Utilisation du jus de datte comme milieu d’immersion pour la déshydratation osmotique des graines de grenadeBchir, Brahim ; ; et alPoster (2010, October 14) Detailed reference viewed: 22 (8 ULg) CARBOHYDRATE-BASED SURFACTANTS FOR FORMING AND STABILIZING COLLOIDAL SYSTEMS AS EMULSIONS AND FOAMSRazafindralambo, Hary ; Blecker, Christophe ; Richel, Aurore et alPoster (2010, October 12) Detailed reference viewed: 29 (18 ULg) CARBOHYDRATE-BASED SURFACTANTS FOR FORMING AND STABILIZING COLLOIDAL SYSTEMS AS EMULSIONS AND FOAMSRazafindralambo, Hary ; Blecker, Christophe ; Richel, Aurore et alin Abstracts book of 5th edition of world congress on emulsions (2010, October 12) Carbohydrate-based surfactants (CBS) constitute a class of amphiphilic molecules with particular and common interests. These surface-active compounds can be produced from the most abundant renewable ... [more ▼] Carbohydrate-based surfactants (CBS) constitute a class of amphiphilic molecules with particular and common interests. These surface-active compounds can be produced from the most abundant renewable materials allowing large product concept possibilities, and may occur in a large structural range with one or more hydrophilic head groups and hydrophobic chains with various linkers/spacers, thanks to numerous reactive functional groups in their basic structure. It is then possible to design a quasi-unlimited number of new compounds by (bio)-synthesis from various raw materials. This structural diversity can generate a wide range of properties, which could be developed in food and non-food applications. Our challenge is now to find out the most suitable molecular structures for the post-development of CBS, mainly for colloidal systems like emulsion, foam, and suspension. A pre-screening of the dynamic and equilibrium interfacial tensions and interfacial rheology properties of various CBS prepared by chemical, enzymatic, or chemo-enzymatic synthesis routes from the derivatives of bio-renewable substrates is carried out. Then, the characterization of emulsifying and foaming properties of pre-selected molecules is performed. These investigations are completed by the characterization of thermal properties of liquid suspensions and powders. Homologous series of two derivative compounds of glucuronic and galacturonic acids with mono- or bicatenar hydrophobic chains and different linkages (linear or cyclic ester, amide) have been chosen as CBS starting compounds. These were full characterized by spectroscopic techniques (RMN, SM, IR). The effect of the hydrophobic chain length and number, polar head group, and the linker on whole properties investigated is easily deduced. [less ▲] Detailed reference viewed: 37 (21 ULg) Chemical characteristics and oxidative stability of sesame paste, and olive oils.; ; Blecker, Christophe et alin Journal of Agricultural Science and Technology (2010), 12 Detailed reference viewed: 18 (4 ULg) Osmotic Dehydration Kinetics of Pomegranate Seeds Using Date Juice as an Immersion Solution Base; ; et al in Food Bioprocess Technol (2010) Detailed reference viewed: 70 (8 ULg) Pretreatment And Enzymatic Hydrolysis Of Miscanthus x giganteus: Influence Of Process ParametersVanderghem, Caroline ; Brostaux, Yves ; Jacquet, Nicolas et alPoster (2010, September 21) Miscanthus x giganteus is a perennial grass which grows rapidly and gives high yields of biomass per hectare. It can be grown in poor quality soil and is non invasive. Due to its high cellulose and ... [more ▼] Miscanthus x giganteus is a perennial grass which grows rapidly and gives high yields of biomass per hectare. It can be grown in poor quality soil and is non invasive. Due to its high cellulose and hemicellulose content, it has attracted considerable attention as a possible energy crop to produce bioethanol. Pretreatment of lignocellulosic biomass is a key step to unlocking the protective structures so that the enzymatic hydrolysis of the carbohydrate fraction to monosugars can be achieved more easily and with greater yield. In this study, Miscanthus x giganteus was delignified by a chemical pre-treatment process using a mixture of formic acid/acetic acid (1). The treated material was then hydrolyzed. By means of Box-Behnken experimental design and response surface methodology we investigated the effect of cooking time (60, 120 and 180 min), formic acid/acetic acid/water concentration (20/60/20, 30/50/20 and 40/40/20) and temperature (80, 90 and 107°C) on the residual Klason lignin content and the % of digestibility. The optimal pretreatment process parameters were identified. [less ▲] Detailed reference viewed: 28 (9 ULg) Osmotic Dehydration Kinetics of Pomegranate Seeds Using Date Juice as an Immersion Solution BaseBchir, Brahim ; ; et alin Food and Bioprocess Technology (2010) Pomegranate seeds were osmodehydrated using date juice added with sucrose (final °Brix, 55) as immersion solution. The kinetics of osmotic dehydration showed