼] Groundwater flow and contaminant transport modelling in karst systems remains a challenge because of the complexity of the geology made of caves, voids, conduits of various sizes and forms and interacting matrix. Such heterogeneous structures cause complex hydraulic conditions for groundwater flow and transport processes. Despite the progresses in field investigation techniques and experiments, detailed knowledge and characterization of the karst system geometry and connectivity remains inaccessible and pragmatic modelling approaches have to be used. Groundwater models of different complexities have been developed for karst systems, ranging from transfer functions and linear reservoir models to spatially distributed models. Here, a new flexible modelling approach, the Hybrid Finite-Element Mixing-Cell method (HFEMC), has been developed that allows combining in a single model, and in a fully interacting way, different mathematical approaches of various complexities for groundwater modelling in complex environments. This includes linear reservoirs, distributed reservoirs, groundwater flow in variably saturated equivalent porous media, with possibilities to consider by-pass flows along preferential flow paths, internal boundary conditions between the karstic features and the surrounding rock mass matrix background and drainage by surface waters. This method has been implemented in the groundwater flow and solute transport numerical code SUFT3D. The objective of this communication is to present the modelling concepts and to discuss the potentials and advantages of the HFEMC method for modelling groundwater flow in karst systems over existing more classical modelling approaches. The discussion is supported by illustrative “synthetic” examples representative of karst systems and a real modelling application to the case of groundwater rebound and water inrush in a closed underground coal mine which presents a very similar geometrical and hydrological context to a karst, with cavities, drains and interacting rock mass. [less ▲] Detailed reference viewed: 37 (13 ULg) Assessing the impacts of technical uncertainty on coupled surface/subsurface flow model predictions using a complex synthetic caseWildemeersch, Samuel ; Goderniaux, Pascal ; Orban, Philippe et alPoster (2011, September) According to the EU Water Framework Directive, Member States have to manage surface water and groundwater at the water body scale and in an integrated way. Flow and transport models constitute useful ... [more ▼] According to the EU Water Framework Directive, Member States have to manage surface water and groundwater at the water body scale and in an integrated way. Flow and transport models constitute useful management tools in this context since they can predict system responses to future stresses. However, numerical modelling at such a scale faces specific issues linked to (1) the representation of the geological and hydrogeological complexity, (2) the uneven level of characterisation knowledge, (3) the representativity of measured parameters and variables in the field, and (4) the CPU time needed for solving the numerical problem. Assumptions and simplifications made for dealing with these issues can lead to a series of models differing by their complexity and by the reliability of their predictions. Consequently, modellers have to find a compromise between complexity and reliability. The main objective of this research is to estimate the impacts of technical uncertainty, which is the uncertainty related to the numerical implementation, on groundwater flow model predictions. To reach that objective, the methodology consists in comparing reference predictions (hydraulic heads and flow rates) of a complex and close to reality synthetic case with the predictions provided by a series of simplified models (coarse spatial discretisation, coarse time discretisation, simplified law in the unsaturated zone). The synthetic case reflects the main characteristics found in groundwater bodies of South Belgium (Condroz region of Wallonia), characterised by a succession of limestone synclines and sandstone anticlines. The numerical model is developed with the fully-integrated surface/subsurface flow and transport code HydroGeoSphere using a mesh refined along the surface water network (153027 nodes and 269872 elements). A 5-year reference transient simulation, with daily stress factors is performed. The simulated hydraulic heads and flow rates constitute the reference observations and predictions for the comparison with the simplified models. The simplified models tested differ by their horizontal (500 m vs. 1000 m element size) and vertical (8 layers vs. 3 layers) spatial discretisations, their time discretisation (daily vs. monthly stress factors), and the type of constitutive law used for simulating the unsaturated flow (linear vs. van Genuchten). The models are run with the same parameter values than those used in the reference model to evaluate the deterioration in model predictions due to technical uncertainty. Additionally, some of the models are calibrated with the inverse modelling code PEST to distinguish how far a model calibration can possibly compensate for technical uncertainty. Then, predictions from each simplified model are compared with the reference predictions of the synthetic case. Then, the simplified models are ranked using several model performance criteria. Results of this research provide guidelines for the numerical implementation of groundwater flow models at the water body scale with respect to specific groundwater management objectives. [less ▲] Detailed reference viewed: 32 (13 ULg) |
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