that the most significant changes of mass ... [more ▼] Pomegranate seeds were osmodehydrated using date juice added with sucrose (final °Brix, 55) as immersion solution. The kinetics of osmotic dehydration showed that the most significant changes of mass transfer took place during the first 20 min of the process, regardless of date juice varieties. During this time, seed water loss and solid gain were estimated to be ∼39% and ∼6%, respectively. After 20 min of the process, the percentage of water loss and solid gain varied slightly and ranged on average close to ∼40% and ∼9%, respectively. During osmotic dehydration, there was a leaching of natural solutes from seeds into the solution, which is quantitatively not negligible, and might have an important impact on the sensorial and nutritional value of seeds and date juices. Both scanning electron microscopy and texture (compression) analysis revealed that osmotic dehydration process induced modifications of seed texture and cell structure. Sucrose was found to be the essential element which influences the texture of seed and the viscosity of date juice. Additionally, natural sugar present in date juice permits substituting 35% of the total quantity of sucrose added to the osmotic solution. [less ▲] Detailed reference viewed: 9 (4 ULg) Enzymatic synthesis of novel carbohydrate surfactants for water/supercritical CO2 emulsionsBoyère, Cédric ; Favrelle, Audrey ; Deleu, Magali et alPoster (2010, September 07) Detailed reference viewed: 8 (1 ULg) Mid-Infrared Spectroscopy Coupled with Chemometrics: A Tool for the Analysis of Intact Food Systems and the Exploration of Their Molecular Structure-Quality Relationships - A Review; ; Blecker, Christophe ![]() in Chemical Reviews (2010), 110(10), 6144-6168 Public interest in food quality and methods of production has increased significantly in recent decades, due in part to changes in eating habits, consumer behavior, and the increased industrialization and ... [more ▼] Public interest in food quality and methods of production has increased significantly in recent decades, due in part to changes in eating habits, consumer behavior, and the increased industrialization and globalization of food supply chains.1 Demand for high levels of quality and safety in food production obviously requires high standards in quality assurance and process control; satisfying this demand in turn requires appropriate analytical tools for food analysis both during and after production. Desirable features of such tools include speed, ease-of-use, minimal or no sample preparation, and the avoidance of sample destruction. These features are characteristic of a range of spectroscopic methods including the mid-infrared (MIR). While it is true that near-infrared (NIR) spectroscopy has achieved greater uptake by the food industry,2 reported applications of MIR in this sector have increased over the past decade or more. Foods represent significant analytical challenges. They are highly complex, variable and can be found in a number of different physical states: these include solids, dilute solutions, emulsions, foams, highly visco-elastic forms, and glassy [less ▲] Detailed reference viewed: 13 (1 ULg) Impact of ageing and food additives on the physico-chemical properties of partially hydrolyzed and pregelatinized rice flourMertens, Cécile ; Blecker, Christophe ![]() Poster (2010, August 25) Conservation of the quality of a food product is an essential preoccupation for industrials. Indeed, food acceptability by consummers depends of this quality. However, the latter decreases with time of ... [more ▼] Conservation of the quality of a food product is an essential preoccupation for industrials. Indeed, food acceptability by consummers depends of this quality. However, the latter decreases with time of storage, due to complex alteration reactions. This study presents a first approach of alteration reactions in a particular range of products: drum-dried pregelatinized cereal products. While this type of product is widely used as thickeners or in infant foods, no study has ever been made on the subject. The cereal studied here is one of the most consumed by mankind: rice. We also investigated the impact of food additives (E170 & E340ii) on the ageing of such a product, because they are often used empirically in industry. [less ▲] Detailed reference viewed: 56 (11 ULg) Influence of steam explosion and thermal degradation of celluloseJacquet, Nicolas ; ; Vanderghem, Caroline et alPoster (2010, August 20) The aim of the present work is to compare the effect of different steam explosion pretreatments on the thermal degradation of a bleached cellulose where components like hemicelluloses and lignin have ... [more ▼] The aim of the present work is to compare the effect of different steam explosion pretreatments on the thermal degradation of a bleached cellulose where components like hemicelluloses and lignin have already been removed by acid and alkaline treatments. The results of this study show that thermal degradation of cellulose fibres, studied by TGA, is still limited for a temperature process below 240 °C. However, derivative TGA show that thermal stability of cellulose obtained by these conditions decreases with the increase of temperature. For temperatures above 250°C, char level is higher at the end of the pyrolysis. According to the literature, the increase of the char level is correlated to an increase of the degradation product1. Determination of the degradation products in the liquor obtained after the pretreatment show an important increase of furfural and 5-hydroxymethylfurfural concentration with the temperature in agreement with the increase of the char level. These results confirm the important degradation of the cellulose fibres. [less ▲] Detailed reference viewed: 29 (5 ULg) Steam explosion pretreatment and thermal degradation of cellulose fibersJacquet, Nicolas ; ; Vanderghem, Caroline et alConference (2010, August 20) Detailed reference viewed: 16 (6 ULg) A Process for the production of a composition, the composition and the use there-of as food additiveGoffin, Dorothée ; Paquot, Michel ; Blecker, Christophe et alPatent (2010) Detailed reference viewed: 41 (20 ULg) Chemical properties of 11 date cultivars and their corresponding fibers extracts.; ; Blecker, Christophe et alin African Journal of Biotechnology (2010), 9(26), 4096-4105 Detailed reference viewed: 37 (12 ULg) Présentation de Pierre Gagnaire, grand chef cuisinierBlecker, Christophe ![]() Scientific conference (2010, May 18) Detailed reference viewed: 10 (1 ULg) Synthèse enzymatique de surfactants sucrés en milieux organiques et dans le CO2 supercritiqueFavrelle, Audrey ; Brognaux, Alison ; Nott, Katherine et alPoster (2010, May 18) Detailed reference viewed: 45 (22 ULg) Characterisation of proteins from date palm sap (Phoenix dactylifera L.) by a proteomic approach; ; et al in Food Chemistry (2010) The proteins contained in juice tapped from date palm (Phoenix dactylifera L.), from Deglet Nour variety, were analysed by the application of two-dimensional electrophoresis (2DE). Identification was ... [more ▼] The proteins contained in juice tapped from date palm (Phoenix dactylifera L.), from Deglet Nour variety, were analysed by the application of two-dimensional electrophoresis (2DE). Identification was carried out by mass spectrometry analyses. The SDS–PAGE patterns showed more than 100 spots of which 52 spots were identified. A proportion of the identified proteins were related to Saccharomyces cerevisiae that may belong to the natural microflora of date palm sap. These proteins are principally involved in glycolysis. While other proteins were assigned to be vegetable proteins, probably a mixture of proteins from the vascular system, which have several biological functions within the palm tree. Thus, we found enzymes involved in stress and defence reactions, in glycolysis, and photosynthesis reactions. Other enzymes are associated with carbohydrates and proteins metabolisms. [less ▲] Detailed reference viewed: 52 (18 ULg) Effect of the addition of deffated date seeds on wheat dough performance and bread quality.; ; Blecker, Christophe et alin Journal of Texture Studies (2010), 41 Detailed reference viewed: 40 (7 ULg) Pectin extraction from lemon by-product with acidified date juice : effect of extraction conditions on chemical composition of pectin.; ; et al in Food Science & Technology International (2010), 16(2), 105-114 The microstructure and the rheological properties of lemon-pectin mixtures were studied and compared to those of pure lemon (high methoxyl: HM) and date (low methoxyl: LM) pectins. Rheological properties ... [more ▼] The microstructure and the rheological properties of lemon-pectin mixtures were studied and compared to those of pure lemon (high methoxyl: HM) and date (low methoxyl: LM) pectins. Rheological properties were carried out in the presence of 30%, 45% and 60% sucrose, and increasing calcium concentrations (0-0.1%). The presence of date with lemon pectin led to a gel formation at 45% sucrose and in the presence of calcium, which was not the case for lemon pectin alone under the same conditions. It is suggested that lemon and date pectins interacted, leading to gel formations at different gelling temperatures, which were strongly dependant on degree of methylation. These results were confirmed by scanning electron microscopy, which revealed inhomogeneous gels where dense aggregated network and loose, open network areas were present. Addition of calcium to pectin mixture gels led to stronger and faster gel formation. [less ▲] Detailed reference viewed: 60 (15 ULg) A la rencontre de l'innovation technologique: la valorisation alimentaireBlecker, Christophe ![]() Scientific conference (2010, March 24) Detailed reference viewed: 13 (3 ULg) |
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